Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy

Xiao Chen Xu; Ke Qiang Qiu

doi:doi:10.11648/j.es.20210601.12

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Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy

Xiao Chen Xu, Ke Qiang Qiu

Published in Engineering Science (Volume 6, Issue 1)

Received: 3 February 2021 Accepted: 10 February 2021 Published: 27 February 2021

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Abstract

Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al₈₆Ni₁₀Y₄ amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm², the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.

Published in	Engineering Science (Volume 6, Issue 1)
DOI	10.11648/j.es.20210601.12
Page(s)	12-16
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Al-based Amorphous Alloy, Electrocoagulation, Oil Wastewater, COD Removal Rate, Degradation

References

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[3]	Ahmadi S, Sardari E, et al. Removal of oil from biodiesel wastewater by electrocoagulation method [J]. The Korean Journal of Chemical Engineering, 2013, 30 (3): 634-641.
[4]	Sravanth T, Ramesh ST, Gandhimathi R, Nidheesh PV Continuous treatability of oily wastewater from locomotive wash facilities by electrocoagulation. Sep Sci Technol [J]. 2020, 55 (3): 583–589.
[5]	Daghrir R, Drogui P. Electrochemical treatment of domestic wastewater using boron-doped diamond and nanostructured amorphous carbon electrodes [J]. Environmental Science and Pollution Research, 2014, 21 (10): 6578-6589.
[6]	Boopathy R, Trupti D, et al. New approach of integrated advanced oxidation processes for the treatment of lube oil processing wastewater [J]. Arab J Sci Eng 2018, 43 (11): 6229–6236.
[7]	Ahmadi S, Sardari E, Javadian HR, Katal R, Sefti MV. Removal of oil from biodiesel wastewater by electrocoagulation method. Korean J Chem Eng, 2013, 30 (3): 634–641.
[8]	Ma X, Zhou M. A comparative study of azo dye decolorization by electro-Fenton in two common electrolytes. J Chem Technol Biotechnol, 2009, 84 (10): 1 544–1549.
[9]	Gobbi L C A, Nascimento I L, Muniz E P, etal. Electrocoagulation with polarity switch for fast oil removal from oil in water emulsions [J]. Journal of Environmental Management, 2018, 13 (1): 119-125.
[10]	Chen Guangguan, Hu Qi, et al. Electrocoagulation Treatment of Petroleum Cracking Catalyst Wastewater [J]. Journal of environmental engineering, 2015, 9 (10): 4850-4856.
[11]	Swati S, Ahmet A, Halis S. Electrochemical treatment of sunflower oil refinery wastewater and optimization of the parameters using response surface methodology Chemosphere, 2020, 249: 126511.
[12]	Khalifa O, Banat F, Srinivasakannan C, Radjenovic J, Hasan SW Performance tests and removal mechanisms of aerated electrocoagulation in the treatment of oily wastewater. J Water Pro Eng, 2020, 36: 101290.
[13]	Flores N, Brillas E, Centellas F, etal. Treatment of olive oil mill wastewater by single electrocoagulation with different electrodes and sequential electrocoagulation/electrochemical Fenton-based processes [J]. Journal of Hazardous Materials, 2018, 347 (2): 58-66.
[14]	Ting W. P., Huang Y. H., Lu M. C., Catalytic treatment of petrochemical wastewater by electro-assisted Fenton technologies [J]. React. Kinet. Catal. Lett, 2007, 92 (1): 41–48.
[15]	Wang C. T., Hu J. L., etal, Removal of color from real dyeing wastewater by electro-Fenton technology using a three-dimensional graphite cathode [J] J Hazard, Mater. 2008, 152 (10): 601–606.

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APA Style

Xiao Chen Xu, Ke Qiang Qiu. (2021). Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Engineering Science, 6(1), 12-16. https://doi.org/10.11648/j.es.20210601.12

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ACS Style

Xiao Chen Xu; Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng. Sci. 2021, 6(1), 12-16. doi: 10.11648/j.es.20210601.12

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AMA Style

Xiao Chen Xu, Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng Sci. 2021;6(1):12-16. doi: 10.11648/j.es.20210601.12

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@article{10.11648/j.es.20210601.12,
  author = {Xiao Chen Xu and Ke Qiang Qiu},
  title = {Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy},
  journal = {Engineering Science},
  volume = {6},
  number = {1},
  pages = {12-16},
  doi = {10.11648/j.es.20210601.12},
  url = {https://doi.org/10.11648/j.es.20210601.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.es.20210601.12},
  abstract = {Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.},
 year = {2021}
}

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TY  - JOUR
T1  - Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy
AU  - Xiao Chen Xu
AU  - Ke Qiang Qiu
Y1  - 2021/02/27
PY  - 2021
N1  - https://doi.org/10.11648/j.es.20210601.12
DO  - 10.11648/j.es.20210601.12
T2  - Engineering Science
JF  - Engineering Science
JO  - Engineering Science
SP  - 12
EP  - 16
PB  - Science Publishing Group
SN  - 2578-9279
UR  - https://doi.org/10.11648/j.es.20210601.12
AB  - Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.
VL  - 6
IS  - 1
ER  -

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Author Information

Xiao Chen Xu

Material Science and Engineering College, Shenyang University of Technology, Shenyang, China
Ke Qiang Qiu

Material Science and Engineering College, Shenyang University of Technology, Shenyang, China

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APA Style

Xiao Chen Xu, Ke Qiang Qiu. (2021). Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Engineering Science, 6(1), 12-16. https://doi.org/10.11648/j.es.20210601.12

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ACS Style

Xiao Chen Xu; Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng. Sci. 2021, 6(1), 12-16. doi: 10.11648/j.es.20210601.12

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AMA Style

Xiao Chen Xu, Ke Qiang Qiu. Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy. Eng Sci. 2021;6(1):12-16. doi: 10.11648/j.es.20210601.12

Copy | Download

@article{10.11648/j.es.20210601.12,
  author = {Xiao Chen Xu and Ke Qiang Qiu},
  title = {Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy},
  journal = {Engineering Science},
  volume = {6},
  number = {1},
  pages = {12-16},
  doi = {10.11648/j.es.20210601.12},
  url = {https://doi.org/10.11648/j.es.20210601.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.es.20210601.12},
  abstract = {Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Electrocoagulation Degradation of Oily Wastewater by Using Al-based Amorphous Alloy
AU  - Xiao Chen Xu
AU  - Ke Qiang Qiu
Y1  - 2021/02/27
PY  - 2021
N1  - https://doi.org/10.11648/j.es.20210601.12
DO  - 10.11648/j.es.20210601.12
T2  - Engineering Science
JF  - Engineering Science
JO  - Engineering Science
SP  - 12
EP  - 16
PB  - Science Publishing Group
SN  - 2578-9279
UR  - https://doi.org/10.11648/j.es.20210601.12
AB  - Oily wastewater is proven to be common both in industry and home life. A particular contaminant of concern is petroleum hydrocarbon present in various types of wastewater comingfrom shipyards, onshore and offshore industries, and engine rooms of ships. As the standards for oily wastewater treatment become more and more strict, and emulsified oil wastewater is characterized by difficult degradation and high toxicity, we adopt the electrocoagulation technology with Al86Ni10Y4 amorphous alloy as anode and graphite as cathode to treat it to surpass the limitations of conventional methods. The degradation effect on the oily wastewater was characterized by chemical demand oxygen (COD), while the ribbons before and after using were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM) The results show that when the pH value is 3 and the current density is 6.5mA/cm2, the COD removal rate can reach to 75.68% within 100 minutes. Large areas of white corrosion products appear on the surface of the Al-based amorphous alloy after reaction. These protrusions are mainly formed by anodic oxidation corrosion of Al-based amorphous alloy. So, the electrocoagulation technology with amorphous alloy as anode and graphite as cathode is suitable for being utilized to treat the emulsified oil wastewater. And it will have a good practical application prospect.
VL  - 6
IS  - 1
ER  -

Copy | Download