Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath; Tungabidya Maharana

doi:doi:10.11648/j.ijmsa.20130204.13

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Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, Tungabidya Maharana

Received: 2 July 2013 Accepted: Published: 10 August 2013

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Abstract

The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.

DOI	10.11648/j.ijmsa.20130204.13
Published in	International Journal of Materials Science and Applications (Volume 2, Issue 4, July 2013)
Page(s)	136-145
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Schiff Base, Polymer Support, Catalysis, Nickel, Phenol, Oxidation

References

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Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. (2013). Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. International Journal of Materials Science and Applications, 2(4), 136-145. https://doi.org/10.11648/j.ijmsa.20130204.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int. J. Mater. Sci. Appl. 2013, 2(4), 136-145. doi: 10.11648/j.ijmsa.20130204.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int J Mater Sci Appl. 2013;2(4):136-145. doi: 10.11648/j.ijmsa.20130204.13

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@article{10.11648/j.ijmsa.20130204.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattnaik and Nibedita Nath and Prasanta Rath and Tungabidya Maharana},
  title = {Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {4},
  pages = {136-145},
  doi = {10.11648/j.ijmsa.20130204.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130204.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130204.13},
  abstract = {The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattnaik
AU  - Nibedita Nath
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130204.13
DO  - 10.11648/j.ijmsa.20130204.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 136
EP  - 145
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130204.13
AB  - The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.
VL  - 2
IS  - 4
ER  -

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Author Information

Alekha Kumar Sutar

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Yasobanta Das

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Sasmita Pattnaik

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Nibedita Nath

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Prasanta Rath

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Tungabidya Maharana

Department of Chemistry, National Institute of Technology, Raipur, India

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APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. (2013). Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. International Journal of Materials Science and Applications, 2(4), 136-145. https://doi.org/10.11648/j.ijmsa.20130204.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattnaik; Nibedita Nath; Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int. J. Mater. Sci. Appl. 2013, 2(4), 136-145. doi: 10.11648/j.ijmsa.20130204.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Nibedita Nath, Prasanta Rath, et al. Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol. Int J Mater Sci Appl. 2013;2(4):136-145. doi: 10.11648/j.ijmsa.20130204.13

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@article{10.11648/j.ijmsa.20130204.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattnaik and Nibedita Nath and Prasanta Rath and Tungabidya Maharana},
  title = {Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol},
  journal = {International Journal of Materials Science and Applications},
  volume = {2},
  number = {4},
  pages = {136-145},
  doi = {10.11648/j.ijmsa.20130204.13},
  url = {https://doi.org/10.11648/j.ijmsa.20130204.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20130204.13},
  abstract = {The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattnaik
AU  - Nibedita Nath
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/08/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ijmsa.20130204.13
DO  - 10.11648/j.ijmsa.20130204.13
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 136
EP  - 145
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20130204.13
AB  - The free and polymer anchored complex of nickel [3-MHBdMBn-Ni and P-3-MHBdMBn-Ni], supported by -ONNO-tetradentate Schiff-base ligand are prepared by the reactions of nickel solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveal that nickel (II) complex of 3-MHBdMBn Schiff base is square planar in geometry. Complexation of nickel ion increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activity of nickel complex towards the oxidation of phenol is investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-Ni is dramatically affected by the polymer support over 3-MHBdMBn-Ni and the rate of oxidation (Rp) for unsupported one is 1.28 x 10-6 mole dm-3 s-1 and for supported analogue is 1.99 x 10-6 mole dm-3 s-1.
VL  - 2
IS  - 4
ER  -

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