International Journal of Materials Science and Applications

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Preparation and Characterization of Phosphate Material Doped with Chromium

Received: 01 October 2017    Accepted: 10 October 2017    Published: 07 November 2017
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Abstract

The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured.

DOI 10.11648/j.ijmsa.s.2018070101.13
Published in International Journal of Materials Science and Applications (Volume 7, Issue 1-1, January 2018)

This article belongs to the Special Issue Energy and Materials II

Page(s) 11-17
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Chemical Durability, IR Spectroscopy, Differential Scanning Calorimetry, Glass Formation, Sodium-Chromium-Iron-Phosphate Glasses, XRD

References
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[8] Y. Makhkhas and E. H. Sayouty “CHEMICAL DURABILITY AND CHARACTERIZATION OF THE PHOSPHATE GLASSES CONTAINING IRON, SODIUM AND CHROMIUM” International Journal of Advances in Chemistry (IJAC) Vol. 2, No. 1, 23-29.
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Author Information
  • Faculty of Science, High Energy and Condensed Matter Lab, Hassan II University of Casablanca, Casablanca, Morocco

  • Faculty of Science, Physico Chemistry of Inorganic Materials Lab, Hassan II University of Casablanca, Morocco

  • Ecole Normale Supérieure de Rabat, Physico Chemistry of Inorganic and Organic Materials Lab, Université Mohammed V, Rabat, Morocco

  • Faculty of Science, High Energy and Condensed Matter Lab, Hassan II University of Casablanca, Casablanca, Morocco

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  • APA Style

    Youssef Makhkhas, Saida Krimi, Mohamed Taibi, El Hassan Sayouty. (2017). Preparation and Characterization of Phosphate Material Doped with Chromium. International Journal of Materials Science and Applications, 7(1-1), 11-17. https://doi.org/10.11648/j.ijmsa.s.2018070101.13

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    ACS Style

    Youssef Makhkhas; Saida Krimi; Mohamed Taibi; El Hassan Sayouty. Preparation and Characterization of Phosphate Material Doped with Chromium. Int. J. Mater. Sci. Appl. 2017, 7(1-1), 11-17. doi: 10.11648/j.ijmsa.s.2018070101.13

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    AMA Style

    Youssef Makhkhas, Saida Krimi, Mohamed Taibi, El Hassan Sayouty. Preparation and Characterization of Phosphate Material Doped with Chromium. Int J Mater Sci Appl. 2017;7(1-1):11-17. doi: 10.11648/j.ijmsa.s.2018070101.13

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  • @article{10.11648/j.ijmsa.s.2018070101.13,
      author = {Youssef Makhkhas and Saida Krimi and Mohamed Taibi and El Hassan Sayouty},
      title = {Preparation and Characterization of Phosphate Material Doped with Chromium},
      journal = {International Journal of Materials Science and Applications},
      volume = {7},
      number = {1-1},
      pages = {11-17},
      doi = {10.11648/j.ijmsa.s.2018070101.13},
      url = {https://doi.org/10.11648/j.ijmsa.s.2018070101.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijmsa.s.2018070101.13},
      abstract = {The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Preparation and Characterization of Phosphate Material Doped with Chromium
    AU  - Youssef Makhkhas
    AU  - Saida Krimi
    AU  - Mohamed Taibi
    AU  - El Hassan Sayouty
    Y1  - 2017/11/07
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ijmsa.s.2018070101.13
    DO  - 10.11648/j.ijmsa.s.2018070101.13
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 11
    EP  - 17
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.s.2018070101.13
    AB  - The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured.
    VL  - 7
    IS  - 1-1
    ER  - 

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