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Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method

Received: 18 September 2015    Accepted: 04 October 2015    Published: 19 October 2015
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Abstract

Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral.

DOI 10.11648/j.sjc.20150306.12
Published in Science Journal of Chemistry (Volume 3, Issue 6, December 2015)
Page(s) 91-94
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Transition Metal Complex, Bidentate Ligand, Schiff Base

References
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Author Information
  • Department of Material Science and Engineering, Faculty of Engineering, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, Faculty of Science, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, Faculty of Science, University of Rajshahi, Rajshahi, Bangladesh

  • Inorganic Research Laboratory, Department of Chemistry, Faculty of Science, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, Faculty of Science, University of Rajshahi, Rajshahi, Bangladesh

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    Gagi Tauhidur Rahman, Md. Kudrat-E-Zahan, M. M. Haque, Md. Mofasserul Alam, Md. Akhter Farooque. (2015). Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Science Journal of Chemistry, 3(6), 91-94. https://doi.org/10.11648/j.sjc.20150306.12

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    ACS Style

    Gagi Tauhidur Rahman; Md. Kudrat-E-Zahan; M. M. Haque; Md. Mofasserul Alam; Md. Akhter Farooque. Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Sci. J. Chem. 2015, 3(6), 91-94. doi: 10.11648/j.sjc.20150306.12

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    AMA Style

    Gagi Tauhidur Rahman, Md. Kudrat-E-Zahan, M. M. Haque, Md. Mofasserul Alam, Md. Akhter Farooque. Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Sci J Chem. 2015;3(6):91-94. doi: 10.11648/j.sjc.20150306.12

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  • @article{10.11648/j.sjc.20150306.12,
      author = {Gagi Tauhidur Rahman and Md. Kudrat-E-Zahan and M. M. Haque and Md. Mofasserul Alam and Md. Akhter Farooque},
      title = {Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method},
      journal = {Science Journal of Chemistry},
      volume = {3},
      number = {6},
      pages = {91-94},
      doi = {10.11648/j.sjc.20150306.12},
      url = {https://doi.org/10.11648/j.sjc.20150306.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjc.20150306.12},
      abstract = {Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method
    AU  - Gagi Tauhidur Rahman
    AU  - Md. Kudrat-E-Zahan
    AU  - M. M. Haque
    AU  - Md. Mofasserul Alam
    AU  - Md. Akhter Farooque
    Y1  - 2015/10/19
    PY  - 2015
    N1  - https://doi.org/10.11648/j.sjc.20150306.12
    DO  - 10.11648/j.sjc.20150306.12
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 91
    EP  - 94
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20150306.12
    AB  - Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral.
    VL  - 3
    IS  - 6
    ER  - 

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