Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals

Xiaohong Yang; Jingjing Cao; Shanshan Hu

doi:doi:10.11648/j.ijmsa.20160502.14

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Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF₂ and CaF₂:Ln³⁺ (Ln = Eu, Tb, Ce/Tb) Microcrystals

Xiaohong Yang, Jingjing Cao, Shanshan Hu

Published in International Journal of Materials Science and Applications (Volume 5, Issue 2)

Received: 8 April 2016 Accepted: Published: 9 April 2016

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Abstract

Spherical CaF₂ and CaF₂:Ln³⁺ (Ln = Eu, Tb, Ce/Tb) with tunable particle size (about 2.5 µm) have been synthesized by one-step facile and effective hydrothermal method. The spherical structure was highly uniform and well-dispersed. It was found that reaction time, pH value, and reaction temperature have important effects on the controlled synthesis of spherical CaF₂. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), photo-luminescence (PL) and luminescence decay curve. Under UV excitation, the CaF₂:Eu³⁺ showed the red emission (⁵D₀→⁷F_{J = 0, 1, 2, 3}) and the CaF₂:Tb³⁺ presented the green emission (⁵D₄→⁷F_{J = 6, 5, 4, 3}), respectively. Furthermore, Ce³⁺/Tb³⁺ co-doped CaF₂ showed efficient energy transfer from Ce³⁺ to Tb³⁺, which presented strong green photo-luminescence of Tb³⁺. Due to excellent luminescent properties, the obtained samples can be used in many fields, such as light display systems, optoelectronic devices and biological imaging.

Published in	International Journal of Materials Science and Applications (Volume 5, Issue 2)
DOI	10.11648/j.ijmsa.20160502.14
Page(s)	54-60
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

CaF₂, Hydrothermal Synthesis, Ce→Tb Energy Transfer, Spherical, Luminescence Properties

References

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APA Style

Xiaohong Yang, Jingjing Cao, Shanshan Hu. (2016). Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. International Journal of Materials Science and Applications, 5(2), 54-60. https://doi.org/10.11648/j.ijmsa.20160502.14

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ACS Style

Xiaohong Yang; Jingjing Cao; Shanshan Hu. Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. Int. J. Mater. Sci. Appl. 2016, 5(2), 54-60. doi: 10.11648/j.ijmsa.20160502.14

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AMA Style

Xiaohong Yang, Jingjing Cao, Shanshan Hu. Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. Int J Mater Sci Appl. 2016;5(2):54-60. doi: 10.11648/j.ijmsa.20160502.14

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@article{10.11648/j.ijmsa.20160502.14,
  author = {Xiaohong Yang and Jingjing Cao and Shanshan Hu},
  title = {Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals},
  journal = {International Journal of Materials Science and Applications},
  volume = {5},
  number = {2},
  pages = {54-60},
  doi = {10.11648/j.ijmsa.20160502.14},
  url = {https://doi.org/10.11648/j.ijmsa.20160502.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20160502.14},
  abstract = {Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) with tunable particle size (about 2.5 µm) have been synthesized by one-step facile and effective hydrothermal method. The spherical structure was highly uniform and well-dispersed. It was found that reaction time, pH value, and reaction temperature have important effects on the controlled synthesis of spherical CaF2. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), photo-luminescence (PL) and luminescence decay curve. Under UV excitation, the CaF2:Eu3+ showed the red emission (5D0→7FJ = 0, 1, 2, 3) and the CaF2:Tb3+ presented the green emission (5D4→7FJ = 6, 5, 4, 3), respectively. Furthermore, Ce3+/Tb3+ co-doped CaF2 showed efficient energy transfer from Ce3+ to Tb3+, which presented strong green photo-luminescence of Tb3+. Due to excellent luminescent properties, the obtained samples can be used in many fields, such as light display systems, optoelectronic devices and biological imaging.},
 year = {2016}
}

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TY  - JOUR
T1  - Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals
AU  - Xiaohong Yang
AU  - Jingjing Cao
AU  - Shanshan Hu
Y1  - 2016/04/09
PY  - 2016
N1  - https://doi.org/10.11648/j.ijmsa.20160502.14
DO  - 10.11648/j.ijmsa.20160502.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 54
EP  - 60
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20160502.14
AB  - Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) with tunable particle size (about 2.5 µm) have been synthesized by one-step facile and effective hydrothermal method. The spherical structure was highly uniform and well-dispersed. It was found that reaction time, pH value, and reaction temperature have important effects on the controlled synthesis of spherical CaF2. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), photo-luminescence (PL) and luminescence decay curve. Under UV excitation, the CaF2:Eu3+ showed the red emission (5D0→7FJ = 0, 1, 2, 3) and the CaF2:Tb3+ presented the green emission (5D4→7FJ = 6, 5, 4, 3), respectively. Furthermore, Ce3+/Tb3+ co-doped CaF2 showed efficient energy transfer from Ce3+ to Tb3+, which presented strong green photo-luminescence of Tb3+. Due to excellent luminescent properties, the obtained samples can be used in many fields, such as light display systems, optoelectronic devices and biological imaging.
VL  - 5
IS  - 2
ER  -

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Author Information

Xiaohong Yang

School of Chemistry and Chemical Engineering, Southwest University, Chongqing, China
Jingjing Cao

School of Chemistry and Chemical Engineering, Southwest University, Chongqing, China
Shanshan Hu

School of Chemistry and Chemical Engineering, Southwest University, Chongqing, China

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APA Style

Xiaohong Yang, Jingjing Cao, Shanshan Hu. (2016). Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. International Journal of Materials Science and Applications, 5(2), 54-60. https://doi.org/10.11648/j.ijmsa.20160502.14

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ACS Style

Xiaohong Yang; Jingjing Cao; Shanshan Hu. Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. Int. J. Mater. Sci. Appl. 2016, 5(2), 54-60. doi: 10.11648/j.ijmsa.20160502.14

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AMA Style

Xiaohong Yang, Jingjing Cao, Shanshan Hu. Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals. Int J Mater Sci Appl. 2016;5(2):54-60. doi: 10.11648/j.ijmsa.20160502.14

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@article{10.11648/j.ijmsa.20160502.14,
  author = {Xiaohong Yang and Jingjing Cao and Shanshan Hu},
  title = {Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals},
  journal = {International Journal of Materials Science and Applications},
  volume = {5},
  number = {2},
  pages = {54-60},
  doi = {10.11648/j.ijmsa.20160502.14},
  url = {https://doi.org/10.11648/j.ijmsa.20160502.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20160502.14},
  abstract = {Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) with tunable particle size (about 2.5 µm) have been synthesized by one-step facile and effective hydrothermal method. The spherical structure was highly uniform and well-dispersed. It was found that reaction time, pH value, and reaction temperature have important effects on the controlled synthesis of spherical CaF2. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), photo-luminescence (PL) and luminescence decay curve. Under UV excitation, the CaF2:Eu3+ showed the red emission (5D0→7FJ = 0, 1, 2, 3) and the CaF2:Tb3+ presented the green emission (5D4→7FJ = 6, 5, 4, 3), respectively. Furthermore, Ce3+/Tb3+ co-doped CaF2 showed efficient energy transfer from Ce3+ to Tb3+, which presented strong green photo-luminescence of Tb3+. Due to excellent luminescent properties, the obtained samples can be used in many fields, such as light display systems, optoelectronic devices and biological imaging.},
 year = {2016}
}

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TY  - JOUR
T1  - Hydrothermal Synthesis and Luminescence Properties of Monodisperse Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) Microcrystals
AU  - Xiaohong Yang
AU  - Jingjing Cao
AU  - Shanshan Hu
Y1  - 2016/04/09
PY  - 2016
N1  - https://doi.org/10.11648/j.ijmsa.20160502.14
DO  - 10.11648/j.ijmsa.20160502.14
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 54
EP  - 60
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20160502.14
AB  - Spherical CaF2 and CaF2:Ln3+ (Ln = Eu, Tb, Ce/Tb) with tunable particle size (about 2.5 µm) have been synthesized by one-step facile and effective hydrothermal method. The spherical structure was highly uniform and well-dispersed. It was found that reaction time, pH value, and reaction temperature have important effects on the controlled synthesis of spherical CaF2. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), photo-luminescence (PL) and luminescence decay curve. Under UV excitation, the CaF2:Eu3+ showed the red emission (5D0→7FJ = 0, 1, 2, 3) and the CaF2:Tb3+ presented the green emission (5D4→7FJ = 6, 5, 4, 3), respectively. Furthermore, Ce3+/Tb3+ co-doped CaF2 showed efficient energy transfer from Ce3+ to Tb3+, which presented strong green photo-luminescence of Tb3+. Due to excellent luminescent properties, the obtained samples can be used in many fields, such as light display systems, optoelectronic devices and biological imaging.
VL  - 5
IS  - 2
ER  -

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