| Peer-Reviewed

Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater

Received: 17 September 2015    Accepted: 25 September 2015    Published: 29 September 2015
Views:       Downloads:
Abstract

Poly (acrylamide/maleic acid/gelatin) P(AAm/MA/G) hydrogels have been prepared by gamma radiation and their adsorption for chromium ion from aqueous solutions have been investigated. The structural of the hydrogels was monitored by FTIR. The swelling behavior of the hydrogels has been investigated in distilled water and different pH's values at ambient temperature. The P(AAm) hydrogel showed fair pH-dependent swelling whereas P(AAm/MA) and P(AAm/MA/G) hydrogels exhibit a higher swelling by increasing the pH. The chromium ion solutions have been exposed to gamma radiation for precipitation. The results showed that the precipitation (%) decrease by increasing the initial chromium ions concentration. The possibility of using different hydrogels for the uptake of irradiated chromium ion solutions was investigated. The P(AAm/MA) hydrogel showed higher chromium ion uptake compared to that by P(AAm) and P(AAm/MA/G). The adsorption studies show that, the chromium uptake is pH dependent. Lowering of the chromium ion concentration has been achieved after the treatment of chromium ion solution by gamma radiation followed by adsorption onto hydrogels.

Published in American Journal of Polymer Science and Technology (Volume 1, Issue 1)
DOI 10.11648/j.ajpst.20150101.12
Page(s) 9-14
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Chromium Ion, Gamma Radiation, Adsorption, Hydrogels

References
[1] Mohan, S., & Sreelakshmi, G. (2008). Fixed bed column study for heavy metal removal using phosphate treated rice husk. Journal of Hazardous Materials, 153, 75–82.
[2] Miretzky, P., Saralegui, A., & Cirelli, A. F. (2006). Simultaneous heavy metal removal mechanism by dead macrophytes. Chemosphere, 62, 247–254.
[3] Lyu, E, Makarov, E., Kuryatnikov, Yu. I, Mazanko, A. F., Dzhagatspanyah, R. V., and. Pikaev A. K, Radiat. Phys. Chem. 22, pp503, (1983).
[4] Al-Sheikhly, M. Chaychian, M. and. L. Mclaughlin, Trans. Am. Nucl. Soc. 72, pp 128, (1995).
[5] Chaychian, M., Al-Sheikhly, M., and L. Mclaughlin, Radiat. Phys. Chem. 53, pp 145, (1998).
[6] El-Arnaouty M. B, Dessouki A. M., Taher N. H. and El-Toony M. M. Seventh Intern. Conf. Nucl. Sci. and Applns., Cairo, (2000).
[7] M. El-Arnaouty, N. Taher, M. El-Toony and A. M. Dessouki Arab J. Nucl. Sci & Applns., 35 (2002).
[8] Bodugoz H, Pursel N. and Guven O., Radiat. Phys. Chem. 55, pp 667, (1999).
[9] T. Caykara, C. Ozyurek, O. Kantoglu, B. Erdogan, Polym. Degrad. Stabil. 80 (2003) 339.
[10] H. Tumturk, T. Caykara, M. Sen, O. Guven, Radiat. Phys. Chem. 55 (1999) 713.
[11] D. Saraydin, E. Karadag, O. Guven, Polym. Adv. Technol. 6 (1995) 719.
[12] A. Chapiro, Radiation Chemistry of Polymeric Systems, Interscience, New York, 1962.
[13] T. Caykara, C. Ozyurek, O. Kantoglu, O. Guven, J. Polym. Sci. Part B: Polym. Phys. 38 (2000) 2063.
[14] E. A. Hegazy, S. E. El-Aal, M. F. Abu Talib, A. M. Dessouki, J. Appl. Polym. Sci. 92 (2004) 2462.
[15] M. Sen, O. Guven, Polymer 39 (1998) 1165.
[16] Sen, M., Uzun, C. and Guven, O. International Journal of Pharmaceuties 203, 149, (2000).
[17] Siegel, R. A., Firestone, B. A., Macromolecules 21, 3254, 1988.
[18] Swallow, A. J, Radiation Chemistry: An Introduction, Wiley, New York, (1973).
[19] Al-Sheikhly M. and Mclaughlin, W. L., Radiat. Phys. Chem. 38,203, (1991).
[20] Sharpe P. H. G., and Sehested, K. Radiat. Phys. Chem. 34, pp763, 1989.
[21] Cooper, W. J, R. D. Curry, W. J and O. Shea K. E.: Environmental Applications of Ionizing Radiation, Wiley, New York, (1998).
[22] Hegazy E. A., Abd El-Aal S. E., Abu Talib M. F and Dessouki A. M. J. Applied Polymer Science 92, 2462 (2004).
[23] Hegazy E. A., Abd El-Rehim H. A., and Shawky H. A. Radiat. Phys. Chem. 57, pp85, (2000).
[24] F. Gode, E. Pehlivan, Journal of Hazardous Materials B119 (2005) 175–182.
[25] Shannon R. S. Acta Crystallogr A; 32:751(1976).
Cite This Article
  • APA Style

    M. Eid. (2015). Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater. American Journal of Polymer Science and Technology, 1(1), 9-14. https://doi.org/10.11648/j.ajpst.20150101.12

    Copy | Download

    ACS Style

    M. Eid. Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater. Am. J. Polym. Sci. Technol. 2015, 1(1), 9-14. doi: 10.11648/j.ajpst.20150101.12

    Copy | Download

    AMA Style

    M. Eid. Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater. Am J Polym Sci Technol. 2015;1(1):9-14. doi: 10.11648/j.ajpst.20150101.12

    Copy | Download

  • @article{10.11648/j.ajpst.20150101.12,
      author = {M. Eid},
      title = {Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater},
      journal = {American Journal of Polymer Science and Technology},
      volume = {1},
      number = {1},
      pages = {9-14},
      doi = {10.11648/j.ajpst.20150101.12},
      url = {https://doi.org/10.11648/j.ajpst.20150101.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20150101.12},
      abstract = {Poly (acrylamide/maleic acid/gelatin) P(AAm/MA/G) hydrogels have been prepared by gamma radiation and their adsorption for chromium ion from aqueous solutions have been investigated. The structural of the hydrogels was monitored by FTIR. The swelling behavior of the hydrogels has been investigated in distilled water and different pH's values at ambient temperature. The P(AAm) hydrogel showed fair pH-dependent swelling whereas P(AAm/MA) and P(AAm/MA/G) hydrogels exhibit a higher swelling by increasing the pH. The chromium ion solutions have been exposed to gamma radiation for precipitation. The results showed that the precipitation (%) decrease by increasing the initial chromium ions concentration. The possibility of using different hydrogels for the uptake of irradiated chromium ion solutions was investigated. The P(AAm/MA) hydrogel showed higher chromium ion uptake compared to that by P(AAm) and P(AAm/MA/G). The adsorption studies show that, the chromium uptake is pH dependent. Lowering of the chromium ion concentration has been achieved after the treatment of chromium ion solution by gamma radiation followed by adsorption onto hydrogels.},
     year = {2015}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Gamma Radiation Preparation of Poly (Acrylamide/Maleic Acid/Gelatin) Hydrogels for Adsorption of Chromium Ions from Wastewater
    AU  - M. Eid
    Y1  - 2015/09/29
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ajpst.20150101.12
    DO  - 10.11648/j.ajpst.20150101.12
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 9
    EP  - 14
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20150101.12
    AB  - Poly (acrylamide/maleic acid/gelatin) P(AAm/MA/G) hydrogels have been prepared by gamma radiation and their adsorption for chromium ion from aqueous solutions have been investigated. The structural of the hydrogels was monitored by FTIR. The swelling behavior of the hydrogels has been investigated in distilled water and different pH's values at ambient temperature. The P(AAm) hydrogel showed fair pH-dependent swelling whereas P(AAm/MA) and P(AAm/MA/G) hydrogels exhibit a higher swelling by increasing the pH. The chromium ion solutions have been exposed to gamma radiation for precipitation. The results showed that the precipitation (%) decrease by increasing the initial chromium ions concentration. The possibility of using different hydrogels for the uptake of irradiated chromium ion solutions was investigated. The P(AAm/MA) hydrogel showed higher chromium ion uptake compared to that by P(AAm) and P(AAm/MA/G). The adsorption studies show that, the chromium uptake is pH dependent. Lowering of the chromium ion concentration has been achieved after the treatment of chromium ion solution by gamma radiation followed by adsorption onto hydrogels.
    VL  - 1
    IS  - 1
    ER  - 

    Copy | Download

Author Information
  • National Center for Radiation Research and Technology, Atomic Energy Authority, Cairo, Egypt

  • Sections