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Application and Market of 1,4-butanediol Production of Reppe Method in China

Received: 21 December 2020    Accepted: 9 March 2021    Published: 17 March 2021
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Abstract

The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.

Published in American Journal of Chemical Engineering (Volume 9, Issue 2)
DOI 10.11648/j.ajche.20210902.11
Page(s) 34-38
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

1,4-Butanediol, Reppe Method, BDO, Technology and Application

References
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[7] Luo Ping, Deng Jiankang, Jiang Jijun, et al. Industrial application of synthesis of 1, 4-butynediol EQ-201 alkynating catalyst [J]. Coal chemical industry, 2019, 47 (6): 9.
[8] Zhou Huanwen, Deng Shaoliang. A catalyst for the production of 1, 4-butynediol and its preparation method: China, CN103480382A [P].2014-01-01.
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  • APA Style

    Ping Luo, Xiaoding Li. (2021). Application and Market of 1,4-butanediol Production of Reppe Method in China. American Journal of Chemical Engineering, 9(2), 34-38. https://doi.org/10.11648/j.ajche.20210902.11

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    ACS Style

    Ping Luo; Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am. J. Chem. Eng. 2021, 9(2), 34-38. doi: 10.11648/j.ajche.20210902.11

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    AMA Style

    Ping Luo, Xiaoding Li. Application and Market of 1,4-butanediol Production of Reppe Method in China. Am J Chem Eng. 2021;9(2):34-38. doi: 10.11648/j.ajche.20210902.11

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  • @article{10.11648/j.ajche.20210902.11,
      author = {Ping Luo and Xiaoding Li},
      title = {Application and Market of 1,4-butanediol Production of Reppe Method in China},
      journal = {American Journal of Chemical Engineering},
      volume = {9},
      number = {2},
      pages = {34-38},
      doi = {10.11648/j.ajche.20210902.11},
      url = {https://doi.org/10.11648/j.ajche.20210902.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20210902.11},
      abstract = {The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Application and Market of 1,4-butanediol Production of Reppe Method in China
    AU  - Ping Luo
    AU  - Xiaoding Li
    Y1  - 2021/03/17
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajche.20210902.11
    DO  - 10.11648/j.ajche.20210902.11
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 34
    EP  - 38
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.20210902.11
    AB  - The industrial production methods of 1,4-butanediol (BDO) are: maleic anhydride method (Davy-McKee), butadiene-acetic acid method (Mitsubishi Chemical), propylene oxide method (Lyondell), Reppe method, etc. Among these methods, only the Reppe process has achieved rapid development in China, with capacity far exceeding that of other petrochemical feedstock methods, because China has abundant mineral resources (e.g., coal and calcium carbide) where cheap feedstock is available for the production of 1,4-butanediol. There are three key steps in the production of 1, 4-butynediol by the Reppe method (methanol oxidation, alkynylation of formaldehyde and acetylene, and hydrogenation of 1, 4-butynediol). In recent years, Chinese enterprises have continuously explored and optimized these technologies introduced from abroad, and made some progress in process, equipment, catalyst, environmental protection and other related application technologies, which has promoted the technological progress of the industry. The latest statistical analysis is made on the application and market status of Reppe process for 1,4-butanediol production in China, and some opinions are put forward for the development of enterprises and 1,4-butanediol industry in the future, hoping to provide meaningful reference for the development of industry.
    VL  - 9
    IS  - 2
    ER  - 

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Author Information
  • Haiso Technology Co., Ltd., Wuhan, China

  • Haiso Technology Co., Ltd., Wuhan, China

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