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Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides

Received: 14 December 2016    Accepted: 22 December 2016    Published: 16 January 2017
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Abstract

The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.

DOI 10.11648/j.mc.20160406.11
Published in Modern Chemistry (Volume 4, Issue 6, December 2016)
Page(s) 52-58
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Isobenzofuran-Dicarboximides, Diels-Alder Reaction, Dehydration, Triflic Acid, Fluorescence

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Author Information
  • Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan

  • Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan

  • Centre for Environmental Conservation and Research Safety, University of Toyama, Toyama, Japan

  • Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan

  • Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan

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  • APA Style

    Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. (2017). Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Modern Chemistry, 4(6), 52-58. https://doi.org/10.11648/j.mc.20160406.11

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    ACS Style

    Yuki Nakahara; Haruki Shimosasa; Ryuta Miyatake; Naoki Kobayashi; Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod. Chem. 2017, 4(6), 52-58. doi: 10.11648/j.mc.20160406.11

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    AMA Style

    Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod Chem. 2017;4(6):52-58. doi: 10.11648/j.mc.20160406.11

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  • @article{10.11648/j.mc.20160406.11,
      author = {Yuki Nakahara and Haruki Shimosasa and Ryuta Miyatake and Naoki Kobayashi and Mitsunori Oda},
      title = {Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides},
      journal = {Modern Chemistry},
      volume = {4},
      number = {6},
      pages = {52-58},
      doi = {10.11648/j.mc.20160406.11},
      url = {https://doi.org/10.11648/j.mc.20160406.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.mc.20160406.11},
      abstract = {The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.},
     year = {2017}
    }
    

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    AU  - Yuki Nakahara
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    AB  - The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.
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