A number of bimetallic thiocyanato-bridged complexes of cations [M(NH2X)6]2+ and [M(en)3]2+ with anions [Co(NCS)4]2– are prepared. Their structure has been investigated in terms of FT-IR, 13C NMR and UV-vis spectroscopy, metal analysis, magnetic and conductance studies. The complexes are proposed to have the following compositions, [M(NH2X)5][Co(NCS)4] and [{M(en)2}{Co(NCS)4}]n (where M=Cu, Ni, Zn, Cd; X=H, Ph; en=ethylenediamine). The general feature results from i. a combination of the bridging thiocyanate ligand, ii. the distorted environments of cobalt(II) and iii. regular octahedral geometry of cations. The antibacterial activity of the prepared complexes against the gram positive, Bacillus cereus and gram negative Salmonella typhi, Pseudomonas alruginosa, Escherichia coli pathogens has also been investigated.
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This article belongs to the Special Issue Synthesis and Microbial Screening of Coordination and Organic Compounds |
| DOI | 10.11648/j.mc.s.2015030101.11 |
| Page(s) | 1-6 |
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Bimetallic Thiocyanato-Bridged Complexes, Cobalt(II), Ethylenediamine, Antibacterial Properties
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APA Style
Mohammad Nasir Uddin, Tania Sultana Rupa. (2015). Thiocyanato Bridged Bimetallic Complexes (M-SCN-Co): Synthesis, Characterization and Biological Studies. Modern Chemistry, 3(1-1), 1-6. https://doi.org/10.11648/j.mc.s.2015030101.11
ACS Style
Mohammad Nasir Uddin; Tania Sultana Rupa. Thiocyanato Bridged Bimetallic Complexes (M-SCN-Co): Synthesis, Characterization and Biological Studies. Mod. Chem. 2015, 3(1-1), 1-6. doi: 10.11648/j.mc.s.2015030101.11
AMA Style
Mohammad Nasir Uddin, Tania Sultana Rupa. Thiocyanato Bridged Bimetallic Complexes (M-SCN-Co): Synthesis, Characterization and Biological Studies. Mod Chem. 2015;3(1-1):1-6. doi: 10.11648/j.mc.s.2015030101.11
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Download@article{10.11648/j.mc.s.2015030101.11,
author = {Mohammad Nasir Uddin and Tania Sultana Rupa},
title = {Thiocyanato Bridged Bimetallic Complexes (M-SCN-Co): Synthesis, Characterization and Biological Studies},
journal = {Modern Chemistry},
volume = {3},
number = {1-1},
pages = {1-6},
doi = {10.11648/j.mc.s.2015030101.11},
url = {https://doi.org/10.11648/j.mc.s.2015030101.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.s.2015030101.11},
abstract = {A number of bimetallic thiocyanato-bridged complexes of cations [M(NH2X)6]2+ and [M(en)3]2+ with anions [Co(NCS)4]2– are prepared. Their structure has been investigated in terms of FT-IR, 13C NMR and UV-vis spectroscopy, metal analysis, magnetic and conductance studies. The complexes are proposed to have the following compositions, [M(NH2X)5][Co(NCS)4] and [{M(en)2}{Co(NCS)4}]n (where M=Cu, Ni, Zn, Cd; X=H, Ph; en=ethylenediamine). The general feature results from i. a combination of the bridging thiocyanate ligand, ii. the distorted environments of cobalt(II) and iii. regular octahedral geometry of cations. The antibacterial activity of the prepared complexes against the gram positive, Bacillus cereus and gram negative Salmonella typhi, Pseudomonas alruginosa, Escherichia coli pathogens has also been investigated.},
year = {2015}
}
TY - JOUR
T1 - Thiocyanato Bridged Bimetallic Complexes (M-SCN-Co): Synthesis, Characterization and Biological Studies
AU - Mohammad Nasir Uddin
AU - Tania Sultana Rupa
Y1 - 2015/01/27
PY - 2015
N1 - https://doi.org/10.11648/j.mc.s.2015030101.11
DO - 10.11648/j.mc.s.2015030101.11
T2 - Modern Chemistry
JF - Modern Chemistry
JO - Modern Chemistry
SP - 1
EP - 6
PB - Science Publishing Group
SN - 2329-180X
UR - https://doi.org/10.11648/j.mc.s.2015030101.11
AB - A number of bimetallic thiocyanato-bridged complexes of cations [M(NH2X)6]2+ and [M(en)3]2+ with anions [Co(NCS)4]2– are prepared. Their structure has been investigated in terms of FT-IR, 13C NMR and UV-vis spectroscopy, metal analysis, magnetic and conductance studies. The complexes are proposed to have the following compositions, [M(NH2X)5][Co(NCS)4] and [{M(en)2}{Co(NCS)4}]n (where M=Cu, Ni, Zn, Cd; X=H, Ph; en=ethylenediamine). The general feature results from i. a combination of the bridging thiocyanate ligand, ii. the distorted environments of cobalt(II) and iii. regular octahedral geometry of cations. The antibacterial activity of the prepared complexes against the gram positive, Bacillus cereus and gram negative Salmonella typhi, Pseudomonas alruginosa, Escherichia coli pathogens has also been investigated.
VL - 3
IS - 1-1
ER -
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