A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes
Science Journal of Chemistry
Volume 2, Issue 6-2, December 2014, Pages: 8-13
Received: Sep. 6, 2014; Accepted: Sep. 23, 2014; Published: Sep. 23, 2014
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Author
Nandini Ratnakar, Department of Chemistry, MITE, Moodabidri-574 226 (DK), Karnataka, India
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Abstract
The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
Keywords
Cationic Dye, Metachromasy, Anionicpolyelectrolytes, Electrostatic Interaction, Aggregation
To cite this article
Nandini Ratnakar, A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes, Science Journal of Chemistry. Special Issue: Polyelectrolytes & Dyes. Vol. 2, No. 6-2, 2014, pp. 8-13. doi: 10.11648/j.sjc.s.2014020602.12
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