American Journal of Nano Research and Applications
Volume 3, Issue 1-1, January 2015, Pages: 29-32
Received: Mar. 5, 2015;
Accepted: Mar. 6, 2015;
Published: Apr. 28, 2015
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Jumin Hao, Agiltron Inc., 15 Presidential Way, Woburn, MA 01801, USA
Qingwu K. Wang, Agiltron Inc., 15 Presidential Way, Woburn, MA 01801, USA
Wayne Weimer, Agiltron Inc., 15 Presidential Way, Woburn, MA 01801, USA
Justin Abell, Agiltron Inc., 15 Presidential Way, Woburn, MA 01801, USA
Monika Wilson, Agiltron Inc., 15 Presidential Way, Woburn, MA 01801, USA
Surface enhanced Raman scattering (SERS) has emerged as an ultrasensitive analytical tool for chemical, biological, and medical analysis. SERS spectra of permethrin, a common synthetic pyrethroid, were investigated for the first time. The SERS substrates used in this work were a silver nanofilm (AgNF) deposited on glass chips. The characteristic SERS bands of permethrin were analyzed and assigned to the corresponding modes. The strongest SERS band appeared at 1003 cm-1 due to the breath vibration of benzene ring in the permethrin molecule. A detection limit of 10 ppm was obtained on the AgNF sub-strates. A good linear relationship between peak height of the 1003 cm-1 band and permethrin concentration was observed in the range of 10 – 1000 ppm. The results obtained in this work indicate that SERS technique has a great potential for rapid, simple, in situ, and cost-effective detection and monitoring of permethrin in environment and on foods.
Qingwu K. Wang,
SERS Spectra of Permethrin on Silver Nanofilm, American Journal of Nano Research and Applications. Special Issue: Nanomaterials and Nanosensors for Chemical and Biological Detection.
Vol. 3, No. 1-1,
2015, pp. 29-32.
Jeanmaire DL, Van Duyne RP. Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 1977;84:1-20.
Sharma B, Frontiera RR, Henry A-I, Ringe E, Van Duyne RP. SERS: Materials, applications, and the future. Materials Today. 2012;15:16-25.
Yan B, Hong Y, Chen T, Reinhard BM. Monitoring enzymatic degradation of pericellular matrices through SERS stamping. Nanoscale. 2012;4:3917-25.
Du J, Jing C. Preparation of Thiol Modified Fe3O4@Ag Magnetic SERS Probe for PAHs Detection and Identification. The Journal of Physical Chemistry C. 2011;115:17829-35.
Kneipp K, Wang Y, Kneipp H, Perelman LT, Itzkan I, Dasari RR, et al. Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS). Physical Review Letters. 1997;78:1667.
Hao J, Han M-J, Han S, Meng X, Su T-L, Wang QK. SERS Detection of Arsenic in Water: a Critical Review. Journal of Environmental Sciences. 2015:Under Review.
Zheng J, Pang S, Labuza TP, He L. Evaluation of surface-enhanced Raman scattering detection using a handheld and a bench-top Raman spectrometer: A comparative study. Talanta. 2014;129:79-85.
Hao J, Han M-J, Xu Z, Li J, Meng X. Fabrication and evolution of multilayer silver nanofilms for surface-enhanced Raman scattering sensing of arsenate. Nanoscale Research Letters 2011;6:263.
Alvarez-Puebla RA, Liz-Marzán LM. SERS Detection of Small Inorganic Molecules and Ions. Angewandte Chemie International Edition. 2012;51:11214-23.
Hao J, Han M-J, Li J, Meng X. Surface modification of silver nanofilms for improved perchlorate detection by surface-enhanced Raman scattering. Journal of Colloid and Interface Science. 2012;377:51-7.
Chen C, Hao J, Zhu L, Yao Y, Meng X, Weimer W, et al. Direct two-phase interfacial self-assembly of aligned silver nanowire films for surface enhanced Raman scattering applications. Journal of Materials Chemistry A. 2013;1:13496-501.
Halvorson RA, Vikesland PJ. Surface-Enhanced Raman Spectroscopy (SERS) for Environmental Analyses. Environmental Science & Technology. 2010;44:7749-55.
Alvarez-Puebla RA, Liz-Marzan LM. Environmental applications of plasmon assisted Raman scattering. Energy & Environmental Science. 2010;3:1011-7.
Li D-W, Zhai W-L, Li Y-T, Long Y-T. Recent progress in surface enhanced Raman spectroscopy for the detection of environmental pollutants. Microchim Acta. 2014;181:23-43.
Hao J, Han M-J, Meng X, Weimer W, Wang QK. Surface-enhanced Raman scattering of perchlorate on cationic-modified silver nanofilms – Effect of inorganic anions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015;136, Part C:1593-9.
He L, Chen T, Labuza TP. Recovery and quantitative detection of thiabendazole on apples using a surface swab capture method followed by surface-enhanced Raman spectroscopy. Food Chemistry. 2014;148:42-6.
Li W, Lu B, Sheng A, Yang F, Wang Z. Spectroscopic and theoretical study on inclusion complexation of beta-cyclodextrin with permethrin. Journal of Molecular Structure. 2010;981:194-203.
Arayne MS, Sultana N, Hussain F. Validated RP-HPLC method for determination of permethrin in bulk and topical preparations using UV-vis detector. Journal of Chromatographic Science. 2011;49:287-91.
Vergun D, Leipold JD. Insect-repelling ACUs now available to all Soldiers. From website: http://wwwarmymil/article/88171/Army_s_new_ACUs_combat_insect_borne_diseases. 2012.
Kazemipour M, Noroozian E, Tehrani MS, Mahmoudian M. A new second-derivative spectrophotometric method for the determination of permethrin in shampoo. Journal of Pharmaceutical and Biomedical Analysis 2002;30:1379–84.
Shan G, Leeman WR, Stoutamire DW, Gee SJ, Chang DPY, Hammock BD. Enzyme-Linked Immunosorbent Assay for the Pyrethroid Permethrin. Journal of Agricultural and Food Chemistry. 2000;48:4032-40.
Baby RE, Cabezas M, Walsöe de Reca EN. Electronic nose: a useful tool for monitoring environmental contamination. Sensors and Actuators B: Chemical. 2000;69:214-8.
Ogata-Kawatal H, Matsudal M, Onda N, Ueyama J, Kamijima M, Shibata E, et al. Direct analysis of permethrins in human blood by SPE-GC/MS. Chromatography. 2007;28:119–24.
Arip MNM, Heng LY, Ahmad M, Hasbullah SA. Reaction of 2,6-dichloroquinone-4-chloroimide (Gibbs reagent) with permethrin – an optical sensor for rapid detection of permethrin in treated wood. Chemistry Central Journal. 2013;7:122.
Han M-J, Hao J, Xu Z, Meng X. Surface-enhanced Raman scattering for arsenate detection on multilayer silver nanofilms. Analytica Chimica Acta. 2011;692:96-102.