Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies

Yowe Kidwe; Abia Daouda; Tcheka Constant; Domga; Domga Richard; Harouna Massai

doi:doi:10.11648/j.ajaic.20220602.13

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Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies

Yowe Kidwe, Abia Daouda, Tcheka Constant, Domga, Domga Richard, Harouna Massai

Published in American Journal of Applied and Industrial Chemistry (Volume 6, Issue 2)

Received: 9 October 2022 Accepted: 8 November 2022 Published: 16 November 2022

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Abstract

This work consists of recovering cottonseed cakes by adsorption of gossypol which is a polyphenolic and extremely toxic pigment found in certain effluents such as those from the oil mill of the cotton development company. However, experimental and practical adsorption tests have shown that the equilibrium time is established after 10 minutes with the initial concentration of 50 mg.L^-1, the same mass of 0.1 g for the biosorbent and the activated carbon based on this agricultural waste, the temperature of the reaction medium of 65 °C and the pH equal to 12. The phenomenon of adsorption of gossypol on these adsorbents is therefore perfectly described by the kinetics of the pseudo-second-order and the Langmuir isotherm model with high correlation coefficients. It was also noted in this work that all the values obtained on the activated carbon are high compared to those obtained on the raw biosorbent. These results would confirm the release of other new adsorption sites by the effect of physico-chemical activation with phosphoric acid. The thermodynamic parameters relating to the adsorbent-adsorbate system indicate that the adsorption of gossypol on adsorbents based on cottonseed cakes occurs spontaneously, unordered and with release of heat (exothermic).

Published in	American Journal of Applied and Industrial Chemistry (Volume 6, Issue 2)
DOI	10.11648/j.ajaic.20220602.13
Page(s)	47-56
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Adsorption, Cottonseed Cakes, Gossypol, Kinetics, Thermodynamic Parameters

References

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APA Style

Yowe Kidwe, Abia Daouda, Tcheka Constant, Domga, Domga Richard, et al. (2022). Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. American Journal of Applied and Industrial Chemistry, 6(2), 47-56. https://doi.org/10.11648/j.ajaic.20220602.13

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ACS Style

Yowe Kidwe; Abia Daouda; Tcheka Constant; Domga; Domga Richard, et al. Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. Am. J. Appl. Ind. Chem. 2022, 6(2), 47-56. doi: 10.11648/j.ajaic.20220602.13

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AMA Style

Yowe Kidwe, Abia Daouda, Tcheka Constant, Domga, Domga Richard, et al. Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. Am J Appl Ind Chem. 2022;6(2):47-56. doi: 10.11648/j.ajaic.20220602.13

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@article{10.11648/j.ajaic.20220602.13,
  author = {Yowe Kidwe and Abia Daouda and Tcheka Constant and Domga and Domga Richard and Harouna Massai},
  title = {Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {6},
  number = {2},
  pages = {47-56},
  doi = {10.11648/j.ajaic.20220602.13},
  url = {https://doi.org/10.11648/j.ajaic.20220602.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20220602.13},
  abstract = {This work consists of recovering cottonseed cakes by adsorption of gossypol which is a polyphenolic and extremely toxic pigment found in certain effluents such as those from the oil mill of the cotton development company. However, experimental and practical adsorption tests have shown that the equilibrium time is established after 10 minutes with the initial concentration of 50 mg.L-1, the same mass of 0.1 g for the biosorbent and the activated carbon based on this agricultural waste, the temperature of the reaction medium of 65 °C and the pH equal to 12. The phenomenon of adsorption of gossypol on these adsorbents is therefore perfectly described by the kinetics of the pseudo-second-order and the Langmuir isotherm model with high correlation coefficients. It was also noted in this work that all the values obtained on the activated carbon are high compared to those obtained on the raw biosorbent. These results would confirm the release of other new adsorption sites by the effect of physico-chemical activation with phosphoric acid. The thermodynamic parameters relating to the adsorbent-adsorbate system indicate that the adsorption of gossypol on adsorbents based on cottonseed cakes occurs spontaneously, unordered and with release of heat (exothermic).},
 year = {2022}
}

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TY  - JOUR
T1  - Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies
AU  - Yowe Kidwe
AU  - Abia Daouda
AU  - Tcheka Constant
AU  - Domga
AU  - Domga Richard
AU  - Harouna Massai
Y1  - 2022/11/16
PY  - 2022
N1  - https://doi.org/10.11648/j.ajaic.20220602.13
DO  - 10.11648/j.ajaic.20220602.13
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 47
EP  - 56
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20220602.13
AB  - This work consists of recovering cottonseed cakes by adsorption of gossypol which is a polyphenolic and extremely toxic pigment found in certain effluents such as those from the oil mill of the cotton development company. However, experimental and practical adsorption tests have shown that the equilibrium time is established after 10 minutes with the initial concentration of 50 mg.L-1, the same mass of 0.1 g for the biosorbent and the activated carbon based on this agricultural waste, the temperature of the reaction medium of 65 °C and the pH equal to 12. The phenomenon of adsorption of gossypol on these adsorbents is therefore perfectly described by the kinetics of the pseudo-second-order and the Langmuir isotherm model with high correlation coefficients. It was also noted in this work that all the values obtained on the activated carbon are high compared to those obtained on the raw biosorbent. These results would confirm the release of other new adsorption sites by the effect of physico-chemical activation with phosphoric acid. The thermodynamic parameters relating to the adsorbent-adsorbate system indicate that the adsorption of gossypol on adsorbents based on cottonseed cakes occurs spontaneously, unordered and with release of heat (exothermic).
VL  - 6
IS  - 2
ER  -

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Author Information

Yowe Kidwe

Faculty of Sciences, University of Ngaoundere, Ngaoundere, Cameroon
Abia Daouda

Faculty of Sciences, University of Ngaoundere, Ngaoundere, Cameroon
Tcheka Constant

Faculty of Sciences, University of Ngaoundere, Ngaoundere, Cameroon
Domga

National School of Agro-Industrial Sciences, University of Ngaoundere, Ngaoundere, Cameroon
Domga Richard

National School of Agro-Industrial Sciences, University of Ngaoundere, Ngaoundere, Cameroon
Harouna Massai

Faculty of Sciences, University of Ngaoundere, Ngaoundere, Cameroon

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APA Style

Yowe Kidwe, Abia Daouda, Tcheka Constant, Domga, Domga Richard, et al. (2022). Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. American Journal of Applied and Industrial Chemistry, 6(2), 47-56. https://doi.org/10.11648/j.ajaic.20220602.13

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ACS Style

Yowe Kidwe; Abia Daouda; Tcheka Constant; Domga; Domga Richard, et al. Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. Am. J. Appl. Ind. Chem. 2022, 6(2), 47-56. doi: 10.11648/j.ajaic.20220602.13

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AMA Style

Yowe Kidwe, Abia Daouda, Tcheka Constant, Domga, Domga Richard, et al. Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies. Am J Appl Ind Chem. 2022;6(2):47-56. doi: 10.11648/j.ajaic.20220602.13

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@article{10.11648/j.ajaic.20220602.13,
  author = {Yowe Kidwe and Abia Daouda and Tcheka Constant and Domga and Domga Richard and Harouna Massai},
  title = {Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies},
  journal = {American Journal of Applied and Industrial Chemistry},
  volume = {6},
  number = {2},
  pages = {47-56},
  doi = {10.11648/j.ajaic.20220602.13},
  url = {https://doi.org/10.11648/j.ajaic.20220602.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajaic.20220602.13},
  abstract = {This work consists of recovering cottonseed cakes by adsorption of gossypol which is a polyphenolic and extremely toxic pigment found in certain effluents such as those from the oil mill of the cotton development company. However, experimental and practical adsorption tests have shown that the equilibrium time is established after 10 minutes with the initial concentration of 50 mg.L-1, the same mass of 0.1 g for the biosorbent and the activated carbon based on this agricultural waste, the temperature of the reaction medium of 65 °C and the pH equal to 12. The phenomenon of adsorption of gossypol on these adsorbents is therefore perfectly described by the kinetics of the pseudo-second-order and the Langmuir isotherm model with high correlation coefficients. It was also noted in this work that all the values obtained on the activated carbon are high compared to those obtained on the raw biosorbent. These results would confirm the release of other new adsorption sites by the effect of physico-chemical activation with phosphoric acid. The thermodynamic parameters relating to the adsorbent-adsorbate system indicate that the adsorption of gossypol on adsorbents based on cottonseed cakes occurs spontaneously, unordered and with release of heat (exothermic).},
 year = {2022}
}

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TY  - JOUR
T1  - Investigation on Removal of Gossypol from Aqueous Solutions Using Cottonseed Cakes: Batch Equilibrium, Kinetics and Thermodynamic Studies
AU  - Yowe Kidwe
AU  - Abia Daouda
AU  - Tcheka Constant
AU  - Domga
AU  - Domga Richard
AU  - Harouna Massai
Y1  - 2022/11/16
PY  - 2022
N1  - https://doi.org/10.11648/j.ajaic.20220602.13
DO  - 10.11648/j.ajaic.20220602.13
T2  - American Journal of Applied and Industrial Chemistry
JF  - American Journal of Applied and Industrial Chemistry
JO  - American Journal of Applied and Industrial Chemistry
SP  - 47
EP  - 56
PB  - Science Publishing Group
SN  - 2994-7294
UR  - https://doi.org/10.11648/j.ajaic.20220602.13
AB  - This work consists of recovering cottonseed cakes by adsorption of gossypol which is a polyphenolic and extremely toxic pigment found in certain effluents such as those from the oil mill of the cotton development company. However, experimental and practical adsorption tests have shown that the equilibrium time is established after 10 minutes with the initial concentration of 50 mg.L-1, the same mass of 0.1 g for the biosorbent and the activated carbon based on this agricultural waste, the temperature of the reaction medium of 65 °C and the pH equal to 12. The phenomenon of adsorption of gossypol on these adsorbents is therefore perfectly described by the kinetics of the pseudo-second-order and the Langmuir isotherm model with high correlation coefficients. It was also noted in this work that all the values obtained on the activated carbon are high compared to those obtained on the raw biosorbent. These results would confirm the release of other new adsorption sites by the effect of physico-chemical activation with phosphoric acid. The thermodynamic parameters relating to the adsorbent-adsorbate system indicate that the adsorption of gossypol on adsorbents based on cottonseed cakes occurs spontaneously, unordered and with release of heat (exothermic).
VL  - 6
IS  - 2
ER  -

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