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Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol

Received: 02 June 2017    Accepted: 11 July 2017    Published: 10 August 2017
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Abstract

An efficient, selective and simple route for the synthesis of 2-Naphthyl acetate has been developed. In reflux conditions the acetylation of 2-naphthol acetylation with a catalytic amount of Nickel nitrate catalysts afforded 2-Naphthyl acetate in moderate to excellent yields. Nickel nitrate showed the best catalytic performance compared to other Nickel salts. Different weights of nickel salts have been evaluated for the title reaction with 30mg NiNO3 afforded the Best conversions. Different acylating reagents were evaluated acetic acid, acetyl chloride and acetic anhydride, and it was observed that acetic acid was the best acetylating reagent. The protocol has advantages including short reaction times, high chemoselectivity towards acylated product simple work-up. Additionally, nickel nitrate, other additives are not required to enhance the reactions.

DOI 10.11648/j.sjc.20170504.11
Published in Science Journal of Chemistry (Volume 5, Issue 4, August 2017)
Page(s) 47-50
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Nickel Nitrate, Acetylation, Homogeneous Catalysts, 2-Naphthol, 2-Naphthyl Acetate

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Author Information
  • Department of Chemistry and Biochemistry, University of Namibia, Windhoek, Namibia

  • Department of Chemistry and Biochemistry, University of Namibia, Windhoek, Namibia

  • Department of Chemistry and Biochemistry, University of Namibia, Windhoek, Namibia

  • Department of Chemistry, Bindura University of Science Education, Bindura, Zimbabwe

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    Ateeq Rahman, Veikko Uahengo, Daniel Shipwiisho Likius, Mathew Mupa. (2017). Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol. Science Journal of Chemistry, 5(4), 47-50. https://doi.org/10.11648/j.sjc.20170504.11

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    ACS Style

    Ateeq Rahman; Veikko Uahengo; Daniel Shipwiisho Likius; Mathew Mupa. Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol. Sci. J. Chem. 2017, 5(4), 47-50. doi: 10.11648/j.sjc.20170504.11

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    AMA Style

    Ateeq Rahman, Veikko Uahengo, Daniel Shipwiisho Likius, Mathew Mupa. Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol. Sci J Chem. 2017;5(4):47-50. doi: 10.11648/j.sjc.20170504.11

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  • @article{10.11648/j.sjc.20170504.11,
      author = {Ateeq Rahman and Veikko Uahengo and Daniel Shipwiisho Likius and Mathew Mupa},
      title = {Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol},
      journal = {Science Journal of Chemistry},
      volume = {5},
      number = {4},
      pages = {47-50},
      doi = {10.11648/j.sjc.20170504.11},
      url = {https://doi.org/10.11648/j.sjc.20170504.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjc.20170504.11},
      abstract = {An efficient, selective and simple route for the synthesis of 2-Naphthyl acetate has been developed. In reflux conditions the acetylation of 2-naphthol acetylation with a catalytic amount of Nickel nitrate catalysts afforded 2-Naphthyl acetate in moderate to excellent yields. Nickel nitrate showed the best catalytic performance compared to other Nickel salts. Different weights of nickel salts have been evaluated for the title reaction with 30mg NiNO3 afforded the Best conversions. Different acylating reagents were evaluated acetic acid, acetyl chloride and acetic anhydride, and it was observed that acetic acid was the best acetylating reagent. The protocol has advantages including short reaction times, high chemoselectivity towards acylated product simple work-up. Additionally, nickel nitrate, other additives are not required to enhance the reactions.},
     year = {2017}
    }
    

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    T1  - Selective Acetylation of 2-Naphthol to 2-Naphthyl Acetate with Ni Homogeneous Catalysts: An Environmentally Friendly Protocol
    AU  - Ateeq Rahman
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    AB  - An efficient, selective and simple route for the synthesis of 2-Naphthyl acetate has been developed. In reflux conditions the acetylation of 2-naphthol acetylation with a catalytic amount of Nickel nitrate catalysts afforded 2-Naphthyl acetate in moderate to excellent yields. Nickel nitrate showed the best catalytic performance compared to other Nickel salts. Different weights of nickel salts have been evaluated for the title reaction with 30mg NiNO3 afforded the Best conversions. Different acylating reagents were evaluated acetic acid, acetyl chloride and acetic anhydride, and it was observed that acetic acid was the best acetylating reagent. The protocol has advantages including short reaction times, high chemoselectivity towards acylated product simple work-up. Additionally, nickel nitrate, other additives are not required to enhance the reactions.
    VL  - 5
    IS  - 4
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