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Molecular Aggregations and Induction of Anisotropy by Light in Azodyes

Published in Optics (Volume 4, Issue 2)
Received: 3 July 2015    Accepted: 17 July 2015    Published: 25 July 2015
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Abstract

The anisotropy induction by light in self-induced molecular aggregations ensemble of azodyes has been studied. In the dynamic regime of anisotropy photoinduction the video-microscopy investigations of the film having photoinduced anisotropy in the crossed polarizers have been conducted. It is shown that image formation herein can be carried out in the way of light modulation of the granular anisotropy integral area of the film. According to an active light exposition, both the concentration and sizes of molecular aggregates having photoinduced anisotropy are being modulated.

Published in Optics (Volume 4, Issue 2)
DOI 10.11648/j.optics.20150402.11
Page(s) 13-16
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Anisotropy Photoinduction, Molecular Aggregations

References
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[3] A. M. Makushenko, B. S. Neporent, B. S. Neporent, and O. V. Stolbova, “Reverssible orientational photodichroism and photoisomerization of aromatic azo compounds. I,” Optics and Spectroscopy (USSR), vol. 31, pp. 557–564, 1971.
[4] F. L. Labarthet, S. Freiberg, C. Pellerin, M. Pézolet, A. Natansohn, and P. Rochon, “Spectroscopic and optical characterization of a series of azobenzene-containing side-chain liquid crystalline polymers,” Macromolecules, vol. 33, no. 18, pp. 6815–6823, 2000. View at Publisher View at Google Scholar View at Scopus
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[6] D. Voloschenko and O. D. Lavrentovich, “Light-induced director-controlled microassembly of dye molecules from a liquid crystal matrix,” Journal of Applied Physics, vol. 86, no. 9, pp. 4843–4846, 1999. View at Scopus
[7] B. J. Kim, S. Y. Park, and D. H. Choi, “Effect of molecular aggregation on the photo-induced anisotropy in amorphous polymethacrylate bearing an aminonitroazobenzene moiety,” Bulletin of the Korean Chemical Society, vol. 22, no. 3, pp. 271–275, 2001. View at Scopus
[8] T. D. Ebralidze, N. A. Ebralidze, G. A. Mumladze, and E. S. Kitsmarishvili, “Light-controlled mass formation of aggregates of molecules in organic compounds,” Chinese Optics Letters, vol. 7, no. 9, pp. 823–825, 2009. View at Publisher View at Google Scholar View at Scopus
[9] A. Priimagi, A. Shevchenko, M. Kaivola, F. J. Rodriguez, M. Kauranen, and P. Rochon, “High and stable photoinduced anisotropy in guest-host polymer mediated by chromophore aggregation,” Optics Letters, vol. 35, no. 11, pp. 1813–1815, 2010. View at Publisher View at Google Scholar View at Scopus
[10] T. D. Ebralidze, N. A. Ebralidze, and G. A. Mumladze, "Anisotropy Photoinduction during the Mass Associations of Dye Molecules in Gelatin Films", Journal of Materials, Volume 2013 (2013), Article ID 507938, 3 pages
[11] Tariel Ebralidze, Nadia Ebralidze, Giorgi Mumladze. "Molecular Aggregations and Anisotropy Photoinduction in Organic Compounds", Optics.Vol. 3, No. 4, 2014, pp. 33-36. doi: 10.11648/j.optics.20140304.12
[12] M. Ivanov, L. Nikolova, T. Todorov, “Photoinduced dichroism and birefringence in films of Mordant Pure Yellow/poly(vinil alcohol): simultaneous real-time investigations at two wavelengths”, Optical and Quantum Electronics, November 1994, vol.26, Issue 11, pp.1013-1018, doi: 10.1007/BF00305001.
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  • APA Style

    Tariel Ebralidze, Nadia Ebralidze, Giorgi Mumladze. (2015). Molecular Aggregations and Induction of Anisotropy by Light in Azodyes. Optics, 4(2), 13-16. https://doi.org/10.11648/j.optics.20150402.11

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    ACS Style

    Tariel Ebralidze; Nadia Ebralidze; Giorgi Mumladze. Molecular Aggregations and Induction of Anisotropy by Light in Azodyes. Optics. 2015, 4(2), 13-16. doi: 10.11648/j.optics.20150402.11

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    AMA Style

    Tariel Ebralidze, Nadia Ebralidze, Giorgi Mumladze. Molecular Aggregations and Induction of Anisotropy by Light in Azodyes. Optics. 2015;4(2):13-16. doi: 10.11648/j.optics.20150402.11

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  • @article{10.11648/j.optics.20150402.11,
      author = {Tariel Ebralidze and Nadia Ebralidze and Giorgi Mumladze},
      title = {Molecular Aggregations and Induction of Anisotropy by Light in Azodyes},
      journal = {Optics},
      volume = {4},
      number = {2},
      pages = {13-16},
      doi = {10.11648/j.optics.20150402.11},
      url = {https://doi.org/10.11648/j.optics.20150402.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.optics.20150402.11},
      abstract = {The anisotropy induction by light in self-induced molecular aggregations ensemble of azodyes has been studied. In the dynamic regime of anisotropy photoinduction the video-microscopy investigations of the film having photoinduced anisotropy in the crossed polarizers have been conducted. It is shown that image formation herein can be carried out in the way of light modulation of the granular anisotropy integral area of the film. According to an active light exposition, both the concentration and sizes of molecular aggregates having photoinduced anisotropy are being modulated.},
     year = {2015}
    }
    

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    AU  - Tariel Ebralidze
    AU  - Nadia Ebralidze
    AU  - Giorgi Mumladze
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    N1  - https://doi.org/10.11648/j.optics.20150402.11
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    AB  - The anisotropy induction by light in self-induced molecular aggregations ensemble of azodyes has been studied. In the dynamic regime of anisotropy photoinduction the video-microscopy investigations of the film having photoinduced anisotropy in the crossed polarizers have been conducted. It is shown that image formation herein can be carried out in the way of light modulation of the granular anisotropy integral area of the film. According to an active light exposition, both the concentration and sizes of molecular aggregates having photoinduced anisotropy are being modulated.
    VL  - 4
    IS  - 2
    ER  - 

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Author Information
  • Department of Coherent Optics and Electronics, Vladimer Chavchanidze Institute of Cybernetics of the Georgian Technical University, Tbilisi, Georgia

  • Department of Coherent Optics and Electronics, Vladimer Chavchanidze Institute of Cybernetics of the Georgian Technical University, Tbilisi, Georgia

  • Department of Computer Engineering Elements and Nanomaterials, Vladimer Chavchanidze Institute of Cybernetics of the Georgian Technical University, Tbilisi, Georgia

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