The objective of this work is to study the elimination of Methyl Orange (MO) contained in wastewater, by adsorption on four different adsorbents, produced from peanut shells. To achieve this, the various adsorbents were first produced. The native biosorbent (BN) was obtained from drying, crushing and sieving the peanut shells. The activated biosorbent (BA) was obtained by chemical activation with ortho-phosphoric acid (H3PO4) 10% BN. The activated carbons (CA1 and CA2) were obtained by pyrolysis at 650°C of BN and BA, respectively. The four products were characterized adsorbents and experiments to determine the effects of pH, contact time, of their masses and the concentration of methyl orange in its removal by adsorption was carried out. The results show that the thermal activation of the BN has multiplied its surface area by 11, while chemical activation has multiplied by its specific surface 8. Both treatment (chemical and thermal) have also tripled the micropores of BN. All four adsorbents have a maximum adsorption capacity at pH6. At this pH, the amount of MO adsorbed decreases with increase in its concentration, regardless of the adsorbent used. Likewise, adsorption equilibrium is reached at 3 min on the four adsorbents. The pseudo second order model describes the adsorption kinetics of MO on the four adsorbents. Ultimately, CA1 is found to be the most effective in removing MO from wastewater.
| Published in | Journal of Energy, Environmental & Chemical Engineering (Volume 6, Issue 2) |
| DOI | 10.11648/j.jeece.20210602.12 |
| Page(s) | 37-44 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Peanut Shells, Acid Treatment, Heat Treatment, Biosorbent, Activated Carbon, Methyl Orange, Wastewater
| [1] | Aboua K. N., Soro D. B., Diarra M., Dibi K., N’guettia K. R. K., Traore K. S. 2018. Adsorption of methyl orange on activated carbons in aqueous solutions: influence of activating chemical agent concentration. Afrique Science. 14 (6) 322–331. |
| [2] | Lei Y and Yong-ming L. 2014. The adsorption mechanism of anionic and cationic dyes by Jerusalem artichoke stalk-based mesoporous activated carbon. J. Environ. Chem. Eng. 2. 220-229. |
| [3] | Hildenbrand S., Schmahl F., Wodarz R., Kimmel R., Dartsch P. 1999. Azo dyes and carcinogenic aromatic amines in cell cultures. Int. Arch. Occup. Environ. Health. 72: M052–M056. http://dx.doi.org/10.1007/PL00014217. |
| [4] | Akansha K., Chakraborty D., Sachan S. G. 2019. Decolorization and degradation of methyl orange by Bacillus stratosphericus SCA1007. Biocatal. Agric. Biotechnol. 18, 101044. |
| [5] | Larakeb M., Youcef L., Achour S. 2014. Etude comparative de l’élimination du Zinc par adsorption sur la goethite et sur la bentonite de Maghnia, LARHYSS Journal. 19 (3) 87-100. |
| [6] | Khelifi O., Nacef M., Affoune A. M. 2018a. Nickel (II) adsorption from aqueous solutions by physic-chemically modified sewage sludge, Iranian Journal of Chemistry and Chemical Engineering. 37 (1) 73–87. |
| [7] | Sejie F. and Nadiye-Tabbiruka M. S. 2016. Removal of Methyl Orange (MO) from Water by adsorption onto Modified Local Clay (Kaolinite). Physical Chemistry. 6 (2): 39-48 http://dx.doi.org/10.5923/j.pc.20160602.02 |
| [8] | Fadhil O. H. and Eisa M. Y. 2019. Removal of Methyl Orange from Aqueous Solutions by Adsorption Using Corn Leaves as Adsorbent Material. Journal of Engineering. 55-69 https://doi.org/10.31026/j.eng.2019.04.05 |
| [9] | Alabbad A. E. 2020, Efficient Removal of Methyl Orange from Wastewater by Polymeric Chitosaniso-vanillin. Chemistry Journal. 7, 16-25. http://dx.doi.org/10.2174/1874842202007010016 |
| [10] | Arami M., Limaee N. Y., Mahmoodi N. M., Tabrisi N. S. 2005. Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies, Journal of Colloid and Interface Science. 288 (2). 371-376. |
| [11] | Hazourli S., Ziati M., Hazourli A., Cherifi M. 2007. Valorisation d’un résidu naturel ligno-cellulosique en charbon actif - exemple des noyaux de dattes. Revue des énergies renouvelables, ICRESD 07 Tlemcen, 187-192. |
| [12] | Pekkuz H., Uzun İ., Güzel F. 2008. Kinetics and thermodynamics of the adsorption of some dyestuffs from aqueous solution by poplar sawdust. Bioresource Technology. 99 (6) 2009-2017. |
| [13] | Khelifi O., Mehrez I., Ben Salah W., Ben Salah F., Younsi M., Nacef M., Affoune A. M. 2016. Study of the adsorption of Methylene Blue (BM) from aqueous solutions on a biosorbent prepared from Algerian date stones. LARHYSS Journal. 28 (4). 135-148. |
| [14] | Djonga W. G., Noubissié E., Noumi G. B. 2019. Discoloration test of a slaughterhouse effluent by adsorption on two adsorbents produced from sawdust of Khaya senegalensis and Pinus sp. Results in Engineering. 4. 8pp. https://doi.org/10.1016/j.rineng.2019.100068. |
| [15] | Soudani N., Najar-Souissi S., Ouederni A. 2019. Enhanced adsorption of phenol using alkaline modified activated carbon prepared From olive stones. J. Chil. Chem. Soc. 64 (1). 4352–4359. http://dx.doi.org/10.4067/s0717-97072019000104352. |
| [16] | Battas A, El Gaidoumi A, Ksakas A, Kherbeche A. 2019. Adsorption study for the Removal of Nitrate from water using local clay. The Scientific World Journal. 10 pp. https://doi.org/10.1155/2019/9529618. |
| [17] | Al-Ghouti Mohammad A., Da'ana Dana A. 2020. Guidelines for the use and interpretation of adsorption isotherm models: Areview. Journal of Hazardous Materials. 393 (2020). 22pp. https://doi.org/10.1016/j.jhazmat.2020.122383. |
| [18] | Inyinbor A. A., Adekola F. A., Olatunji G. A. 2016. Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water Resources and Industry. 15 (2016). 14–27. http://dx.doi.org/10.1016/j.wri.2016.06.001. |
| [19] | Zewail T. M., Yousef N. S. 2015. Kinetic study of heavy metal ions removal by ion exchange in batch conical air spouted bed. Alexandria Engineering Journal. 54. 83–90. http://dx.doi.org/10.1016/j.aej.2014.11.008 |
| [20] | Alghamdi A. A., Abdel-Basit Al-Odayni A. B., Saeed W. S., Almutairi M. S., Alharthi F. A., Aouak T., Al-Kahtani A. 2019. Adsorption of Azo Dye Methyl Orange from Aqueous Solutions Using Alkali-Activated Polypyrrole-Based Graphene Oxide. Molecules. 24, 3685 1-17. http://dx.doi.org/10.3390/molecules24203685 |
| [21] | Khelifi O., Mehrez I., Younsi M., Nacef M., Affoune A. M. 2018b. Methyl orange adsorption on biosorbent derived from mango seed kernels. Larhyss Journal. 36. 145-156. |
APA Style
Etienne Yanne, Eric Noubissié, Daniele Kada Benessoubo, Marie Charlène Eko. (2021). Physico-chemical Study of the Adsorption of Methyl Orange from Water by Biosorbent and Activated Carbon Based on Peanut Shells. Journal of Energy, Environmental & Chemical Engineering, 6(2), 37-44. https://doi.org/10.11648/j.jeece.20210602.12
ACS Style
Etienne Yanne; Eric Noubissié; Daniele Kada Benessoubo; Marie Charlène Eko. Physico-chemical Study of the Adsorption of Methyl Orange from Water by Biosorbent and Activated Carbon Based on Peanut Shells. J. Energy Environ. Chem. Eng. 2021, 6(2), 37-44. doi: 10.11648/j.jeece.20210602.12
AMA Style
Etienne Yanne, Eric Noubissié, Daniele Kada Benessoubo, Marie Charlène Eko. Physico-chemical Study of the Adsorption of Methyl Orange from Water by Biosorbent and Activated Carbon Based on Peanut Shells. J Energy Environ Chem Eng. 2021;6(2):37-44. doi: 10.11648/j.jeece.20210602.12
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.jeece.20210602.12,
author = {Etienne Yanne and Eric Noubissié and Daniele Kada Benessoubo and Marie Charlène Eko},
title = {Physico-chemical Study of the Adsorption of Methyl Orange from Water by Biosorbent and Activated Carbon Based on Peanut Shells},
journal = {Journal of Energy, Environmental & Chemical Engineering},
volume = {6},
number = {2},
pages = {37-44},
doi = {10.11648/j.jeece.20210602.12},
url = {https://doi.org/10.11648/j.jeece.20210602.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20210602.12},
abstract = {The objective of this work is to study the elimination of Methyl Orange (MO) contained in wastewater, by adsorption on four different adsorbents, produced from peanut shells. To achieve this, the various adsorbents were first produced. The native biosorbent (BN) was obtained from drying, crushing and sieving the peanut shells. The activated biosorbent (BA) was obtained by chemical activation with ortho-phosphoric acid (H3PO4) 10% BN. The activated carbons (CA1 and CA2) were obtained by pyrolysis at 650°C of BN and BA, respectively. The four products were characterized adsorbents and experiments to determine the effects of pH, contact time, of their masses and the concentration of methyl orange in its removal by adsorption was carried out. The results show that the thermal activation of the BN has multiplied its surface area by 11, while chemical activation has multiplied by its specific surface 8. Both treatment (chemical and thermal) have also tripled the micropores of BN. All four adsorbents have a maximum adsorption capacity at pH6. At this pH, the amount of MO adsorbed decreases with increase in its concentration, regardless of the adsorbent used. Likewise, adsorption equilibrium is reached at 3 min on the four adsorbents. The pseudo second order model describes the adsorption kinetics of MO on the four adsorbents. Ultimately, CA1 is found to be the most effective in removing MO from wastewater.},
year = {2021}
}
TY - JOUR T1 - Physico-chemical Study of the Adsorption of Methyl Orange from Water by Biosorbent and Activated Carbon Based on Peanut Shells AU - Etienne Yanne AU - Eric Noubissié AU - Daniele Kada Benessoubo AU - Marie Charlène Eko Y1 - 2021/07/21 PY - 2021 N1 - https://doi.org/10.11648/j.jeece.20210602.12 DO - 10.11648/j.jeece.20210602.12 T2 - Journal of Energy, Environmental & Chemical Engineering JF - Journal of Energy, Environmental & Chemical Engineering JO - Journal of Energy, Environmental & Chemical Engineering SP - 37 EP - 44 PB - Science Publishing Group SN - 2637-434X UR - https://doi.org/10.11648/j.jeece.20210602.12 AB - The objective of this work is to study the elimination of Methyl Orange (MO) contained in wastewater, by adsorption on four different adsorbents, produced from peanut shells. To achieve this, the various adsorbents were first produced. The native biosorbent (BN) was obtained from drying, crushing and sieving the peanut shells. The activated biosorbent (BA) was obtained by chemical activation with ortho-phosphoric acid (H3PO4) 10% BN. The activated carbons (CA1 and CA2) were obtained by pyrolysis at 650°C of BN and BA, respectively. The four products were characterized adsorbents and experiments to determine the effects of pH, contact time, of their masses and the concentration of methyl orange in its removal by adsorption was carried out. The results show that the thermal activation of the BN has multiplied its surface area by 11, while chemical activation has multiplied by its specific surface 8. Both treatment (chemical and thermal) have also tripled the micropores of BN. All four adsorbents have a maximum adsorption capacity at pH6. At this pH, the amount of MO adsorbed decreases with increase in its concentration, regardless of the adsorbent used. Likewise, adsorption equilibrium is reached at 3 min on the four adsorbents. The pseudo second order model describes the adsorption kinetics of MO on the four adsorbents. Ultimately, CA1 is found to be the most effective in removing MO from wastewater. VL - 6 IS - 2 ER -
Information
Email: