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Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution

Received: 21 May 2016    Accepted:     Published: 24 May 2016
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Abstract

To investigate the resistance of normal concrete to sulfate solution frost, concrete specimens with different water/cement (w/c) ratios, mineral admixture types, replacement ratios, and air contents were fabricated. Then, these specimens were frozen and thawed cyclically in 5% concentration Na2SO4 solution. As the freezing and thawing cycles proceeding, the appearance morphology, mass loss, and dynamic elastic modulus (DEM) of the specimens were observed. The service life of concrete that is subjected to the freeze–thaw cycles in Na2SO4 solution was calculated based on specimens' DEM losses. Results indicated that the appearance damage and mass loss of concrete along with the freeze–thaw cycles were unnoticeable until failure, and DEM losses played a controlling role in determining specimens' failure. In addition, a sudden fracture failure in the middle occurred easily in specimens with low w/c ratio. Decreasing concrete w/c ratio can slightly increase the concrete resistance to the freeze–thaw cycles in Na2SO4 solution, whereas incorporating fly ash or slag has almost no effect. Moreover, higher replacement ratio of fly ash or slag increases the adverse effects on concrete. Adding an air-entraining agent to concrete can significantly improve its resistance to the freeze–thaw cycles. Air content at 4.6% and 5.7% can extend the service life of concrete under the freeze–thaw cycles in Na2SO4 solution by more than 5 times its ordinary life span.

Published in American Journal of Civil Engineering (Volume 4, Issue 3)
DOI 10.11648/j.ajce.20160403.17
Page(s) 104-110
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Concrete, Freeze–Thaw Cycle, Deterioration, Na2SO4 Solution, Service Life Prediction

References
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[2] Zhou, G., S. R. Li, Z. J. Wang and C. F. Wang. Investigation and analysis on the corrosion of concrete in saline soil area. Journal of Architectural Science and Engineering 2011, 28(4): 121-126. (in Chinese)
[3] Neville A. The confused world of sulfate attack on concrete, Cem. Concr. Res. 8(2004) 1275-1296.
[4] Amini A., Tehrani S. S. Combined effects of saltwater and water flow on deterioration of concrete under freezing-thawing cycles, J. Cold Reg. Eng. 25(2011) 145-161.
[5] Sotiriadis K., Nikolopoulou E., Ysivilis S. Sulfate resistance of limestone cement concrete exposed to combined chloride and sulfate environment at low temperature, Cem. Concr. Comps. 8(2012) 903-910.
[6] Łaźniewska-Piekarczyk B. The frost resistance versus air voids parameters of high performance self compacting concrete modified by non-air-entrained admixtures, Constr. Build. Mater. 48(2013) 1209-1220.
[7] Mu R., C. W. Miao, J. P. Liu and W. Sun. Effect of NaCl and Na2SO4 solution on the frost resistance of concrete and its mechanism. Journal of the Chinese Ceramic Society 2001, 29(6): 523-529. (in Chinese)
[8] Yu H. F., W. Sun, L. H. Yan and B. Yang. Freezing thawing durability of high strength and high performance concrete exposed to salt lakes. Journal of the Chinese Ceramic Society 2004, 32(7): 842-848. (in Chinese)
[9] Yuan L. D., D. T. Niu, L. Jiang, Y. Z. Sun and Q. N. Fei. Study on damage of concrete under the combined action of sulfate attack and freeze–thaw cycle. Bulletin of the Chinese Ceramic Society 2013, 32(6): 1171-1176. (in Chinese)
[10] Zhang Y. Q., H. F. Yu, W. Sun and J. Y. Zhang. Frost resistance of concrete under action of magnesium sulfate attack. Journal of Building Materials 2011, 14(5): 698-702. (in Chinese)
[11] Jiang L., D. T. Niu, L. D. Yuan and Q. N. Fei. Durability of concrete under sulfate attack exposed to freeze–thaw cycles. Cold Regions Science and Technology 2015, 112: 112-117.
[12] Ge Y., W. C. Yang, J. Yuan, B. S. Zhang and A. L. Xiong. Freezing resistance of concrete in sulfate solution. Concrete 2005, 8: 71-73. (in Chinese)
[13] Mu R., C. W. Miao, J. P. Liu W. Sun. Effect of sodium sulphate solution on the frost resistance of concrete. Journal of Building Materials, 2001, 4(4): 311-316. (in Chinese)
[14] Yu H. F., W. Sun, L. H. Yan and Q. Wang. Research on freezing-thawing durability of air-entrained concrete exposed to salt lakes. Journal of Wuhan University of Technology, 2004, 26(3): 15-18. (in Chinese)
[15] Du J. M., Y. Chen, G. X. Yu and Y. S. Ji. Research on the sulfate corrosion resistance of fly ash concrete in adsorption area. Journal of China University of Mining & Technology, 2014, 43(4): 600-605. (in Chinese)
[16] Ghafoori N., M. Najimi, H. Diawara and M. S. Islam. Effects of class F fly ash on sulfate resistance of Type V Portland cement concretes under continuous and interrupted sulfate exposures. Constr. Build. Mater. 2015, 78: 85-91.
[17] Peng G. F., Q. Ma, H. M. Hu, R. Gao, Q. F. Yao and Y. F. Liu. The effects of air entrainment and pozzolans on frost resistance of 50-60 MPa grade concrete. Constr. Build. Mater. 2007, 21: 1034-1039.
[18] Su X. P., Q. Wang, W. H. Wang and H. Y. Sun. Frost resistance and durability mechanism of concrete under saline-alkali condition in seasonal frozen soil area. Journal of Jilin University: Earth Science Edition 2014, 44(4): 1244-1253. (in Chinese)
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  • APA Style

    Guo Li, Dan Wang, Jian-Min Du. (2016). Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution. American Journal of Civil Engineering, 4(3), 104-110. https://doi.org/10.11648/j.ajce.20160403.17

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    ACS Style

    Guo Li; Dan Wang; Jian-Min Du. Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution. Am. J. Civ. Eng. 2016, 4(3), 104-110. doi: 10.11648/j.ajce.20160403.17

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    AMA Style

    Guo Li, Dan Wang, Jian-Min Du. Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution. Am J Civ Eng. 2016;4(3):104-110. doi: 10.11648/j.ajce.20160403.17

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  • @article{10.11648/j.ajce.20160403.17,
      author = {Guo Li and Dan Wang and Jian-Min Du},
      title = {Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution},
      journal = {American Journal of Civil Engineering},
      volume = {4},
      number = {3},
      pages = {104-110},
      doi = {10.11648/j.ajce.20160403.17},
      url = {https://doi.org/10.11648/j.ajce.20160403.17},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajce.20160403.17},
      abstract = {To investigate the resistance of normal concrete to sulfate solution frost, concrete specimens with different water/cement (w/c) ratios, mineral admixture types, replacement ratios, and air contents were fabricated. Then, these specimens were frozen and thawed cyclically in 5% concentration Na2SO4 solution. As the freezing and thawing cycles proceeding, the appearance morphology, mass loss, and dynamic elastic modulus (DEM) of the specimens were observed. The service life of concrete that is subjected to the freeze–thaw cycles in Na2SO4 solution was calculated based on specimens' DEM losses. Results indicated that the appearance damage and mass loss of concrete along with the freeze–thaw cycles were unnoticeable until failure, and DEM losses played a controlling role in determining specimens' failure. In addition, a sudden fracture failure in the middle occurred easily in specimens with low w/c ratio. Decreasing concrete w/c ratio can slightly increase the concrete resistance to the freeze–thaw cycles in Na2SO4 solution, whereas incorporating fly ash or slag has almost no effect. Moreover, higher replacement ratio of fly ash or slag increases the adverse effects on concrete. Adding an air-entraining agent to concrete can significantly improve its resistance to the freeze–thaw cycles. Air content at 4.6% and 5.7% can extend the service life of concrete under the freeze–thaw cycles in Na2SO4 solution by more than 5 times its ordinary life span.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Deterioration and Service Life Prediction of Concrete Subjected to Freeze–Thaw Cycles in Na2SO4 Solution
    AU  - Guo Li
    AU  - Dan Wang
    AU  - Jian-Min Du
    Y1  - 2016/05/24
    PY  - 2016
    N1  - https://doi.org/10.11648/j.ajce.20160403.17
    DO  - 10.11648/j.ajce.20160403.17
    T2  - American Journal of Civil Engineering
    JF  - American Journal of Civil Engineering
    JO  - American Journal of Civil Engineering
    SP  - 104
    EP  - 110
    PB  - Science Publishing Group
    SN  - 2330-8737
    UR  - https://doi.org/10.11648/j.ajce.20160403.17
    AB  - To investigate the resistance of normal concrete to sulfate solution frost, concrete specimens with different water/cement (w/c) ratios, mineral admixture types, replacement ratios, and air contents were fabricated. Then, these specimens were frozen and thawed cyclically in 5% concentration Na2SO4 solution. As the freezing and thawing cycles proceeding, the appearance morphology, mass loss, and dynamic elastic modulus (DEM) of the specimens were observed. The service life of concrete that is subjected to the freeze–thaw cycles in Na2SO4 solution was calculated based on specimens' DEM losses. Results indicated that the appearance damage and mass loss of concrete along with the freeze–thaw cycles were unnoticeable until failure, and DEM losses played a controlling role in determining specimens' failure. In addition, a sudden fracture failure in the middle occurred easily in specimens with low w/c ratio. Decreasing concrete w/c ratio can slightly increase the concrete resistance to the freeze–thaw cycles in Na2SO4 solution, whereas incorporating fly ash or slag has almost no effect. Moreover, higher replacement ratio of fly ash or slag increases the adverse effects on concrete. Adding an air-entraining agent to concrete can significantly improve its resistance to the freeze–thaw cycles. Air content at 4.6% and 5.7% can extend the service life of concrete under the freeze–thaw cycles in Na2SO4 solution by more than 5 times its ordinary life span.
    VL  - 4
    IS  - 3
    ER  - 

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Author Information
  • School of Mechanics & Civil Engineering, China University of Mining and Technology, Xuzhou, China

  • School of Mechanics & Civil Engineering, China University of Mining and Technology, Xuzhou, China

  • School of Mechanics & Civil Engineering, China University of Mining and Technology, Xuzhou, China

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