Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS

Decong Hu; Xiaozhong Hu; Wei Chen; Hong Wang; Kuanzheng Zhu; Bin Wu; Changjun Lin

doi:doi:10.11648/j.sjac.20150306.12

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Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS

Decong Hu, Xiaozhong Hu, Wei Chen, Hong Wang, Kuanzheng Zhu, Bin Wu, Changjun Lin

Received: 16 September 2015 Accepted: 4 October 2015 Published: 23 October 2015

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Abstract

In this paper, the method of simultaneous determinations of methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in dairy products from China was investigated. PBDEs are widely used brominated flame retardant, which are increasingly reported in the environment. MeO-PBDEs are structural analogs to PBDEs, and reported as natural products and novel pollutants present in the environment. A new isotopic dilution GC-MS method was firstly developed to simultaneously determine fourteen PBDEs and eight MeO-PBDEs in dairy products (full cream milk powder, skim milk powder, pure milk and acidophilus milk) in this study. Solvent extraction, gel permeation chromatography (GPC) and silica gel column cleanup were used, some important steps and crucial parameters were modified and intensified compared with other literatures. Besides, the conditions of GC and MS were also optimized. The limits of quantitation values of 1-50, 4-20 μg kg^-1 in full cream milk powders, skim milk powders, pure milks and acidophilus milks were calculated for PBDEs and MeO-PBDEs. In addition, good repeatability and accuracy of the whole method were achieved. Moreover, Eighteen kinds of commercial full cream milk powder samples, sixteen skim milk powder samples, twenty pure milk samples and fifteen acidophilus milk samples were collected from local supermarket in Wuhan, Hubei province. These samples were analyzed to determine whether these samples were contaminated by PBDEs and MeO-PBDEs. The method was successfully applied to determine methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in these dairy products. Using the established methods, PBDEs and MeO-PBDEs were not detected in all samples.

DOI	10.11648/j.sjac.20150306.12
Published in	Science Journal of Analytical Chemistry (Volume 3, Issue 6, November 2015)
Page(s)	80-90
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

MeO-PBDEs, PBDEs, Dairy Products, Isotopic Dilution, GC-MS

References

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APA Style

Decong Hu, Xiaozhong Hu, Wei Chen, Hong Wang, Kuanzheng Zhu, et al. (2015). Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Science Journal of Analytical Chemistry, 3(6), 80-90. https://doi.org/10.11648/j.sjac.20150306.12

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ACS Style

Decong Hu; Xiaozhong Hu; Wei Chen; Hong Wang; Kuanzheng Zhu, et al. Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Sci. J. Anal. Chem. 2015, 3(6), 80-90. doi: 10.11648/j.sjac.20150306.12

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AMA Style

Decong Hu, Xiaozhong Hu, Wei Chen, Hong Wang, Kuanzheng Zhu, et al. Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Sci J Anal Chem. 2015;3(6):80-90. doi: 10.11648/j.sjac.20150306.12

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@article{10.11648/j.sjac.20150306.12,
  author = {Decong Hu and Xiaozhong Hu and Wei Chen and Hong Wang and Kuanzheng Zhu and Bin Wu and Changjun Lin},
  title = {Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS},
  journal = {Science Journal of Analytical Chemistry},
  volume = {3},
  number = {6},
  pages = {80-90},
  doi = {10.11648/j.sjac.20150306.12},
  url = {https://doi.org/10.11648/j.sjac.20150306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20150306.12},
  abstract = {In this paper, the method of simultaneous determinations of methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in dairy products from China was investigated. PBDEs are widely used brominated flame retardant, which are increasingly reported in the environment. MeO-PBDEs are structural analogs to PBDEs, and reported as natural products and novel pollutants present in the environment. A new isotopic dilution GC-MS method was firstly developed to simultaneously determine fourteen PBDEs and eight MeO-PBDEs in dairy products (full cream milk powder, skim milk powder, pure milk and acidophilus milk) in this study. Solvent extraction, gel permeation chromatography (GPC) and silica gel column cleanup were used, some important steps and crucial parameters were modified and intensified compared with other literatures. Besides, the conditions of GC and MS were also optimized. The limits of quantitation values of 1-50, 4-20 μg kg-1 in full cream milk powders, skim milk powders, pure milks and acidophilus milks were calculated for PBDEs and MeO-PBDEs. In addition, good repeatability and accuracy of the whole method were achieved. Moreover, Eighteen kinds of commercial full cream milk powder samples, sixteen skim milk powder samples, twenty pure milk samples and fifteen acidophilus milk samples were collected from local supermarket in Wuhan, Hubei province. These samples were analyzed to determine whether these samples were contaminated by PBDEs and MeO-PBDEs. The method was successfully applied to determine methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in these dairy products. Using the established methods, PBDEs and MeO-PBDEs were not detected in all samples.},
 year = {2015}
}

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TY  - JOUR
T1  - Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS
AU  - Decong Hu
AU  - Xiaozhong Hu
AU  - Wei Chen
AU  - Hong Wang
AU  - Kuanzheng Zhu
AU  - Bin Wu
AU  - Changjun Lin
Y1  - 2015/10/23
PY  - 2015
N1  - https://doi.org/10.11648/j.sjac.20150306.12
DO  - 10.11648/j.sjac.20150306.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 80
EP  - 90
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20150306.12
AB  - In this paper, the method of simultaneous determinations of methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in dairy products from China was investigated. PBDEs are widely used brominated flame retardant, which are increasingly reported in the environment. MeO-PBDEs are structural analogs to PBDEs, and reported as natural products and novel pollutants present in the environment. A new isotopic dilution GC-MS method was firstly developed to simultaneously determine fourteen PBDEs and eight MeO-PBDEs in dairy products (full cream milk powder, skim milk powder, pure milk and acidophilus milk) in this study. Solvent extraction, gel permeation chromatography (GPC) and silica gel column cleanup were used, some important steps and crucial parameters were modified and intensified compared with other literatures. Besides, the conditions of GC and MS were also optimized. The limits of quantitation values of 1-50, 4-20 μg kg-1 in full cream milk powders, skim milk powders, pure milks and acidophilus milks were calculated for PBDEs and MeO-PBDEs. In addition, good repeatability and accuracy of the whole method were achieved. Moreover, Eighteen kinds of commercial full cream milk powder samples, sixteen skim milk powder samples, twenty pure milk samples and fifteen acidophilus milk samples were collected from local supermarket in Wuhan, Hubei province. These samples were analyzed to determine whether these samples were contaminated by PBDEs and MeO-PBDEs. The method was successfully applied to determine methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in these dairy products. Using the established methods, PBDEs and MeO-PBDEs were not detected in all samples.
VL  - 3
IS  - 6
ER  -

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Author Information

Decong Hu

Hubei Entry-Exit Inspection and Quarantine Bureau of PRC, Wuhan, China; China Certification & Inspection Group HuBei Co., Ltd, Wuhan, China
Xiaozhong Hu

Hubei Entry-Exit Inspection and Quarantine Bureau of PRC, Wuhan, China; China Certification & Inspection Group HuBei Co., Ltd, Wuhan, China
Wei Chen

Hubei Entry-Exit Inspection and Quarantine Bureau of PRC, Wuhan, China; China Certification & Inspection Group HuBei Co., Ltd, Wuhan, China
Hong Wang

Hubei Provincial Supervision and Inspection Research Institute for Products Quality, Wuhan, China
Kuanzheng Zhu

Hubei Provincial Supervision and Inspection Research Institute for Products Quality, Wuhan, China
Bin Wu

Technology Center of Liaoning Entry-Exit Inspection and Quarantine Bureau of PRC, Changjiang Dalian, China
Changjun Lin

Technology Center of Liaoning Entry-Exit Inspection and Quarantine Bureau of PRC, Changjiang Dalian, China

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APA Style

Decong Hu, Xiaozhong Hu, Wei Chen, Hong Wang, Kuanzheng Zhu, et al. (2015). Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Science Journal of Analytical Chemistry, 3(6), 80-90. https://doi.org/10.11648/j.sjac.20150306.12

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ACS Style

Decong Hu; Xiaozhong Hu; Wei Chen; Hong Wang; Kuanzheng Zhu, et al. Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Sci. J. Anal. Chem. 2015, 3(6), 80-90. doi: 10.11648/j.sjac.20150306.12

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AMA Style

Decong Hu, Xiaozhong Hu, Wei Chen, Hong Wang, Kuanzheng Zhu, et al. Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS. Sci J Anal Chem. 2015;3(6):80-90. doi: 10.11648/j.sjac.20150306.12

Copy | Download

@article{10.11648/j.sjac.20150306.12,
  author = {Decong Hu and Xiaozhong Hu and Wei Chen and Hong Wang and Kuanzheng Zhu and Bin Wu and Changjun Lin},
  title = {Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS},
  journal = {Science Journal of Analytical Chemistry},
  volume = {3},
  number = {6},
  pages = {80-90},
  doi = {10.11648/j.sjac.20150306.12},
  url = {https://doi.org/10.11648/j.sjac.20150306.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20150306.12},
  abstract = {In this paper, the method of simultaneous determinations of methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in dairy products from China was investigated. PBDEs are widely used brominated flame retardant, which are increasingly reported in the environment. MeO-PBDEs are structural analogs to PBDEs, and reported as natural products and novel pollutants present in the environment. A new isotopic dilution GC-MS method was firstly developed to simultaneously determine fourteen PBDEs and eight MeO-PBDEs in dairy products (full cream milk powder, skim milk powder, pure milk and acidophilus milk) in this study. Solvent extraction, gel permeation chromatography (GPC) and silica gel column cleanup were used, some important steps and crucial parameters were modified and intensified compared with other literatures. Besides, the conditions of GC and MS were also optimized. The limits of quantitation values of 1-50, 4-20 μg kg-1 in full cream milk powders, skim milk powders, pure milks and acidophilus milks were calculated for PBDEs and MeO-PBDEs. In addition, good repeatability and accuracy of the whole method were achieved. Moreover, Eighteen kinds of commercial full cream milk powder samples, sixteen skim milk powder samples, twenty pure milk samples and fifteen acidophilus milk samples were collected from local supermarket in Wuhan, Hubei province. These samples were analyzed to determine whether these samples were contaminated by PBDEs and MeO-PBDEs. The method was successfully applied to determine methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in these dairy products. Using the established methods, PBDEs and MeO-PBDEs were not detected in all samples.},
 year = {2015}
}

Copy | Download

TY  - JOUR
T1  - Simultaneous Determinations of Methoxylated Polybrominated Diphenyl Ethers and Polybrominated Diphenyl Ethers in Dairy Products from China by GC-MS
AU  - Decong Hu
AU  - Xiaozhong Hu
AU  - Wei Chen
AU  - Hong Wang
AU  - Kuanzheng Zhu
AU  - Bin Wu
AU  - Changjun Lin
Y1  - 2015/10/23
PY  - 2015
N1  - https://doi.org/10.11648/j.sjac.20150306.12
DO  - 10.11648/j.sjac.20150306.12
T2  - Science Journal of Analytical Chemistry
JF  - Science Journal of Analytical Chemistry
JO  - Science Journal of Analytical Chemistry
SP  - 80
EP  - 90
PB  - Science Publishing Group
SN  - 2376-8053
UR  - https://doi.org/10.11648/j.sjac.20150306.12
AB  - In this paper, the method of simultaneous determinations of methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in dairy products from China was investigated. PBDEs are widely used brominated flame retardant, which are increasingly reported in the environment. MeO-PBDEs are structural analogs to PBDEs, and reported as natural products and novel pollutants present in the environment. A new isotopic dilution GC-MS method was firstly developed to simultaneously determine fourteen PBDEs and eight MeO-PBDEs in dairy products (full cream milk powder, skim milk powder, pure milk and acidophilus milk) in this study. Solvent extraction, gel permeation chromatography (GPC) and silica gel column cleanup were used, some important steps and crucial parameters were modified and intensified compared with other literatures. Besides, the conditions of GC and MS were also optimized. The limits of quantitation values of 1-50, 4-20 μg kg-1 in full cream milk powders, skim milk powders, pure milks and acidophilus milks were calculated for PBDEs and MeO-PBDEs. In addition, good repeatability and accuracy of the whole method were achieved. Moreover, Eighteen kinds of commercial full cream milk powder samples, sixteen skim milk powder samples, twenty pure milk samples and fifteen acidophilus milk samples were collected from local supermarket in Wuhan, Hubei province. These samples were analyzed to determine whether these samples were contaminated by PBDEs and MeO-PBDEs. The method was successfully applied to determine methoxylated polybrominated diphenyl ethers and polybrominated diphenyl ethers in these dairy products. Using the established methods, PBDEs and MeO-PBDEs were not detected in all samples.
VL  - 3
IS  - 6
ER  -

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