Research Article | | Peer-Reviewed

Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds

Received: 3 January 2024    Accepted: 15 January 2024    Published: 1 February 2024
Views:       Downloads:
Abstract

Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.

Published in Science Frontiers (Volume 5, Issue 1)
DOI 10.11648/sf.20240501.13
Page(s) 13-23
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Synthetic Organic Compounds, Chemical Oxygen Demand, Adsorption, Nipa Palm, Carbonized Carbon, Wastewater

References
[1] Adowei, P. Spiff, A. I. & Abia, A. A. (2014). Evaluation of Carbonized and Surface-Modified Carbon Produced from Nipa Palm (Nypa Fruiticans Wurmb) Leaves for the Removal of 2-(N,N-Dimethyl-4-aminophenyl)-azo-benzene carboxylic acid (DMABA) in Aqueous Solution Acta Chim. Pharm. Indica: 4(3), 2014, 146-156.
[2] Adowei, P; Abia, A. A; & Spiff, A. I (2015). Physicochemical Characteristics of Biocarbons obtained from Nipa Palm (Nypa Fruiticans Wurmb) Leaves. Research. Journal of Chemical Sciences. Volume 5 No. 1, pp 18-26.
[3] Adowei, P; Wariboko, E & Markmanuel, D, (2020). Removal of Low concentration of. Kerosene from water using Nipa paim (Nypa Fruticans Wurmb) fruit fibre. International Journal of Research Volume 8 No. 6 pp 1-9.
[4] Adowei, P; & Abia A. A (2016). Chemical Oxygen Demand (COD) Attenuation of Methyl Red in Water using Biocarbons obtained from Nipa palm (Nypa fruticans Wurmb) Leaves. Journal of Applied Sciences & Environmental Management. Volume 20 No. 4 pp 1163-1176.
[5] Abia, A. A., Horsfall, M. Jnr & Didi, O (2003). The Use of Chemically Modified and Unmodified Cassava Waste for the Removal of Cd, Cu and Zn ions from Aqueous Solution. Bioresource Techno. 90 345–348.
[6] Verla, A. W; Adowei, Pereware; & Verla, E. N. (2014). Physicochemical and Microbiological Characteristic of Palm Oil Mill Effluent (POME) in Nguru - Aboh Mbaise, Eastern Nigeria Acta Chimica. Pharmaceutica. Indica: 4(3), 2014, 119-125.
[7] Horsfall, M. Jnr & Abia, A. A (2003). Sorption of Cd (II) and Zn (II) ions from Aqueous solutions by Cassava Waste Biomass (Manihot sculenta Cranz). Wat. Res. 37: 4913–4923.
[8] Epkete, O. A; Spiff, A. I; Horsfall, M. Jnr; & Adowei, Pereware. (2012). Adsorption of Phenol and Chlorophenol in aqueous solution on a commercial activated carbon in batch sorption systems. Innovations in Science and Engineering. 2(2) 72-78.
[9] Horsfall, M. Jnr.; Spiff, A. I. & Abia, A. A. (2004). Studies on the Influence of Mercaptoacetic Acid (MAA) Modification of Cassava (Manihot esculenta Cranz) Waste Biomass on the Adsorption of Cu2+ and Cd2+ from Aqueous Solution. Bull. Korean Chem. Soc. Vol. 25(7), 969–976.
[10] Horsfall, M. Jnr & Spiff, A. I. (2005) a. Effect of metal ion concentration on the biosorption of Pb2+ and Cd2+ by Caladium bicolor (wild cocoyam). African J. of Biotech. Vol. 4(2) pp 191-196.
[11] Abechi, S. E, Gimba, C E, Uzairu, A, & Dallatu, Y A (2013). Preparation and Characterization of activated carbon from Palm Kernel Shell by Chemical Activation. Research Journal of Chemical Sciences. 3(7) 54-61.
[12] Adinata, D, Wan Daud WMA, Aroua MK. (2007) Preparation and characterization of activated carbon from palm shell by chemical activation with K2CO3. Bioresource Technology 98: 145-49.
[13] Fadini, Pedro Sérgio; Jardim, Wilson F.; Guimarães, & José Roberto (2004). Evaluation of Organic Load Measurement Techniques in a Sewage and Waste Stabilisation Pond. J. Braz. Chem. Soc., 15(1): 131-135.
[14] Ademiluyi, F T; & Braide, O (2012). Effectiveness of Nigerian Bamboo Activated with Different Activating Agents on the Adsorption of BTX. Journal of Appl. Sci. Environ. Manage. 16(3) 267–273.
[15] Adowei, P; Abia, A. A; & Okorosaye-Orubite, K (2017). Study of kerosene elimination in water by steam-modified and acid-modified carbons made from nipa palm (Nypa Fruiticans Wurmb) leaves. Journal, Chemical Society of Nigeria. Volume 42, No. 1 pp 75-8.
[16] Gimba C, Ocholi O, & Nok A. (2004). Preparation of A. C from Agricultural wastes II. Cyanide binding with activated carbon matrix from groundnut shell. Nigerian journal of scientific research. Bioresour. Technol. 97, 401-406.
[17] Fan, M., Marshall, W., Daugaard, D., & Brown, R. C., (2003), Steam activation of chars produced from oat hulls and cornstover, Bioresource Technol., 93, 103–117.
[18] Itodo A. U., Abdulrahman F. W., Hassan L. G, Maigandi S. A., & Itodo H. U. (2010). Physicochemical parameters of Adsorbents from locally sorted H3PO4 and ZnCl2 modified Agricultural wastes (Groundnut shells, Shea nut shells, Poultry wastes and Poultry droppings). New York Science Journal 3(5) 17–24.
[19] Ash B, Satapathy D, Mukherjee PS, Nanda B, Gumaste JL, & Mishra BK, (2006). Characterization and application of activated carbon prepared from coir pith. J. Sci. Ind. Res. 65 1008-1012.
[20] Sugumaran, P, Priya. S. V, Ravichandran, P. & Seshadri, S (2012). Production and Characterization of Activated Carbon from Banana Empty Fruit Bunch and Delonix regia Fruit Pod. Journal of Sustainable Energy & Environment 3: 125-132.
[21] Ahmedna M, Marshal W, & Rao M. (2000). Production of Granular activated carbon from selected Agriculture by products. Bioresource and Technology. 71(2): 113–123.
[22] Wayne Boyles (1997). The Science of Chemical Oxygen Demand (COD). Technical Information Series, Booklet No. 9. Pp8-9.
[23] Horsfall, M. Jnr., Abia, A. A.; & Spiff, A. I. (2006). Kinetic studies of Adsorption of Cd2+, Cu2+, and Zn2+ ions from Aqueous solutions by cassava (Manihot sculenta Cranz) tuber bark waste. Bio Resource Tech. 97, pp 283–291.
[24] Ekpete, O. A. & Horsfall, M. Jnr (2011). Preparation and Characterization of Activated Carbon derived from Fluted Pumpkin Stem Waste (Telfairia occidentalis Hook F). Research Journal of Chemical Sciences. Vol. 1(3) June 2011 10-17.
[25] Wankasi, D., Horsfall, M. Jnr; & Spiff, A. I., (2005). Desorption of Pb2+ and Cu2+ from Nipa palm (Nypa fruticans Wurmb) biomass. Afr. J. Biotechnol. 4, 923-927.
[26] Horsfall, M. Jnr; & Spiff, A. I. (2005) b. Effect of Temperature on the Sorption of Pb2+ and Cu2+ from Aqueous Solution by Caladium bicolor (Wild Cocoyam) Biomass. Electronic Jour. Of Biotech. Vol. 8(2); pp 162-169.
[27] Poots, V. J. P., G. Mackay & J. J. Healy, (1978). Removal of basic dye from effluent using wood as an adsorbent. J. Water Pollut. Control Federation, 50: 926-935.
[28] Tarawou, T; Wankasi, D; & Horsfall, M (2010). Sorption kinetic study on the removal of basic blue-9 dye using activated carbon produced from water spinach. Int. J, Biol. Chem. Sci. 4. (3). 703–709.
Cite This Article
  • APA Style

    Adowei, P. (2024). Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Science Frontiers, 5(1), 13-23. https://doi.org/10.11648/sf.20240501.13

    Copy | Download

    ACS Style

    Adowei, P. Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Sci. Front. 2024, 5(1), 13-23. doi: 10.11648/sf.20240501.13

    Copy | Download

    AMA Style

    Adowei P. Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds. Sci Front. 2024;5(1):13-23. doi: 10.11648/sf.20240501.13

    Copy | Download

  • @article{10.11648/sf.20240501.13,
      author = {Pereware Adowei},
      title = {Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds},
      journal = {Science Frontiers},
      volume = {5},
      number = {1},
      pages = {13-23},
      doi = {10.11648/sf.20240501.13},
      url = {https://doi.org/10.11648/sf.20240501.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.sf.20240501.13},
      abstract = {Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.
    },
     year = {2024}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Adsorptive Removal of Synthetic Organic Compounds in Aqueous Solutions by Fresh Nipa Palm Fronds
    AU  - Pereware Adowei
    Y1  - 2024/02/01
    PY  - 2024
    N1  - https://doi.org/10.11648/sf.20240501.13
    DO  - 10.11648/sf.20240501.13
    T2  - Science Frontiers
    JF  - Science Frontiers
    JO  - Science Frontiers
    SP  - 13
    EP  - 23
    PB  - Science Publishing Group
    SN  - 2994-7030
    UR  - https://doi.org/10.11648/sf.20240501.13
    AB  - Adsorptive removal of contaminants in wastewater is distinctive because the technique is simple, effective and with low cost, however, the flexibility of the adsorption process is actually contingent on the sorption abilities of the adsorbent. Nipa palm has been tested in several studies to be effective due to its porous structure and surface properties. Hence, the objective of this paper was to evaluate the adsorptive removal of synthetic organic compounds (SOCs) in aqueous solutions using carbonized and surface-modified carbons produced from Nipa Palm (Nypa Fruticans Wurmb) fronds using chemical oxygen demand (COD) as the index of measurement. Data obtained for the present investigation revealed that percent COD reduction of SOCs by the carbons ranged between 93.81 – 96.67%, while COD reduction capacity estimated by Langmuir-type model was between 1.77 - 11.83 mg/g at ambient temperature and at an optimum pH of 8.5. Thermodynamic assessment by Gibbs free energy (∆Go, KJ/mol) revealed that ∆Go values were negative (from - 1.45 KJ/mol to - 5.89 KJ/mol). The results obtained show that Nipa palm could be a beneficial source for the development of an eco-friendly and locally available activated carbon for removal of organic contaminants from domestic and industrial wastewaters.
    
    VL  - 5
    IS  - 1
    ER  - 

    Copy | Download

Author Information
  • Department of Pure and Industrial Chemistry, University of Port Harcourt, Port Harcourt, Nigeria

  • Sections