International Journal of Materials Science and Applications

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The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect

Received: 28 May 2018    Accepted: 23 July 2018    Published: 17 August 2018
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Abstract

Silicone materials have excellent weathering resistance, high and low temperature resistance, anti-yellowing and a series of excellent properties over other materials. In this study vinyl silicone oil as the base polymer, hydrogen silicone oil as a cross-linking agent, vinyl silicone resin and ultraviolet absorber as additives, platinum complex as a catalyst, were used to make ultraviolet absorption of highly transparent silicone rubber. Different structures of silicone resin with vinyl group have different effects on the curing speed of the products. The silicone resin with MMViQ can help achieve rapid curing speed. Due to polarity difference for polysiloxane system and ultraviolet absorber, when necessary a suitable organic solvent may be introduced to increase the compatibility of the ultraviolet absorber with the silicone composition to prepare transparent products. Considering that the addition of organic solvents may have effects such as volatiles and properties, the amount of solvent introduced should be as low as possible. In addition, regarding the amount of the ultraviolet absorber added, too little ultraviolet absorber may not achieve a satisfactory ultraviolet absorption effect, but too much would lead to an increase in the amount of solvent introduced. Different ultraviolet absorber could induce different ultraviolet absorption effect and aging resistance.

DOI 10.11648/j.ijmsa.20180704.14
Published in International Journal of Materials Science and Applications (Volume 7, Issue 4, July 2018)
Page(s) 142-146
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Vinyl Silicone Resin, Light Transmittance, Ultraviolet Absorber, Rapid Vulcanization

References
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[3] J.-H. Lee, S.-J. Park, S.-H. Hwang, B.-J. Mun, H.-S. Song, “Resin Composition for Optical Material and Optical Film Comprising the Same,” KR20180018334A [P], February 21 2018.
[4] H. Kametani, S. Ogi, K. Imazumi, N. Kiyoyanagi, J. Ichikawa, T. Mizu, guchi, R. Shitara, “(Meth) acrylate Compound, Resin Composition Containing the Same, Cured Product of the Resin Composition, and Energy Ray-Curable Resin Composition for Optical Lens Sheet and Cured Product thereof,”CN101675089A [P], March 17 2010.
[5] J. Wang, X.-H. Zhang, X.-M. Zhang, X.-L. Kong, C.-C. Li, E.-L. Xiao, Q. Zhang; L.-P. Sun, PVC “Composition Used for Fresnel Lens and Preparation Method,” CN102863709A [P], January 09 2013.
[6] T. G. Pett, T. J. Hebrink, N.-Y. Jing, J. A. Riddle, D. S. Thompson, A. K. Hartzell, J.-K. Liu, “Silicone-Based Material,” CN102918093A [P], February 06 2013.
[7] S.-M. Xing, Y.-L. Wang, “Organic Silicone Synthesis Technology and Product Application,” p.717, 2000.
[8] A. Pouchelon, F. Lafaysse, “Method for Obtaining a Fibrous Material/Silicone Composite and Said Fibrous Material/Silicone Composite,” CN101680162 [P], March 24 2010.
[9] M. Bahadur, R. Nelson, M. Strong, “Silicone Composition for Producing Transparent Silicone Materials and Optical Devices,” CN102414275 [P], April 11 2012.
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[11] T. Yamazaki, T. Kashiwagi, M. Wakao, “Addition-Curable Silicone Resin Composition and Die Attach Material for Optical Semiconductor Device,” CN105924974 [P], September 07 2016.
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[14] L. L Zhang, Z. C. Li, X. Xu, “Ultraviolet-Curable Organic-Silicon Liquid Optical-Adhesive Composition and Preparation Method of Composition,” CN107674640A [P], February 9 2018.
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Author Information
  • Elkem Silicones Shanghai Co., Ltd., Shanghai, China

  • Elkem Silicones Shanghai Co., Ltd., Shanghai, China

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  • APA Style

    Jia Liya, Man Zhongbiao. (2018). The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect. International Journal of Materials Science and Applications, 7(4), 142-146. https://doi.org/10.11648/j.ijmsa.20180704.14

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    ACS Style

    Jia Liya; Man Zhongbiao. The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect. Int. J. Mater. Sci. Appl. 2018, 7(4), 142-146. doi: 10.11648/j.ijmsa.20180704.14

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    AMA Style

    Jia Liya, Man Zhongbiao. The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect. Int J Mater Sci Appl. 2018;7(4):142-146. doi: 10.11648/j.ijmsa.20180704.14

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  • @article{10.11648/j.ijmsa.20180704.14,
      author = {Jia Liya and Man Zhongbiao},
      title = {The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect},
      journal = {International Journal of Materials Science and Applications},
      volume = {7},
      number = {4},
      pages = {142-146},
      doi = {10.11648/j.ijmsa.20180704.14},
      url = {https://doi.org/10.11648/j.ijmsa.20180704.14},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijmsa.20180704.14},
      abstract = {Silicone materials have excellent weathering resistance, high and low temperature resistance, anti-yellowing and a series of excellent properties over other materials. In this study vinyl silicone oil as the base polymer, hydrogen silicone oil as a cross-linking agent, vinyl silicone resin and ultraviolet absorber as additives, platinum complex as a catalyst, were used to make ultraviolet absorption of highly transparent silicone rubber. Different structures of silicone resin with vinyl group have different effects on the curing speed of the products. The silicone resin with MMViQ can help achieve rapid curing speed. Due to polarity difference for polysiloxane system and ultraviolet absorber, when necessary a suitable organic solvent may be introduced to increase the compatibility of the ultraviolet absorber with the silicone composition to prepare transparent products. Considering that the addition of organic solvents may have effects such as volatiles and properties, the amount of solvent introduced should be as low as possible. In addition, regarding the amount of the ultraviolet absorber added, too little ultraviolet absorber may not achieve a satisfactory ultraviolet absorption effect, but too much would lead to an increase in the amount of solvent introduced. Different ultraviolet absorber could induce different ultraviolet absorption effect and aging resistance.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - The Preparation of Transparent Silicone Rubber with Rapid Vulcanization and Ultraviolet Absorbing Effect
    AU  - Jia Liya
    AU  - Man Zhongbiao
    Y1  - 2018/08/17
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ijmsa.20180704.14
    DO  - 10.11648/j.ijmsa.20180704.14
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 142
    EP  - 146
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20180704.14
    AB  - Silicone materials have excellent weathering resistance, high and low temperature resistance, anti-yellowing and a series of excellent properties over other materials. In this study vinyl silicone oil as the base polymer, hydrogen silicone oil as a cross-linking agent, vinyl silicone resin and ultraviolet absorber as additives, platinum complex as a catalyst, were used to make ultraviolet absorption of highly transparent silicone rubber. Different structures of silicone resin with vinyl group have different effects on the curing speed of the products. The silicone resin with MMViQ can help achieve rapid curing speed. Due to polarity difference for polysiloxane system and ultraviolet absorber, when necessary a suitable organic solvent may be introduced to increase the compatibility of the ultraviolet absorber with the silicone composition to prepare transparent products. Considering that the addition of organic solvents may have effects such as volatiles and properties, the amount of solvent introduced should be as low as possible. In addition, regarding the amount of the ultraviolet absorber added, too little ultraviolet absorber may not achieve a satisfactory ultraviolet absorption effect, but too much would lead to an increase in the amount of solvent introduced. Different ultraviolet absorber could induce different ultraviolet absorption effect and aging resistance.
    VL  - 7
    IS  - 4
    ER  - 

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