Journal of Food and Nutrition Sciences

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Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia

Received: 02 June 2014    Accepted: 12 June 2014    Published: 30 June 2014
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Abstract

The present study investigates pesticide residues in samples of fresh and processed fruits and vegetables produced in Republic of Macedonia. Investigations were carried out as a part of the National Monitoring Programme under the recommendations of the European Food Safety Authority (EFSA). From September 2012 to June 2013, a total of 168 samples of different fresh vegetables: tomato, paprika, cucumber, potato, onion, carrot, cabbage; processed vegetables: pasteurized paprika, ketchup; fresh fruits: apple, acid cherry, table grapes and wine grapes; processed fruits: jams and canned fruits were tested on the presence of 33 pesticide residues. The QuEChERS procedure was used for sample preparation, except for dithiocarabamates and gas chromatography – mass spectrometry (GC-MS) and liquid chromatography – tandem mass spectrometry (LC-MS/MS) techniques were applied for pesticide residues identification and determination. The results of the study showed that cucumber was the crop with the highest number of pesticide residues with the predominant presence of methomyl, (0.015-0.21 mg/kg), metalaxyl (0.04-0.16 mg/kg), and imidacloprid (0.017-0.036 mg/kg). Only two samples (1.19% of the total samples) contained one pesticide residue above the Maximum Residues Levels (MRLs). The results of the current study showed that 98.8% of the tested samples contained residues below the MRLs.

DOI 10.11648/j.jfns.20140204.15
Published in Journal of Food and Nutrition Sciences (Volume 2, Issue 4, July 2014)
Page(s) 124-129
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Pesticide Residues, Fungicides, Insecticides, GC-MS, LC-MS/MS

References
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[13] B. Kmellar, P. Fodor, L. Pareja, C. Ferrer, M.A.; Marti-nez-Uroz, A. Valverde and A.R Fernandez-Alba, “Validation and uncertainty study of a compre-hensive list of 160 pesticide residues in multi – class vegetables by liquid chromatography – tan-dem mass spectrometry,” Journal of Chromatography A., vol. 1215, pp. 37-50, 2008
[14] H. Baša Česnik and A Gregorčič, “Validation of the method for the determination of dithiocarba-mates and thiuram disulphide on apple, lettuce, potato, strawberry and tomato matrix,” Acta Chimica Slovenica, vol. 53 (1), pp. 100-104, 2006.
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Author Information
  • Faculty of Medical Science, Department of Pharmacy, University “Goce Delchev”, Shtip, Republic of Macedonia

  • Faculty of Medical Science, Department of Pharmacy, University “Goce Delchev”, Shtip, Republic of Macedonia

  • Department of Pharmacy, University Goce Delchev, Shtip, Republic of Macedonia

  • Faculty of Pharmacy, University of “Ss Cyril and Methodius”, Skopje, Republic of Macedonia

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    Vesna Kostik, Bistra Angelovska, Evgenija Kiroska-Petreska, Biljana Bauer. (2014). Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia. Journal of Food and Nutrition Sciences, 2(4), 124-129. https://doi.org/10.11648/j.jfns.20140204.15

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    ACS Style

    Vesna Kostik; Bistra Angelovska; Evgenija Kiroska-Petreska; Biljana Bauer. Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia. J. Food Nutr. Sci. 2014, 2(4), 124-129. doi: 10.11648/j.jfns.20140204.15

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    AMA Style

    Vesna Kostik, Bistra Angelovska, Evgenija Kiroska-Petreska, Biljana Bauer. Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia. J Food Nutr Sci. 2014;2(4):124-129. doi: 10.11648/j.jfns.20140204.15

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  • @article{10.11648/j.jfns.20140204.15,
      author = {Vesna Kostik and Bistra Angelovska and Evgenija Kiroska-Petreska and Biljana Bauer},
      title = {Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia},
      journal = {Journal of Food and Nutrition Sciences},
      volume = {2},
      number = {4},
      pages = {124-129},
      doi = {10.11648/j.jfns.20140204.15},
      url = {https://doi.org/10.11648/j.jfns.20140204.15},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.jfns.20140204.15},
      abstract = {The present study investigates pesticide residues in samples of fresh and processed fruits and vegetables produced in Republic of Macedonia. Investigations were carried out as a part of the National Monitoring Programme under the recommendations of the European Food Safety Authority (EFSA). From September 2012 to June 2013, a total of 168 samples of different fresh vegetables: tomato, paprika, cucumber, potato, onion, carrot, cabbage; processed vegetables: pasteurized paprika, ketchup; fresh fruits: apple, acid cherry, table grapes and wine grapes; processed fruits: jams and canned fruits were tested on the presence of 33 pesticide residues. The QuEChERS procedure was used for sample preparation, except for dithiocarabamates and gas chromatography – mass spectrometry (GC-MS) and liquid chromatography – tandem mass spectrometry (LC-MS/MS) techniques were applied for pesticide residues identification and determination. The results of the study showed that cucumber was the crop with the highest number of pesticide residues with the predominant presence of methomyl, (0.015-0.21 mg/kg), metalaxyl (0.04-0.16 mg/kg), and imidacloprid (0.017-0.036 mg/kg). Only two samples (1.19% of the total samples) contained one pesticide residue above the Maximum Residues Levels (MRLs). The results of the current study showed that 98.8% of the tested samples contained residues below the MRLs.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Determination of Pesticide Residues in Plant-Based Foods from the Republic of Macedonia
    AU  - Vesna Kostik
    AU  - Bistra Angelovska
    AU  - Evgenija Kiroska-Petreska
    AU  - Biljana Bauer
    Y1  - 2014/06/30
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    N1  - https://doi.org/10.11648/j.jfns.20140204.15
    DO  - 10.11648/j.jfns.20140204.15
    T2  - Journal of Food and Nutrition Sciences
    JF  - Journal of Food and Nutrition Sciences
    JO  - Journal of Food and Nutrition Sciences
    SP  - 124
    EP  - 129
    PB  - Science Publishing Group
    SN  - 2330-7293
    UR  - https://doi.org/10.11648/j.jfns.20140204.15
    AB  - The present study investigates pesticide residues in samples of fresh and processed fruits and vegetables produced in Republic of Macedonia. Investigations were carried out as a part of the National Monitoring Programme under the recommendations of the European Food Safety Authority (EFSA). From September 2012 to June 2013, a total of 168 samples of different fresh vegetables: tomato, paprika, cucumber, potato, onion, carrot, cabbage; processed vegetables: pasteurized paprika, ketchup; fresh fruits: apple, acid cherry, table grapes and wine grapes; processed fruits: jams and canned fruits were tested on the presence of 33 pesticide residues. The QuEChERS procedure was used for sample preparation, except for dithiocarabamates and gas chromatography – mass spectrometry (GC-MS) and liquid chromatography – tandem mass spectrometry (LC-MS/MS) techniques were applied for pesticide residues identification and determination. The results of the study showed that cucumber was the crop with the highest number of pesticide residues with the predominant presence of methomyl, (0.015-0.21 mg/kg), metalaxyl (0.04-0.16 mg/kg), and imidacloprid (0.017-0.036 mg/kg). Only two samples (1.19% of the total samples) contained one pesticide residue above the Maximum Residues Levels (MRLs). The results of the current study showed that 98.8% of the tested samples contained residues below the MRLs.
    VL  - 2
    IS  - 4
    ER  - 

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