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Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives

Received: 7 October 2017     Accepted: 23 October 2017     Published: 26 March 2018
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Abstract

Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.

Published in International Journal of Materials Science and Applications (Volume 7, Issue 2)
DOI 10.11648/j.ijmsa.20180702.13
Page(s) 49-57
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Fused Heterocycles, 1,2,4-triazoles, tris[1,2,4]triazolo[1,3,5]triazine, 1,3,5-triazines, Benzotriazole Nitrogen Oxides, Synthetic Methods

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  • APA Style

    Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. (2018). Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. International Journal of Materials Science and Applications, 7(2), 49-57. https://doi.org/10.11648/j.ijmsa.20180702.13

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    ACS Style

    Yanyang Qu; Qun Zeng; Jun Wang; Guijuan Fan; Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int. J. Mater. Sci. Appl. 2018, 7(2), 49-57. doi: 10.11648/j.ijmsa.20180702.13

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    AMA Style

    Yanyang Qu, Qun Zeng, Jun Wang, Guijuan Fan, Jinglun Huang, et al. Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives. Int J Mater Sci Appl. 2018;7(2):49-57. doi: 10.11648/j.ijmsa.20180702.13

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  • @article{10.11648/j.ijmsa.20180702.13,
      author = {Yanyang Qu and Qun Zeng and Jun Wang and Guijuan Fan and Jinglun Huang and Gaungchen Yang},
      title = {Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives},
      journal = {International Journal of Materials Science and Applications},
      volume = {7},
      number = {2},
      pages = {49-57},
      doi = {10.11648/j.ijmsa.20180702.13},
      url = {https://doi.org/10.11648/j.ijmsa.20180702.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20180702.13},
      abstract = {Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Synthesis and Properties for Benzotriazole Nitrogen Oxides (BTzO) and Tris[1,2,4]triazolo[1,3,5]triazine Derivatives
    AU  - Yanyang Qu
    AU  - Qun Zeng
    AU  - Jun Wang
    AU  - Guijuan Fan
    AU  - Jinglun Huang
    AU  - Gaungchen Yang
    Y1  - 2018/03/26
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ijmsa.20180702.13
    DO  - 10.11648/j.ijmsa.20180702.13
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 49
    EP  - 57
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20180702.13
    AB  - Herein we first report a novel method of synthesis fused ring nitrogen-enriched compounds by intramolecular cyclization reaction. Some of them were characterized by IR, 1H and 13C NMR spectroscopy. Most of them exhibit outstanding positive heat of formation (155-376 kJ/mol). Densities of these compounds fall in the range between 1.7321-1.8847 g.cm-1, which places them in a class of relatively dense energetic materials. Their physical properties were evaluated by Gaussian 09, and EXPLO5 6.02 calculations. Their detonation velocities and pressures were calculated to fall in the range of 6713-8441 m.s-1 and 14.47-30.61 Gpa.
    VL  - 7
    IS  - 2
    ER  - 

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Author Information
  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

  • Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, China

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