| Peer-Reviewed

The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics

Received: 16 December 2021    Accepted: 26 March 2022    Published: 31 March 2022
Views:       Downloads:
Abstract

The presence of cationic dyes; especially the basic ones in an aqueous solution causes several problems. Therefore, it is necessary to reduce itfrom industrial effluents before being discharged into the environment. This study aimed to investigate the removal of Basic Blue 41 (BB41) dye from an aqueous solution using agricultural waste as an adsorbent. This study was conducted in a batch experimental system. The effect of various parameters such as initial dye concentration, pH, pHzpc and adsorbent dosage was studied. The data were examined by Freundlich, Temkin, Debinin-Radushkevich, pseudo first order and pseudo second order kinetic, and thermodynamic parameters. The characterization of the adsorbent was determined by the Scanning Electron Microscopy (SEM), Fourier transform infrared (FTIR) and X-Ray Diffraction (DRX). The results of this work showed that the Scolymus Maculatus adsorbent was proven most effective in removing Basic Blue 41 from an aqueous solution at pH=7,09 with 85,14%. The results showed also that the adsorption process follows the Freundlich isotherm as well as pseudo-second-order kinetic. The results of the thermodynamic process showed that the adsorption is spontaneous and endothermic in nature.

Published in American Journal of Engineering and Technology Management (Volume 7, Issue 2)
DOI 10.11648/j.ajetm.20220702.12
Page(s) 27-35
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Scolymus Maculatus, BB41, Adsorption, Kinetic, Thermodynamic

References
[1] Dutta, A. K., Ghorai, U. K., Chattopadhyay, K. K., & Banerjee, D. (2018). Removal of textile dyes by carbon nanotubes: A comparison between adsorption and UV assisted photocatalysis. Physical E: Low-dimensional Systems and Nanostructure, 99, 6-15.
[2] Kim, T. S. (2018). Fast adsorption kinetics of highly dispersed ultrafine nickel/carbon nanoparticles for organic dye removal. Applied Surface Science, 439, 364-370.
[3] Chen, Y. d., Yen-Chang, L., Shih-Hsin, H., Yan, Z., & Nan-qi R. (2018). Highly efficient adsorption of dyes by biochar derived from pigments extracted macro-algae pyrolyzed at different temperature. Bioresource Technology, 259, 104–110.
[4] Luan, J., Hou, P. X., Liu, C., Shi, C., Li, G. X., & Cheng, H. M. (2016). Efficient adsorption of organic dyes on a flexible single-wall carbon nanotube film. Journal of Material and Chemistry, 4, 1191–1194.
[5] Sharifpour, E., Khafri, H. Z., Ghaedi, M., Asfaram A., & Jannesar, R. (2018). Isotherms and kinetic study of ultrasound-assisted adsorption of malachite green and Pb2+ ions from aqueous samples by copper sulfide nanorods loaded on activated carbon: experimental design optimization. Ultrasonic Sonochemistry, 40, 373–382.
[6] Song, K., Xu, H., Xu, L., Xie K., & Yang, Y. (2017). Preparation of cellulose nanocrystalreinforced keratin bioadsorbent for highly effective and recyclable removal of dyes from aqueous solution. Bioresource Technology, 232, 254-262.
[7] Suyog Jain, N., & Parag Gogate R. R. (2018). Efficient removal of Acid Green 25 dye from wastewater using activated Prunus Dulcis as biosorbent: Batch and column studies. Journal of Environmental Management, 210, 226-238.
[8] Santos, R. M. M., Goncalves, R. G. L., Constantino, V. R. L., Santilli, C. V., Borges, P. D., Tronto, J., & Pinto, F. G. (2017). Adsorption of Acid Yellow 42 dye on calcined layered double hydroxide: effect of time, concentration, pH and temperature. Applied Clay Science, 140, 132-139.
[9] Subramaniam R., & Ponnusamy, S. K. (2015). Novel adsorbent from agricultural waste (cashew NUT shell) for methylene blue dye removal: optimization by response surface methodology. Water Resources and Industry, 11, 64-70.
[10] Ng, H. K. M., Leo, C. P., & Abdullah, A. Z. (2017). Selective removal of dyes by molecular imprinted TiO2 nanoparticles in polysulfone ultrafiltration membrane. Journal of Environmental and Chemical Engineering, 5, 3991-3998.
[11] Xue, C., Chen, Q., Liu, Y., Yang, Y., Xu, D., Xue, L., & Zhang, W. (2015). Acid blue 9 desalting using electrodialysis. Journal Membrane of Science, 493, 28-36.
[12] Singh S. A., & Shukla S. R. (2016). Adsorptive removal of cobalt ions on raw and alkalitreated lemon peels. International Journal and Environmental Science Technology, 13, 165-178.
[13] Huang, Y., Cui, C., Zhang, D., Li, L., & Pan, D. (2015). Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon. Chemosphere, 119, 295-301.
[14] Fontoura, J. T. D., Rolim, G. S., Mella, B., Farenzena M., & Gutterres, M. (2017). Defatted microalgal biomass as biosorbent for the removal of Acid Blue 161 dye from tannery effluent. Journal of Environmental Chemical Engineering, 5, pp 5.
[15] Khamparia S., & Jaspal, D. K. (2017). Xanthium strumarium L. seed hull as a zero cost alternative for Rhodamine B dye removal. Journal of Environmental Manager, 197, 498-506.
[16] Monteiro, M. S., Farias, F. R. D., Chaves, J. A. P., Santana, S. A., Silva H. A. S., & Bezerra, C. W. B. (2017). Wood (BagassaguianensisAubl) and green coconut mesocarp (cocoa nucifera) residues as textile dye removers (Remazol Red and Remazol Brilliant Violet). Journal of Environmental Manager, 204, 23-30.
[17] Dahri, M. K., Lim, L. B. L., Kooh M. R. R., & Chan, C. M. (2017). Adsorption of brilliant green from aqueous solution by unmodified and chemically modified Tarap (Artocarpusodoratissimus) peel. International Journal of Environmental Science Technology, 14, 2683-2694.
[18] Tangaraj, V., Janot, J., Jaber, M., Bechelany, M., & Balme, S. (2017). Adsorption and photophysical properties of fluorescent dyes over montmorillonite and saponite modified by surfactant. Chemosphere, 184, 1355-1361.
[19] Humelnicu, I., Baiceanu, A., Ignat, M. I., & Dulman, V. (2017). The removal of basic blue 41 textile dye from aqueous solution by adsorption onto natural zeolitic tuff: Kinetics and thermodynamics. Process Safety and Environmental Protection, 105, 274-287.
[20] Raghunath, S., Anand, K., Gengan, R. M., Nuyunigari, M. K., & Maity, A. (2016). Sorption isotherms, Kinetics and optimization process of amino acid prolin based polymer nanocomposite for the removal of selected textile dyes from industrial wastewater. Journal of photochemistry and photobiology, B: Biology, 165, 189-201.
[21] Barka, N., Abdennour, M., & El-Makhfouk, M. (2011). Removal of methylene blue and eriochrome Black from aqueous solution by biosorption on scolymushispanicus L: Kinetics, Equilibriums and Thermodynamics. Journal of the Taiwan Institute of Chemical Engineers, 42, 320-326.
[22] Barka, N., Abdennour, M., Boussaoud, A., & El-Makhfouk (2009). Biosorption characteristics of cadmium (II) onto scolymushispanicus. L as low cost natural biosorbent. Desalination, 258, 66-71.
[23] Nebel, S., Pieroni A., & Heinrich, M. (2006). Ta cho`rta: Wild Edible Greens used in theGraecanic Area in Calabria, Southern Italy. Appetite, 47, 333-342.
[24] Gonzalez-Tejero, M. R., Casares-Porcel, M., Sanchez-Rojas, C. P., Ramiro-Gutierrez, J.., Molero-Mesa, J., Pieroni, A., et al. (2008). Medicinal Plants in the Mediterranean Area: Synthesis of the Results of the Project Rubia. Journal of Ethnopharmacol, 116, 341-357.
[25] Ugurlu, E., & Secmen, O. (2008). Medicinal Plants Popularly used in the Villages of Yunt Mountain (Manisa-Turkey). Fitoterapia, 79, 126-31.
[26] Royer, E. C., Vaghelti, B., Simon, J. C. P. C., Cunha, N. M., Pavan, B. M., Benvenutti, F. A., et al. (2008). Application of Brazilian pine. Fruit shell as a biosorbent to removal of reactive red 194 textile dye from aqueous solution kinetics and equilibrium study. Journal of Hazardous Materials, 155, 536-550.
[27] Hameed B., & El-Khaiary, M. (2008). Equilibrium, kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3 activation and subsequent gasification with CO2. Journal of Hazardous Materials, 157, 344-351.
[28] Dawood S., & Sen, T. K. (2012). Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design. Journal of Water Research, 46, 1933-1946.
[29] Nautiyal, P., Subramanian K. A., & Dastidar, M. G. (2016). Adsorptive removal of dye using biochar derived from residual algae after in-situ transesterification: alternate use of waste of biodiesel industry. Journal of Environmental Manager, 182, 187-197.
[30] Freundlich, H. M. F. J. (1906). Kinetics and Thermodynamics of adsorption Methylene blue onto tea waste/CuFe2O4 composite. Journal of Physical Chemistry, 57: 385-417.
[31] Dubinin, M. M., & Radushkevich, L. V. (1947). The equation of the characteristic curve of the activated charcoal. USSR Physical Chemistry Section A, 55, 331-337.
[32] Ho, Y. S., & Ma Kay, G. (1999). Sorption of copper and nickel ions from aqueous solution using peat. Journal of Adsorption, 5, 409-417.
[33] Lo, I. M. C., & Zhang. (2005). EDTA-enhanced washing for remediation of Pb- and/or Zn contaminated soils. Journal of Environmental Management, 132, 1282-1288.
[34] Ayad, M. M., & El-Nasr A. A. (2012). Anionic dye (acid green 25) adsorption from water by using polyaniline nanotubes salt/silica composite. Journal of Nanostructure in Chemistry, 3, 1-9.
[35] Islam, M. A., Ahmed, M. J., & Khanday. W. A. (2017). Mesoporous activated coconut shell-derived hydrochar prepared via hydrothermal carbonization-NaOH activation for methylene blue adsorption. Journal of Environmental Management, 203, 237-244.
[36] Singh, V. K., & Kumar, E. A. (2016) Measurement and analysis of adsorption isotherms of CO2 on activated carbon. Applied Thermal Engineering, 97, 77-86.
[37] Paşka, O. M., Păcurariu, C., & Muntean, S. G. (2014). Kinetic and thermodynamic studies on methylene blue biosorption using corn-husk. RSC Advances, 4, 62621-62630.
[38] Papita, S., & Shamik, C. (2011). Insight into adsorption thermodynamics. Prof. Tadashi, M (Ed.), Thermodynamic. InTech Open Access Publisher, 349-364.
[39] Vimonses, V., Sei, S., & Jin, B. (2009). Kinetic study and equilibrium isotherm analysis of Congo red adsorption by clay materials. Chemical Engineering Journal, 148, 354-364.
Cite This Article
  • APA Style

    Amel Hamadi, Hiba Kais, Ahmed Hamdi Aissa, Nacera Yeddou-Mezenner. (2022). The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics. American Journal of Engineering and Technology Management, 7(2), 27-35. https://doi.org/10.11648/j.ajetm.20220702.12

    Copy | Download

    ACS Style

    Amel Hamadi; Hiba Kais; Ahmed Hamdi Aissa; Nacera Yeddou-Mezenner. The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics. Am. J. Eng. Technol. Manag. 2022, 7(2), 27-35. doi: 10.11648/j.ajetm.20220702.12

    Copy | Download

    AMA Style

    Amel Hamadi, Hiba Kais, Ahmed Hamdi Aissa, Nacera Yeddou-Mezenner. The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics. Am J Eng Technol Manag. 2022;7(2):27-35. doi: 10.11648/j.ajetm.20220702.12

    Copy | Download

  • @article{10.11648/j.ajetm.20220702.12,
      author = {Amel Hamadi and Hiba Kais and Ahmed Hamdi Aissa and Nacera Yeddou-Mezenner},
      title = {The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics},
      journal = {American Journal of Engineering and Technology Management},
      volume = {7},
      number = {2},
      pages = {27-35},
      doi = {10.11648/j.ajetm.20220702.12},
      url = {https://doi.org/10.11648/j.ajetm.20220702.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajetm.20220702.12},
      abstract = {The presence of cationic dyes; especially the basic ones in an aqueous solution causes several problems. Therefore, it is necessary to reduce itfrom industrial effluents before being discharged into the environment. This study aimed to investigate the removal of Basic Blue 41 (BB41) dye from an aqueous solution using agricultural waste as an adsorbent. This study was conducted in a batch experimental system. The effect of various parameters such as initial dye concentration, pH, pHzpc and adsorbent dosage was studied. The data were examined by Freundlich, Temkin, Debinin-Radushkevich, pseudo first order and pseudo second order kinetic, and thermodynamic parameters. The characterization of the adsorbent was determined by the Scanning Electron Microscopy (SEM), Fourier transform infrared (FTIR) and X-Ray Diffraction (DRX). The results of this work showed that the Scolymus Maculatus adsorbent was proven most effective in removing Basic Blue 41 from an aqueous solution at pH=7,09 with 85,14%. The results showed also that the adsorption process follows the Freundlich isotherm as well as pseudo-second-order kinetic. The results of the thermodynamic process showed that the adsorption is spontaneous and endothermic in nature.},
     year = {2022}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - The Effectiveness of Scolymus Maculatus in the Removal of Basic Blue Dye 41 in Aqueous Solutions: Kinetics and Thermodynamics
    AU  - Amel Hamadi
    AU  - Hiba Kais
    AU  - Ahmed Hamdi Aissa
    AU  - Nacera Yeddou-Mezenner
    Y1  - 2022/03/31
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajetm.20220702.12
    DO  - 10.11648/j.ajetm.20220702.12
    T2  - American Journal of Engineering and Technology Management
    JF  - American Journal of Engineering and Technology Management
    JO  - American Journal of Engineering and Technology Management
    SP  - 27
    EP  - 35
    PB  - Science Publishing Group
    SN  - 2575-1441
    UR  - https://doi.org/10.11648/j.ajetm.20220702.12
    AB  - The presence of cationic dyes; especially the basic ones in an aqueous solution causes several problems. Therefore, it is necessary to reduce itfrom industrial effluents before being discharged into the environment. This study aimed to investigate the removal of Basic Blue 41 (BB41) dye from an aqueous solution using agricultural waste as an adsorbent. This study was conducted in a batch experimental system. The effect of various parameters such as initial dye concentration, pH, pHzpc and adsorbent dosage was studied. The data were examined by Freundlich, Temkin, Debinin-Radushkevich, pseudo first order and pseudo second order kinetic, and thermodynamic parameters. The characterization of the adsorbent was determined by the Scanning Electron Microscopy (SEM), Fourier transform infrared (FTIR) and X-Ray Diffraction (DRX). The results of this work showed that the Scolymus Maculatus adsorbent was proven most effective in removing Basic Blue 41 from an aqueous solution at pH=7,09 with 85,14%. The results showed also that the adsorption process follows the Freundlich isotherm as well as pseudo-second-order kinetic. The results of the thermodynamic process showed that the adsorption is spontaneous and endothermic in nature.
    VL  - 7
    IS  - 2
    ER  - 

    Copy | Download

Author Information
  • Laboratory of Engineering of Reaction, Department of Environmental Engineering, Faculty of Mechanical Engineering and Process Engineering, University of Science and Technology Haouari Boumadien, Algiers, Algeria

  • Laboratory of Engineering of Reaction, Department of Environmental Engineering, Faculty of Mechanical Engineering and Process Engineering, University of Science and Technology Haouari Boumadien, Algiers, Algeria

  • Departement of Education, National University of Malaysia, Bangi, Malaysia

  • Laboratory of Engineering of Reaction, Department of Environmental Engineering, Faculty of Mechanical Engineering and Process Engineering, University of Science and Technology Haouari Boumadien, Algiers, Algeria

  • Sections