International Journal of Materials Science and Applications

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Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water

Received: 2 August 2017    Accepted: 15 August 2017    Published: 28 August 2017
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Abstract

The elements Be, Bi, Mg, Pb, Zr, Al, Ca, Na, Sn, Rb and Ce are the metallic elements of small thermal neutron absorption cross section. Except Be and Zr, they are all soft metals. But the reasons for these small thermal neutron absorption cross-sections are not known. To clarify its mechanism, the thermal neutron absorption cross-sections of elements were plotted on the TC-YM diagram. They lie on a line connecting the elements of low Young’s modulus on the TC-YM diagram. The author at first considered that the neutron absorption characteristics of elements relate to the neutron multiple number which means the number of neutrons per proton in the nucleus. The absorption cross-section of elements roughly increases with increasing neutron multiple number. Among the elements of small neutron absorption cross section, only Zr and Be are the elements of high melting temperature. Zr should not show the small neutron absorption cross section inherently. But in fact, Zr is exceptional both on the TC-YM diagram and in the neutron multiple number. Zr has a small absorption cross-section against the general trends in both the TC-YM diagram and neutron multiple number. On the other hand, the corrosion resistance of Zircaloy is given by the anodic protection provided by the precipitates of metallic compounds containing Fe and Cr. It is fortunate that Fe and Cr belong to the element group of the metals nobler than Zr and that of no solubility in Zr on the TC-YM diagram.

DOI 10.11648/j.ijmsa.20170605.12
Published in International Journal of Materials Science and Applications (Volume 6, Issue 5, September 2017)
Page(s) 235-240
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Thermal Neutron Absorption Cross Section, Neutron, Proton, Young’s Modulus, Thermal Conductivity, Anodic Protection, Zr

References
[1] T. Isobe, T, Murai, and Y. Mae, “Anodic protection provided by precipitates in aqueous corrosion of Zircaloy,” Zirconium in the nuclear industry: 11th Symposium, ASTM, pp. 203-216, 1999.
[2] Y. Mae, “What the Darken-Gurry plot means about the solubility of elements in metals,” Metall. Mater. Trans. A, vol. 47, pp. 6498-6506, Dec. 2016.
[3] Y. Mae, “Anthropic principle observed in the material properties of Fe,” J. Mater. Sci. Res., vol. 6, No. 3, pp. 11-19, 2017.
[4] Y. Mae, “Schematic Interpretation of anomalies in the Physical Properties of Eu and Yb among the lanthanides,” Int. J. Mater. Sci. App., vol. 6, pp. 165-170, 2017.
[5] Y. Mae, “Neutron multiple number as a factor ruling both the abundance and some material properties of elements,” J. Mater. Sci. Res., Vol. 6, No. 3, pp. 37-42, 2017.
[6] Y. Mae, “Correlation of the effects of alloying elements on the hardenability of steels to the diffusion coefficients of elements in Fe,” Int. J. Mater. Sci. App., Vol. 6, No. 4, pp. 200-206, 2017.
[7] Japan Atomic Energy Research Institute, Data sheet JAERI 6010, 1962.
[8] http://en.wikipedia.org/wiki/Zirconium
[9] H. Sakurai, New knowledge about 111 elements, Koudan-sha, 1997, pp. 201.
[10] S. Nagakura, etc., Dictionary of physics and chemistry, Iwanami, 1998, p. 667.
[11] R. W. Bauer, J. D. Anderson, S. M. Grimes and V. A. Maden, “Application of Simple Ramsauer Model to Neutron Total Cross Section,” UCRL_JC_127199, 1997.
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    Yoshiharu Mae. (2017). Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water. International Journal of Materials Science and Applications, 6(5), 235-240. https://doi.org/10.11648/j.ijmsa.20170605.12

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    ACS Style

    Yoshiharu Mae. Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water. Int. J. Mater. Sci. Appl. 2017, 6(5), 235-240. doi: 10.11648/j.ijmsa.20170605.12

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    AMA Style

    Yoshiharu Mae. Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water. Int J Mater Sci Appl. 2017;6(5):235-240. doi: 10.11648/j.ijmsa.20170605.12

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  • @article{10.11648/j.ijmsa.20170605.12,
      author = {Yoshiharu Mae},
      title = {Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water},
      journal = {International Journal of Materials Science and Applications},
      volume = {6},
      number = {5},
      pages = {235-240},
      doi = {10.11648/j.ijmsa.20170605.12},
      url = {https://doi.org/10.11648/j.ijmsa.20170605.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20170605.12},
      abstract = {The elements Be, Bi, Mg, Pb, Zr, Al, Ca, Na, Sn, Rb and Ce are the metallic elements of small thermal neutron absorption cross section. Except Be and Zr, they are all soft metals. But the reasons for these small thermal neutron absorption cross-sections are not known. To clarify its mechanism, the thermal neutron absorption cross-sections of elements were plotted on the TC-YM diagram. They lie on a line connecting the elements of low Young’s modulus on the TC-YM diagram. The author at first considered that the neutron absorption characteristics of elements relate to the neutron multiple number which means the number of neutrons per proton in the nucleus. The absorption cross-section of elements roughly increases with increasing neutron multiple number. Among the elements of small neutron absorption cross section, only Zr and Be are the elements of high melting temperature. Zr should not show the small neutron absorption cross section inherently. But in fact, Zr is exceptional both on the TC-YM diagram and in the neutron multiple number. Zr has a small absorption cross-section against the general trends in both the TC-YM diagram and neutron multiple number. On the other hand, the corrosion resistance of Zircaloy is given by the anodic protection provided by the precipitates of metallic compounds containing Fe and Cr. It is fortunate that Fe and Cr belong to the element group of the metals nobler than Zr and that of no solubility in Zr on the TC-YM diagram.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Peculiarity of Zr in the Neutron Absorption Cross-section and Corrosion Resistance in Water
    AU  - Yoshiharu Mae
    Y1  - 2017/08/28
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ijmsa.20170605.12
    DO  - 10.11648/j.ijmsa.20170605.12
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 235
    EP  - 240
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20170605.12
    AB  - The elements Be, Bi, Mg, Pb, Zr, Al, Ca, Na, Sn, Rb and Ce are the metallic elements of small thermal neutron absorption cross section. Except Be and Zr, they are all soft metals. But the reasons for these small thermal neutron absorption cross-sections are not known. To clarify its mechanism, the thermal neutron absorption cross-sections of elements were plotted on the TC-YM diagram. They lie on a line connecting the elements of low Young’s modulus on the TC-YM diagram. The author at first considered that the neutron absorption characteristics of elements relate to the neutron multiple number which means the number of neutrons per proton in the nucleus. The absorption cross-section of elements roughly increases with increasing neutron multiple number. Among the elements of small neutron absorption cross section, only Zr and Be are the elements of high melting temperature. Zr should not show the small neutron absorption cross section inherently. But in fact, Zr is exceptional both on the TC-YM diagram and in the neutron multiple number. Zr has a small absorption cross-section against the general trends in both the TC-YM diagram and neutron multiple number. On the other hand, the corrosion resistance of Zircaloy is given by the anodic protection provided by the precipitates of metallic compounds containing Fe and Cr. It is fortunate that Fe and Cr belong to the element group of the metals nobler than Zr and that of no solubility in Zr on the TC-YM diagram.
    VL  - 6
    IS  - 5
    ER  - 

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Author Information
  • Maetech, Mimuro, Midori Ward, Saitama City, Japan

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