American Journal of Applied Chemistry

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Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins

Received: 08 November 2016    Accepted:     Published: 08 November 2016
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Abstract

Immersion tests were used to study the inhibition effects of a complex vapor phase inhibitor on rusty iron coins. Electrochemical behaviors of simulated cast iron specimens in corrosion solution with or without inhibitor have been investigated by Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The rust composition structure of the cast iron coins after corrosion inhibition treatment was analyzed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Scanning Electron Microscope (SEM) has been used to detect the morphology change before and after inhibition treatment. The results show that the vapor phase inhibitor has a good synergistic inhibition effect. The corrosion potentials of cast iron electrode were positive shift and passivation phenomenon has been tested. A steady deposit film containing Fe2O3 and α-FeOOH were formed on the surface of the specimen. A chemisorption was formed between the inhibitor and iron coin surface rust, and the rust changed compact. It increases the corrosion resistance of the rust layer.

DOI 10.11648/j.ajac.20160405.18
Published in American Journal of Applied Chemistry (Volume 4, Issue 5, October 2016)
Page(s) 207-211
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Iron Relics, Vapor Phase Inhibitor, Compound

References
[1] Hu G, Lu GC, Xu CC, Wu XH. Inhibitive effects of molybdenate on iron artifacts during desalination process [J]. Corrosion & Protection, 2007, 28(4): 191-193.
[2] Zhang TS, Zhang H, Gao H. Corrosion Inhibitors (2d ed) [M]. Beijing: Chemical industry press, 2008, 292.
[3] Wang J L, Wu Y Q, Liu J. Effectiveness of Corrosion Inhibitors on Bronze and Cast Iron with Prefilming Treatment [J]. Int. J. Electrochemical Science, 2013(8):4631-4640.
[4] Wei G, Yang M, Xiong RC. A study of cyclohexylamine carbonate for the gas phase protection of chemical equipment [J]. Chemical Engineering & Machnery, 2000, 27(4): 190-192.
[5] Alagta A, Felhősi I, Bertoti I, et al. Corrosion protection properties of hydroxamic acid self-assembled monolayer on carbon steel [J], Corrosion Science, 2008, 50 (6): 1644-1649
[6] Bei Qian, Baorong Hou, Meng Zheng, The inhibition effect of tannic acid on mild steel corrosion in seawater wet/dry cyclic conditions, Corrosion Science, 2013, 72(7):1-9.
[7] Nasrazadani S, Diaz J, Stevens J, et al. Effects of DBU, morpholine, and DMA on corrosion of low carbon steel exposed to steam [J]. Corrosion Science, 2007, 49(7): 3024-3039.
[8] Zhang D Q, Gao L X, Zhou G D. Self-assembled urea-amine compound as vapor phase corrosion inhibitor for mild steel[J], Surface and Coatings Technology, 2010, 204(9-10): 1646.
[9] Liu F, Chen Y. XPS Study of Fe2p and Fe3s for Fe-containing Compounds[J].Analysis and Testing Technology and Instruments, 2001, 7(3): 166-169.
[10] M. L. A. Gil, A. Santos, M. Bethencourt, Use of X-ray and other techniques to analyse the phase transformation induced in archaeological cast iron after its stabilisation by the electrolytic method, Analytica Chimica Acta, 2003, 494(1-2): 245-254.
Author Information
  • Faculty of Archaeology and Museology, Peking University, Beijing, China

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  • APA Style

    HU Gang. (2016). Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins. American Journal of Applied Chemistry, 4(5), 207-211. https://doi.org/10.11648/j.ajac.20160405.18

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    ACS Style

    HU Gang. Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins. Am. J. Appl. Chem. 2016, 4(5), 207-211. doi: 10.11648/j.ajac.20160405.18

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    AMA Style

    HU Gang. Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins. Am J Appl Chem. 2016;4(5):207-211. doi: 10.11648/j.ajac.20160405.18

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  • @article{10.11648/j.ajac.20160405.18,
      author = {HU Gang},
      title = {Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins},
      journal = {American Journal of Applied Chemistry},
      volume = {4},
      number = {5},
      pages = {207-211},
      doi = {10.11648/j.ajac.20160405.18},
      url = {https://doi.org/10.11648/j.ajac.20160405.18},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajac.20160405.18},
      abstract = {Immersion tests were used to study the inhibition effects of a complex vapor phase inhibitor on rusty iron coins. Electrochemical behaviors of simulated cast iron specimens in corrosion solution with or without inhibitor have been investigated by Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The rust composition structure of the cast iron coins after corrosion inhibition treatment was analyzed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Scanning Electron Microscope (SEM) has been used to detect the morphology change before and after inhibition treatment. The results show that the vapor phase inhibitor has a good synergistic inhibition effect. The corrosion potentials of cast iron electrode were positive shift and passivation phenomenon has been tested. A steady deposit film containing Fe2O3 and α-FeOOH were formed on the surface of the specimen. A chemisorption was formed between the inhibitor and iron coin surface rust, and the rust changed compact. It increases the corrosion resistance of the rust layer.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Study of Inhibition Performance of a Vapor Phase Inhibitor on Rusty Iron Coins
    AU  - HU Gang
    Y1  - 2016/11/08
    PY  - 2016
    N1  - https://doi.org/10.11648/j.ajac.20160405.18
    DO  - 10.11648/j.ajac.20160405.18
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 207
    EP  - 211
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20160405.18
    AB  - Immersion tests were used to study the inhibition effects of a complex vapor phase inhibitor on rusty iron coins. Electrochemical behaviors of simulated cast iron specimens in corrosion solution with or without inhibitor have been investigated by Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The rust composition structure of the cast iron coins after corrosion inhibition treatment was analyzed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Scanning Electron Microscope (SEM) has been used to detect the morphology change before and after inhibition treatment. The results show that the vapor phase inhibitor has a good synergistic inhibition effect. The corrosion potentials of cast iron electrode were positive shift and passivation phenomenon has been tested. A steady deposit film containing Fe2O3 and α-FeOOH were formed on the surface of the specimen. A chemisorption was formed between the inhibitor and iron coin surface rust, and the rust changed compact. It increases the corrosion resistance of the rust layer.
    VL  - 4
    IS  - 5
    ER  - 

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