| Peer-Reviewed

Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses

Received: 31 October 2016    Accepted: 1 December 2016    Published: 17 December 2016
Views:       Downloads:
Abstract

The effect of gamma radiation on the mechanical and chemical properties of x CuO, (70-x) Bi2O3, 20SiO2,10 Na2O, where 0 ≤ x ≤ 30 weight % were carefully studied in order to obtain information about the changes that appear in the structure of the glass matrix with the doping of copper ions. The glass matrix was fabricated by melt-quenching technique. The results showed that, the glass system has good durability, density and mechanical properties with increasing CuO content at the expense of Bi2O3, and that the effect of irradiation with gamma dose is very small. UV-VIS absorption spectra for all glasses have a single asymmetric band, which corresponds to a BiO3→BiO6 transition of the Cu2+ ions in octahedral symmetry with an elongated tetragonal distortion. These measurements indicate the presence of Cu2+ ions in the glasses. Furthermore, it has good water resistance ability with increasing copper oxide. So, it can be used as a container for keeping radioactive waste and radioactive sources.

Published in American Journal of Physics and Applications (Volume 4, Issue 6)
DOI 10.11648/j.ajpa.20160406.11
Page(s) 140-144
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Bismosilicate Glasses, Hardness, Durability

References
[1] Y. B. Dimitriev, in Proc. Inter. Cong. Glass, Invited Papers, Edinburgh, Scotland, vol. 1 p. 225, (2001).
[2] L. Baia, R. Stefan, W. Kiefer, J. Popp, S. I. Simon, J. Non-Cryst. Solids 303, 379 (2002).
[3] S. Sindhu, S. Sanghi, A. Agarwal, V. Seth, N. Kishore, Mater. Chem. Phys. 90, 83 (2005).
[4] F. H. ElBatal, Nucl. Instrum. Methods Phys. Res., Sect. B, Beam Interact. Mater. Atoms 254, 243 (2007).
[5] F. H. ElBatal, S. Y. Marzouk, N. Nada, S. M. Desouky, Physica B 391, 88 (2007).
[6] Heba A. Saudy, Sawsan El Mosallamy, Samir U. El Kameesy, Nashwa Sheta, Ahmed G. Mostafa, Hanaa A. Sallam, World Journal of Condensed Matter Physics, 3, 9-13 (2013). (http://www.scirp.org/journal/wjcmp).
[7] J. Fu, H. Yatsuda, Phys. Chem. Glasses 36 (1995) 211.
[8] L. Montagne, G. Palavit, G. Mairesse, M. Draoui, K. Aomari, M. Saidi Idrissi, Phys. Chem. Glasses 38 (1997) 15.
[9] Werner Vogel, Glass Chemistry, Second Edition Springer-Verlag, Berlin, 1994.
[10] I. Ardelean, solid state common 27,697, (1978).
[11] F. M. Ezz Eldin, N. A. El-Alaily, H. A. Elbatal, J. Radio-Anal. Nucl. Chem. 63 (2) (1992) 267.
[12] H. A. Saudi, Applied Mathematics and Physics, Vol. 1, No. 4, 143-146 (2013). (http://pubs.sciepub.com/amp/1/4/7 © Science and Education Publishing).
[13] R. Bajpai and S. C. Datt, Indian J pure Appl. Phys, 24 (1986).
[14] N. A. El-Alaily, W. M. Abdallah, B. A. Sabrah, A. I. Saad, Silicon (2017) 9: 117–130 DOI 10.1007/s12633-015-9330-7.
[15] E. J. Friebele, Radiation effects, in: D. R. Uhlmann, N. J. Kreidl (Eds.), Optical Properties (2012).
[16] A. Bishay, J. Non-Cryst. Solids 3 (1970) 54–114.
[17] M. A. Marzouk et al. / Journal of Non-Crystalline Solids 387 (2014) 155–160.
[18] LI Xiu-ying, YANG Hua-ming, REN Yu-xi, J. Cent. South Univ. (2013) 20: 44−49
[19] D. S. McClure, Solid State Physics, Vol. 9, Ed. F. Seitz, D. Turnbull, Academic Press, New York, 1959, p. 195.
[20] B. Karthikeyan, S. Mohan, Matt. Lett. 57, 3789 (2003).
Cite This Article
  • APA Style

    H. A. Saudi. (2016). Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses. American Journal of Physics and Applications, 4(6), 140-144. https://doi.org/10.11648/j.ajpa.20160406.11

    Copy | Download

    ACS Style

    H. A. Saudi. Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses. Am. J. Phys. Appl. 2016, 4(6), 140-144. doi: 10.11648/j.ajpa.20160406.11

    Copy | Download

    AMA Style

    H. A. Saudi. Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses. Am J Phys Appl. 2016;4(6):140-144. doi: 10.11648/j.ajpa.20160406.11

    Copy | Download

  • @article{10.11648/j.ajpa.20160406.11,
      author = {H. A. Saudi},
      title = {Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses},
      journal = {American Journal of Physics and Applications},
      volume = {4},
      number = {6},
      pages = {140-144},
      doi = {10.11648/j.ajpa.20160406.11},
      url = {https://doi.org/10.11648/j.ajpa.20160406.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20160406.11},
      abstract = {The effect of gamma radiation on the mechanical and chemical properties of x CuO, (70-x) Bi2O3, 20SiO2,10 Na2O, where 0 ≤ x ≤ 30 weight % were carefully studied in order to obtain information about the changes that appear in the structure of the glass matrix with the doping of copper ions. The glass matrix was fabricated by melt-quenching technique. The results showed that, the glass system has good durability, density and mechanical properties with increasing CuO content at the expense of Bi2O3, and that the effect of irradiation with gamma dose is very small. UV-VIS absorption spectra for all glasses have a single asymmetric band, which corresponds to a BiO3→BiO6 transition of the Cu2+ ions in octahedral symmetry with an elongated tetragonal distortion. These measurements indicate the presence of Cu2+ ions in the glasses. Furthermore, it has good water resistance ability with increasing copper oxide. So, it can be used as a container for keeping radioactive waste and radioactive sources.},
     year = {2016}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Gamma Ray Irradiation Effects on the Mechanical and Chemical Properties of CuO–Bi2O3–SiO2 Glasses
    AU  - H. A. Saudi
    Y1  - 2016/12/17
    PY  - 2016
    N1  - https://doi.org/10.11648/j.ajpa.20160406.11
    DO  - 10.11648/j.ajpa.20160406.11
    T2  - American Journal of Physics and Applications
    JF  - American Journal of Physics and Applications
    JO  - American Journal of Physics and Applications
    SP  - 140
    EP  - 144
    PB  - Science Publishing Group
    SN  - 2330-4308
    UR  - https://doi.org/10.11648/j.ajpa.20160406.11
    AB  - The effect of gamma radiation on the mechanical and chemical properties of x CuO, (70-x) Bi2O3, 20SiO2,10 Na2O, where 0 ≤ x ≤ 30 weight % were carefully studied in order to obtain information about the changes that appear in the structure of the glass matrix with the doping of copper ions. The glass matrix was fabricated by melt-quenching technique. The results showed that, the glass system has good durability, density and mechanical properties with increasing CuO content at the expense of Bi2O3, and that the effect of irradiation with gamma dose is very small. UV-VIS absorption spectra for all glasses have a single asymmetric band, which corresponds to a BiO3→BiO6 transition of the Cu2+ ions in octahedral symmetry with an elongated tetragonal distortion. These measurements indicate the presence of Cu2+ ions in the glasses. Furthermore, it has good water resistance ability with increasing copper oxide. So, it can be used as a container for keeping radioactive waste and radioactive sources.
    VL  - 4
    IS  - 6
    ER  - 

    Copy | Download

Author Information
  • Department of Physics, Faculty of Science (Girls' Branch), Al-Azhar University, Nasr City, Egypt

  • Sections