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Design of an Alkaline Water Electrolyzer for Hydrogen Production

Received: 27 November 2022    Accepted: 26 December 2022    Published: 10 January 2023
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Abstract

Hydrogen is an excellent energy carrier that is capable of storing excess generated renewable energy. It can be utilised in a fuel cell to produce electrical energy which is a sustainable alternative to conventional energy sources. This paper focuses on the design process of an alkaline water electrolyzer for the production of hydrogen through the electrolysis of water. A single cell, zero-gap, unipolar alkaline water electrolyzer, operating with 30 wt.% KOH solution as electrolyte is designed for a capacity of about 306 g of water. The design of the cell geometry was modified to enable improved hydrogen production. Thermal and stress simulations were performed with Autodesk Inventor Nastran 2019 on some modelled components of the designed electrolyzer cell, with the working temperature at about 80°C to 90°C, while maintaining the operating pressure at about 1.0 bar. Thermal and stress distributions from the results agree with the choice of material for the components, and confirms polytetrafluoroethylene (Teflon), and polypropylene plastic suitable for alkaline electrolyzer construction. Von Mises stress evaluation obtained maximum stress values of 0.143 Mpa and 0.138 Mpa, as well as 0.126 Mpa and 0.157 Mpa, for the endplates and spacers for polytetrafluoroethylene and polypropylene plastics respectively. The stress values are well within the safe limits for both PTFE and PP materials which have yield strength of 35 Mpa and 24 Mpa respectively.

Published in American Journal of Mechanical and Industrial Engineering (Volume 7, Issue 6)
DOI 10.11648/j.ajmie.20220706.12
Page(s) 89-98
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Alkaline, Electrolysis, Electrolyzer, Hydrogen, Water

References
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[2] U. S. Department of Energy (2020). Hydrogen and fuel cell technologies office. Energy Efficiency & Renewable Energy. Retrieved from https://www.energy.gov/eere/fuelcells/hydrogen-and-fuel-cell-technologies-office on June 26, 2021.
[3] Kalamaras, C. M. and Efstathiou, A. M. (2013). Hydrogen production technologies: current state and future developments. Conference papers in energy, 2013: 1-9. Retrieved from https://www.hindawi.com/journals/cpis/2013/690627/ on April 10, 2020.
[4] Stolten, D. (2016). Hydrogen Science and Engineering: materials, processes, systems and technology. John Wiley & sons (898).
[5] Campbell, R. J. (2020). Hydrogen in electricity’s future. Congressional Research Service. CRS Report, R46436. June 30, 2020.
[6] Fuel Cell Store (2017). Introduction to electrolyzers. Retrieved from https://www.fuelcellstore.com/blog-section/introduction-to-electrolyzers on June 27, 2021.
[7] Amores, E., Rodriguez, J. and Carreras, C. (2014). Influence of operation parameters in the modeling of alkaline water electrolyzers for hydrogen production. International Journal of Hydrogen Energy (39) 13063-13078.
[8] Haug, P., Kreitz, B., Koj, M. and Turek, T. (2017). Process modeling of an alkaline water electrolyzer. Institute of Chemical and Electrochemical Process Engineering, Clausthal University of Technology, Leibnizstr, Germany. International Journal of Hydrogen Energy, 1-19.
[9] Kuleshov, V. N., Kuleshov. N. V., Grigoriev, S. A., Udris, E. Y., Millet, P. and Grigoriev, A. S. (2016). Development and characterization of new nickel coatings for application in alkaline water electrolysis. International Journal of Hydrogen Energy 41, 36-45.
[10] Brauns, J. and Turek, T. (2020). Alkaline water electrolysis powered by renewable energy: a review. Institute of Chemical and Electrochemical Process Engineering, Clausthal University of Technology, Leibnizstr, Germany (8) 248.
[11] Britannica (2011). Electrode electronics. The Editors of Encyclopedia Britannica. Retrieved from https://www.britannica.com/science/electrode on August 4, 2021.
[12] Coutanceau, C., Baranton, S. and Audichon, T. (2018). Chapter 3 – Hydrogen production from water electrolysis. In Hydrogen Energy and Fuel Cells Primers, Hydrogen Electrochemical Production, Academic Press, 17-62.
[13] Scott, K. (2017). Hydrogen production and water electrolysis. Sustainable and Green Electrochemical Science and Technology, First Edition. Published by John Wiley & Sons Ltd.
[14] Hnát, J., Paidar, M. and Bouzek, K. (2020). Hydrogen production by electrolysis. Current Ttrends and Future Developments on (Bio-) Membranes. Department of Inorganic Technology, University of Chemistry and Technology Prague, Czechia.
[15] Schalenbach, M., Kasian, O. and Mayrhofer, K. (2018). An alkaline water electrolyzer with nickel electrodes enables efficient high current density operation. International Journal of Hydrogen Energy, 1-7.
[16] Phillips, R. and Dunnill, C. W. (2019). Zero gap cell design for alkaline electrolysis. A PHD Thesis, Energy Safety Research Institute, Swansea University Prifysgol Abertawe.
[17] De Silva, Y. S. K. and Middleton, P. H. (2020). Design of an alkaline electrolysis stack. Faculty of Engineering and Science, University of Agder.
[18] Chakik, F., Kaddami, M. and Mikou, M. (2017). Effect of operating parameters on hydrogen production by electrolysis of water. Faculty of Science and Technology, University Hassan 1, Settat, Morocco. International Journal of Hydrogen Energy.
[19] Mittelsteadt, C., Norman, T., Rich, M. and Willey, J. (2015). PEM electrolyzers and PEM regenerative fuel cells industrial view. Electrochemical Energy Storage for Renewable Sources and Grid Balancing (159-181). Retrieved from https://www.sciencedirect.com/topics/engineering/electrolyzer-technology on June 27, 2021.
[20] Chisholm, G. and Cronin, L. (2016). Hydrogen from water electrolysis. School of Chemistry, University of Glasgow, United Kingdom. (16) 315-339.
[21] Matmatch (2022). Polytetrafluoroethylene (PTFE) datasheet. Retrieved from https://matmatch.com/materials/mbas023-polytetrafluoroethylene-ptfe- on June 04, 2022.
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Cite This Article
  • APA Style

    Chijindu Ikechukwu Igwe, Chinonso Hubert Achebe, Arinze Everest Chinweze. (2023). Design of an Alkaline Water Electrolyzer for Hydrogen Production. American Journal of Mechanical and Industrial Engineering, 7(6), 89-98. https://doi.org/10.11648/j.ajmie.20220706.12

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    ACS Style

    Chijindu Ikechukwu Igwe; Chinonso Hubert Achebe; Arinze Everest Chinweze. Design of an Alkaline Water Electrolyzer for Hydrogen Production. Am. J. Mech. Ind. Eng. 2023, 7(6), 89-98. doi: 10.11648/j.ajmie.20220706.12

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    AMA Style

    Chijindu Ikechukwu Igwe, Chinonso Hubert Achebe, Arinze Everest Chinweze. Design of an Alkaline Water Electrolyzer for Hydrogen Production. Am J Mech Ind Eng. 2023;7(6):89-98. doi: 10.11648/j.ajmie.20220706.12

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  • @article{10.11648/j.ajmie.20220706.12,
      author = {Chijindu Ikechukwu Igwe and Chinonso Hubert Achebe and Arinze Everest Chinweze},
      title = {Design of an Alkaline Water Electrolyzer for Hydrogen Production},
      journal = {American Journal of Mechanical and Industrial Engineering},
      volume = {7},
      number = {6},
      pages = {89-98},
      doi = {10.11648/j.ajmie.20220706.12},
      url = {https://doi.org/10.11648/j.ajmie.20220706.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmie.20220706.12},
      abstract = {Hydrogen is an excellent energy carrier that is capable of storing excess generated renewable energy. It can be utilised in a fuel cell to produce electrical energy which is a sustainable alternative to conventional energy sources. This paper focuses on the design process of an alkaline water electrolyzer for the production of hydrogen through the electrolysis of water. A single cell, zero-gap, unipolar alkaline water electrolyzer, operating with 30 wt.% KOH solution as electrolyte is designed for a capacity of about 306 g of water. The design of the cell geometry was modified to enable improved hydrogen production. Thermal and stress simulations were performed with Autodesk Inventor Nastran 2019 on some modelled components of the designed electrolyzer cell, with the working temperature at about 80°C to 90°C, while maintaining the operating pressure at about 1.0 bar. Thermal and stress distributions from the results agree with the choice of material for the components, and confirms polytetrafluoroethylene (Teflon), and polypropylene plastic suitable for alkaline electrolyzer construction. Von Mises stress evaluation obtained maximum stress values of 0.143 Mpa and 0.138 Mpa, as well as 0.126 Mpa and 0.157 Mpa, for the endplates and spacers for polytetrafluoroethylene and polypropylene plastics respectively. The stress values are well within the safe limits for both PTFE and PP materials which have yield strength of 35 Mpa and 24 Mpa respectively.},
     year = {2023}
    }
    

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  • TY  - JOUR
    T1  - Design of an Alkaline Water Electrolyzer for Hydrogen Production
    AU  - Chijindu Ikechukwu Igwe
    AU  - Chinonso Hubert Achebe
    AU  - Arinze Everest Chinweze
    Y1  - 2023/01/10
    PY  - 2023
    N1  - https://doi.org/10.11648/j.ajmie.20220706.12
    DO  - 10.11648/j.ajmie.20220706.12
    T2  - American Journal of Mechanical and Industrial Engineering
    JF  - American Journal of Mechanical and Industrial Engineering
    JO  - American Journal of Mechanical and Industrial Engineering
    SP  - 89
    EP  - 98
    PB  - Science Publishing Group
    SN  - 2575-6060
    UR  - https://doi.org/10.11648/j.ajmie.20220706.12
    AB  - Hydrogen is an excellent energy carrier that is capable of storing excess generated renewable energy. It can be utilised in a fuel cell to produce electrical energy which is a sustainable alternative to conventional energy sources. This paper focuses on the design process of an alkaline water electrolyzer for the production of hydrogen through the electrolysis of water. A single cell, zero-gap, unipolar alkaline water electrolyzer, operating with 30 wt.% KOH solution as electrolyte is designed for a capacity of about 306 g of water. The design of the cell geometry was modified to enable improved hydrogen production. Thermal and stress simulations were performed with Autodesk Inventor Nastran 2019 on some modelled components of the designed electrolyzer cell, with the working temperature at about 80°C to 90°C, while maintaining the operating pressure at about 1.0 bar. Thermal and stress distributions from the results agree with the choice of material for the components, and confirms polytetrafluoroethylene (Teflon), and polypropylene plastic suitable for alkaline electrolyzer construction. Von Mises stress evaluation obtained maximum stress values of 0.143 Mpa and 0.138 Mpa, as well as 0.126 Mpa and 0.157 Mpa, for the endplates and spacers for polytetrafluoroethylene and polypropylene plastics respectively. The stress values are well within the safe limits for both PTFE and PP materials which have yield strength of 35 Mpa and 24 Mpa respectively.
    VL  - 7
    IS  - 6
    ER  - 

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Author Information
  • Department of Mechanical Engineering, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Mechanical Engineering, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Mechanical Engineering, Nnamdi Azikiwe University, Awka, Nigeria

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