Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics

Le Dai Vuong; Phan Dinh Gio

doi:doi:10.11648/j.ijmsa.20130203.13

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Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics

Le Dai Vuong, Phan Dinh Gio

Published in International Journal of Materials Science and Applications (Volume 2, Issue 3)

Received: 13 May 2013 Accepted: Published: 10 June 2013

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Abstract

The 0.8Pb(Zr0.48Ti0.52)]O3–0.125Pb(Zn1/3Nb2/3)O3–0.075Pb(Mn1/3Nb2/3)O3 + x wt% Li2CO3 ceramics (PZT-PZN-PMnN), where x = 0  1.0, has been prepared by two-stage calcinations method. The Li2CO3 addition significantly improved the sinterability of the ceramics, resulting in a reduction of sintering temperature from 1150 0C to 930 0C. The effect of the Li2CO3 addition on the sintering behavior and physical properties of ceramic samples have been investigated. Experimental results showed that all samples have pure perovskite phase with tetragonal structure, the c/a ratio increases with increasing of Li2CO3 content. At x = 0.7, electrical properties of ceramics are best: the density () of 7.86 g/cm3, the electromechanical coupling factor, kp = 0.64 and kt = 0.51, the dielectric constant, ε = 1320, the dielectric loss (tan) of 0.005, the mechanical quality factor (Qm) of 1150, the piezoelectric constant (d31) of 145 pC/N, and the remanent polarization (Pr) of 30.5 C/cm2, which makes it as a promising material for high power piezoelectric devices.

Published in	International Journal of Materials Science and Applications (Volume 2, Issue 3)
DOI	10.11648/j.ijmsa.20130203.13
Page(s)	89-93
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Crystal Structure, Dielectrics, Piezoelectrics, Electromechanical Coupling Factor, Li2co3 Addition

References

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[2]	Gao. F., Cheng L., Hong R., Liu J., Wang C. and Tian C. (2009). Crystal structure and piezoelectric properties of xPb(Mn1/3Nb2/3)O3–(0.2 x)Pb(Zn1/3Nb2/3)O3–0.8Pb(Zr0.52Ti0.48)O3 ceramic, Ceramics International 35, 1719–1723.
[3]	Yuhuan Xu (1991). Ferroelctric Materials and Their Applications (North-Holland, Amsterdam-London-Newyork-Tokyo).
[4]	Yoo J., Lee Y., Yoon K., Hwang S., Suh S., Kim J. and Yoo C. (2001). Microstructural, Electrical Properties and Temperature Stability of Resonant Frequency in Pb(Ni1/2W1/2)O3–Pb(Mn1/3Nb2/3)O3–Pb(Zr,Ti)O3 Ceramics for High-Power Piezoelectric Transformer, Jpn. J. Appl. Phys 40, 3256–3259.
[5]	Houa Y. D., Zhua M. K., Tian C. S., Yan H. (2004). Structure and electrical properties of PMZN–PZT quaternary ceramics for piezoelectric transformers, Sensors and Actuators A 116, 455–460.
[6]	Yoo J. and Lee. S. (2009). Piezoelectric and Dielectric Properties of Low Temperature Sintered Pb(Mn1/3Nb2/3)0.02(Ni1/3Nb2/3)0.12(ZrxTi1-x)0.86O3 System Ceramics, Transactions on electrical and electronic materials 10, 121-125.
[7]	Lee J. S., Choi M. S., Nguyen V. H. Kim Y. S, Kim I. W., Park E. C., Jeong S. J., Song J. S. (2007). Effects of high energy ball-milling on the sintering behavior and piezoelectric properties of PZT-based ceramics, Ceramics International 33, 1283–1286.
[8]	Material safety data sheet, Lithium Carbonate, Chengdu Chemphys Chemical Industry Co., Lt d., Development Park, Wenjiang, Chengdu, Sichuan, 611137, P. R. China.
[9]	Han H. S., Park E. C., and Lee J. S. (2011). Low-Firing Pb(Zr,Ti)O3-Based Multilayer Ceramic Actuators Using Ag Inner Electrode, Transactions on electrical and electronic materials 12, 249-252.
[10]	Hou Y. D., Chang L. M., Zhu M. K., Song X. M. and Yan H. (2007). Effect of Li2CO3 addition on the dielectric and piezoelectric responses in the low-temperature sintered 0.5PZN–0.5PZT systems, Journal of applied physics 102, 084507(1)-084507(7).
[11]	Le Dai Vuong, Phan Dinh Gio, Truong Van Chuong, Dung Thi Hoai Trang, Duong Viet Hung, Nguyen Trung Duong (2013). Effect of Zr/Ti Ratio Content on Some Physical Properties of Low Temperature Sintering PZT PZN PMnN Ceramics, International Journal of Materials and Chemistry 2013, 3(2): 39-43.
[12]	Kang S. H. & Ahn C. W. & Lee H. J. & Kim I. W. & Park E. C. & Lee J. S. (2008). Dielectric and pyroelectric properties of Li2CO3 doped 0.2Pb(Mg1/3Nb2/3)O3 – 0.5Pb(Zr0.48Ti0.52)O3 –0.3Pb(Fe1/3Nb2/3)O3 ceramics, J Electroceram 21, 855–858.

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APA Style

Le Dai Vuong, Phan Dinh Gio. (2013). Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. International Journal of Materials Science and Applications, 2(3), 89-93. https://doi.org/10.11648/j.ijmsa.20130203.13

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ACS Style

Le Dai Vuong; Phan Dinh Gio. Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. Int. J. Mater. Sci. Appl. 2013, 2(3), 89-93. doi: 10.11648/j.ijmsa.20130203.13

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AMA Style

Le Dai Vuong, Phan Dinh Gio. Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. Int J Mater Sci Appl. 2013;2(3):89-93. doi: 10.11648/j.ijmsa.20130203.13

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@article{10.11648/j.ijmsa.20130203.13,
  author = {Le Dai Vuong and Phan Dinh Gio},
  title = {Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {3},
  pages = {89-93},
  doi = {10.11648/j.ijmsa.20130203.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130203.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130203.13},
  abstract = {The 0.8Pb(Zr0.48Ti0.52)]O3–0.125Pb(Zn1/3Nb2/3)O3–0.075Pb(Mn1/3Nb2/3)O3 + x wt% Li2CO3 ceramics (PZT-PZN-PMnN), where x = 0  1.0, has been prepared by two-stage calcinations method. The Li2CO3 addition significantly improved the sinterability of the ceramics, resulting in a reduction of sintering temperature from 1150 0C to 930 0C. The effect of the Li2CO3 addition on the sintering behavior and physical properties of ceramic samples have been investigated. Experimental results showed that all samples have pure perovskite phase with tetragonal structure, the c/a ratio increases with increasing of Li2CO3 content. At x = 0.7, electrical properties of ceramics are best: the density () of 7.86 g/cm3, the electromechanical coupling factor, kp = 0.64 and kt = 0.51, the dielectric constant, ε = 1320, the dielectric loss (tan) of 0.005, the mechanical quality factor (Qm) of 1150, the piezoelectric constant (d31) of 145 pC/N, and the remanent polarization (Pr) of 30.5 C/cm2, which makes it as a promising material for high power piezoelectric devices.},
 year = {2013}
}

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TY  - JOUR
T1  - Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics
AU  - Le Dai Vuong
AU  - Phan Dinh Gio
Y1  - 2013/06/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130203.13
DO  - 10.11648/j.ijmsa.20130203.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 89
EP  - 93
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130203.13
AB  - The 0.8Pb(Zr0.48Ti0.52)]O3–0.125Pb(Zn1/3Nb2/3)O3–0.075Pb(Mn1/3Nb2/3)O3 + x wt% Li2CO3 ceramics (PZT-PZN-PMnN), where x = 0  1.0, has been prepared by two-stage calcinations method. The Li2CO3 addition significantly improved the sinterability of the ceramics, resulting in a reduction of sintering temperature from 1150 0C to 930 0C. The effect of the Li2CO3 addition on the sintering behavior and physical properties of ceramic samples have been investigated. Experimental results showed that all samples have pure perovskite phase with tetragonal structure, the c/a ratio increases with increasing of Li2CO3 content. At x = 0.7, electrical properties of ceramics are best: the density () of 7.86 g/cm3, the electromechanical coupling factor, kp = 0.64 and kt = 0.51, the dielectric constant, ε = 1320, the dielectric loss (tan) of 0.005, the mechanical quality factor (Qm) of 1150, the piezoelectric constant (d31) of 145 pC/N, and the remanent polarization (Pr) of 30.5 C/cm2, which makes it as a promising material for high power piezoelectric devices.
VL  - 2
IS  - 3
ER  -

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Author Information

Le Dai Vuong

Department of Physics, College of Sciences, Hue University, Vietnam
Phan Dinh Gio

Department of Physics, College of Sciences, Hue University, Vietnam

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APA Style

Le Dai Vuong, Phan Dinh Gio. (2013). Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. International Journal of Materials Science and Applications, 2(3), 89-93. https://doi.org/10.11648/j.ijmsa.20130203.13

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ACS Style

Le Dai Vuong; Phan Dinh Gio. Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. Int. J. Mater. Sci. Appl. 2013, 2(3), 89-93. doi: 10.11648/j.ijmsa.20130203.13

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AMA Style

Le Dai Vuong, Phan Dinh Gio. Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics. Int J Mater Sci Appl. 2013;2(3):89-93. doi: 10.11648/j.ijmsa.20130203.13

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@article{10.11648/j.ijmsa.20130203.13,
  author = {Le Dai Vuong and Phan Dinh Gio},
  title = {Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {3},
  pages = {89-93},
  doi = {10.11648/j.ijmsa.20130203.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130203.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130203.13},
  abstract = {The 0.8Pb(Zr0.48Ti0.52)]O3–0.125Pb(Zn1/3Nb2/3)O3–0.075Pb(Mn1/3Nb2/3)O3 + x wt% Li2CO3 ceramics (PZT-PZN-PMnN), where x = 0  1.0, has been prepared by two-stage calcinations method. The Li2CO3 addition significantly improved the sinterability of the ceramics, resulting in a reduction of sintering temperature from 1150 0C to 930 0C. The effect of the Li2CO3 addition on the sintering behavior and physical properties of ceramic samples have been investigated. Experimental results showed that all samples have pure perovskite phase with tetragonal structure, the c/a ratio increases with increasing of Li2CO3 content. At x = 0.7, electrical properties of ceramics are best: the density () of 7.86 g/cm3, the electromechanical coupling factor, kp = 0.64 and kt = 0.51, the dielectric constant, ε = 1320, the dielectric loss (tan) of 0.005, the mechanical quality factor (Qm) of 1150, the piezoelectric constant (d31) of 145 pC/N, and the remanent polarization (Pr) of 30.5 C/cm2, which makes it as a promising material for high power piezoelectric devices.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Effect of Li2CO3 Addition on the Sintering Behavior and Physical Properties of PZT-PZN-Pmnn Ceramics
AU  - Le Dai Vuong
AU  - Phan Dinh Gio
Y1  - 2013/06/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130203.13
DO  - 10.11648/j.ijmsa.20130203.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 89
EP  - 93
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130203.13
AB  - The 0.8Pb(Zr0.48Ti0.52)]O3–0.125Pb(Zn1/3Nb2/3)O3–0.075Pb(Mn1/3Nb2/3)O3 + x wt% Li2CO3 ceramics (PZT-PZN-PMnN), where x = 0  1.0, has been prepared by two-stage calcinations method. The Li2CO3 addition significantly improved the sinterability of the ceramics, resulting in a reduction of sintering temperature from 1150 0C to 930 0C. The effect of the Li2CO3 addition on the sintering behavior and physical properties of ceramic samples have been investigated. Experimental results showed that all samples have pure perovskite phase with tetragonal structure, the c/a ratio increases with increasing of Li2CO3 content. At x = 0.7, electrical properties of ceramics are best: the density () of 7.86 g/cm3, the electromechanical coupling factor, kp = 0.64 and kt = 0.51, the dielectric constant, ε = 1320, the dielectric loss (tan) of 0.005, the mechanical quality factor (Qm) of 1150, the piezoelectric constant (d31) of 145 pC/N, and the remanent polarization (Pr) of 30.5 C/cm2, which makes it as a promising material for high power piezoelectric devices.
VL  - 2
IS  - 3
ER  -

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