Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides
Modern Chemistry
Volume 4, Issue 6, December 2016, Pages: 52-58
Received: Dec. 14, 2016; Accepted: Dec. 22, 2016; Published: Jan. 16, 2017
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Yuki Nakahara, Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Haruki Shimosasa, Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Ryuta Miyatake, Centre for Environmental Conservation and Research Safety, University of Toyama, Toyama, Japan
Naoki Kobayashi, Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Mitsunori Oda, Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
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The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.
Isobenzofuran-Dicarboximides, Diels-Alder Reaction, Dehydration, Triflic Acid, Fluorescence
To cite this article
Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda, Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides, Modern Chemistry. Vol. 4, No. 6, 2016, pp. 52-58. doi: 10.11648/
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