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Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System

Received: 05 July 2014    Accepted: 08 August 2014    Published: 20 August 2014
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Abstract

An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.

DOI 10.11648/j.ijmsa.20140304.12
Published in International Journal of Materials Science and Applications (Volume 3, Issue 4, July 2014)
Page(s) 129-136
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

PVA: PVK Blend, CH3COONH4, PVK Based Electrolyte, Ion- Electron Conductor, Polymer Composite Electrolyte

References
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Author Information
  • SSI Laboratory Department of Physics, A P S University, Rewa India

  • Department of Physics, Govt. Maharaja College, Chhatarpur India

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  • APA Style

    Shanker Lal Agrawal, Rajendra Prasad Kumhar. (2014). Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. International Journal of Materials Science and Applications, 3(4), 129-136. https://doi.org/10.11648/j.ijmsa.20140304.12

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    ACS Style

    Shanker Lal Agrawal; Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int. J. Mater. Sci. Appl. 2014, 3(4), 129-136. doi: 10.11648/j.ijmsa.20140304.12

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    AMA Style

    Shanker Lal Agrawal, Rajendra Prasad Kumhar. Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System. Int J Mater Sci Appl. 2014;3(4):129-136. doi: 10.11648/j.ijmsa.20140304.12

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  • @article{10.11648/j.ijmsa.20140304.12,
      author = {Shanker Lal Agrawal and Rajendra Prasad Kumhar},
      title = {Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System},
      journal = {International Journal of Materials Science and Applications},
      volume = {3},
      number = {4},
      pages = {129-136},
      doi = {10.11648/j.ijmsa.20140304.12},
      url = {https://doi.org/10.11648/j.ijmsa.20140304.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijmsa.20140304.12},
      abstract = {An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.},
     year = {2014}
    }
    

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    AU  - Shanker Lal Agrawal
    AU  - Rajendra Prasad Kumhar
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    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
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    AB  - An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.
    VL  - 3
    IS  - 4
    ER  - 

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