Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH

Zeyad A. Saleh; Dhaidan Kh. Kafi

doi:doi:10.11648/j.ajop.20170504.11

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Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH

Zeyad A. Saleh, Dhaidan Kh. Kafi

Published in American Journal of Optics and Photonics (Volume 5, Issue 4)

Received: 21 January 2017 Accepted: 16 February 2017 Published: 30 October 2017

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Abstract

In this study, a fluorescent compound; N, N'-Bis (2-Hydroxy Benzylidene) Benzidine, (C₂₆H₂₀N₂O₂) prepared and calculated by FT-IR, 1H NMR, UV-Vis and fluorescence procedures. The ¹H NMR field examined in Chloroform-d solvent. The Fourier Transform-Infrared FT-IR in hard case detected in the area 4000-600 cm-1. The absorption spectrum of the Bis (2-Hydroxy Benzylidene) Benzidine resolved in tetrahydrofuran registered on the range 250-800nm. The fluorescence spectrum show in the region 520-700nm in different pH at room temperature. Photoluminescent properties of the title compound examined in tetrahydrofuran, Chloroform, acetone, and Toluene. The intensity and Stoke’s move of N, N' Bis (2-Hydroxy Benzylidene) Benzidine in THF solvent found greater than other solvents. The structural value, fundamental vibration modes, Proton Nuclear magnetic resonance isotropic chemical changes, and absorption spectrum of the N, N'-Bis (2-Hydroxy Benzylidene) Benzidine computed by density functional theory (DFT) using B3LYP/6-311G (d, p) basis set.

Published in	American Journal of Optics and Photonics (Volume 5, Issue 4)
DOI	10.11648/j.ajop.20170504.11
Page(s)	36-44
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Fluorescence, N, N' Bis (2-Hydroxy Benzylidene) Benzidine, Solvent Effect, PH Effect, Density Functional Theory (DFT)

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APA Style

Zeyad A. Saleh, Dhaidan Kh. Kafi. (2017). Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. American Journal of Optics and Photonics, 5(4), 36-44. https://doi.org/10.11648/j.ajop.20170504.11

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ACS Style

Zeyad A. Saleh; Dhaidan Kh. Kafi. Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. Am. J. Opt. Photonics 2017, 5(4), 36-44. doi: 10.11648/j.ajop.20170504.11

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AMA Style

Zeyad A. Saleh, Dhaidan Kh. Kafi. Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. Am J Opt Photonics. 2017;5(4):36-44. doi: 10.11648/j.ajop.20170504.11

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@article{10.11648/j.ajop.20170504.11,
  author = {Zeyad A. Saleh and Dhaidan Kh. Kafi},
  title = {Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH},
  journal = {American Journal of Optics and Photonics},
  volume = {5},
  number = {4},
  pages = {36-44},
  doi = {10.11648/j.ajop.20170504.11},
  url = {https://doi.org/10.11648/j.ajop.20170504.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajop.20170504.11},
  abstract = {In this study, a fluorescent compound; N, N'-Bis (2-Hydroxy Benzylidene) Benzidine, (C26H20N2O2) prepared and calculated by FT-IR, 1H NMR, UV-Vis and fluorescence procedures. The 1H NMR field examined in Chloroform-d solvent. The Fourier Transform-Infrared FT-IR in hard case detected in the area 4000-600 cm-1. The absorption spectrum of the Bis (2-Hydroxy Benzylidene) Benzidine resolved in tetrahydrofuran registered on the range 250-800nm. The fluorescence spectrum show in the region 520-700nm in different pH at room temperature. Photoluminescent properties of the title compound examined in tetrahydrofuran, Chloroform, acetone, and Toluene. The intensity and Stoke’s move of N, N' Bis (2-Hydroxy Benzylidene) Benzidine in THF solvent found greater than other solvents. The structural value, fundamental vibration modes, Proton Nuclear magnetic resonance isotropic chemical changes, and absorption spectrum of the N, N'-Bis (2-Hydroxy Benzylidene) Benzidine computed by density functional theory (DFT) using B3LYP/6-311G (d, p) basis set.},
 year = {2017}
}

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TY  - JOUR
T1  - Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH
AU  - Zeyad A. Saleh
AU  - Dhaidan Kh. Kafi
Y1  - 2017/10/30
PY  - 2017
N1  - https://doi.org/10.11648/j.ajop.20170504.11
DO  - 10.11648/j.ajop.20170504.11
T2  - American Journal of Optics and Photonics
JF  - American Journal of Optics and Photonics
JO  - American Journal of Optics and Photonics
SP  - 36
EP  - 44
PB  - Science Publishing Group
SN  - 2330-8494
UR  - https://doi.org/10.11648/j.ajop.20170504.11
AB  - In this study, a fluorescent compound; N, N'-Bis (2-Hydroxy Benzylidene) Benzidine, (C26H20N2O2) prepared and calculated by FT-IR, 1H NMR, UV-Vis and fluorescence procedures. The 1H NMR field examined in Chloroform-d solvent. The Fourier Transform-Infrared FT-IR in hard case detected in the area 4000-600 cm-1. The absorption spectrum of the Bis (2-Hydroxy Benzylidene) Benzidine resolved in tetrahydrofuran registered on the range 250-800nm. The fluorescence spectrum show in the region 520-700nm in different pH at room temperature. Photoluminescent properties of the title compound examined in tetrahydrofuran, Chloroform, acetone, and Toluene. The intensity and Stoke’s move of N, N' Bis (2-Hydroxy Benzylidene) Benzidine in THF solvent found greater than other solvents. The structural value, fundamental vibration modes, Proton Nuclear magnetic resonance isotropic chemical changes, and absorption spectrum of the N, N'-Bis (2-Hydroxy Benzylidene) Benzidine computed by density functional theory (DFT) using B3LYP/6-311G (d, p) basis set.
VL  - 5
IS  - 4
ER  -

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Author Information

Zeyad A. Saleh

Physics Department, College of Science, AL-Mustansiriyah University, Baghdad, Iraq
Dhaidan Kh. Kafi

Physics Department, College of Science, AL-Mustansiriyah University, Baghdad, Iraq

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Plain Text BibTeX RIS

APA Style

Zeyad A. Saleh, Dhaidan Kh. Kafi. (2017). Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. American Journal of Optics and Photonics, 5(4), 36-44. https://doi.org/10.11648/j.ajop.20170504.11

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ACS Style

Zeyad A. Saleh; Dhaidan Kh. Kafi. Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. Am. J. Opt. Photonics 2017, 5(4), 36-44. doi: 10.11648/j.ajop.20170504.11

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AMA Style

Zeyad A. Saleh, Dhaidan Kh. Kafi. Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH. Am J Opt Photonics. 2017;5(4):36-44. doi: 10.11648/j.ajop.20170504.11

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@article{10.11648/j.ajop.20170504.11,
  author = {Zeyad A. Saleh and Dhaidan Kh. Kafi},
  title = {Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH},
  journal = {American Journal of Optics and Photonics},
  volume = {5},
  number = {4},
  pages = {36-44},
  doi = {10.11648/j.ajop.20170504.11},
  url = {https://doi.org/10.11648/j.ajop.20170504.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajop.20170504.11},
  abstract = {In this study, a fluorescent compound; N, N'-Bis (2-Hydroxy Benzylidene) Benzidine, (C26H20N2O2) prepared and calculated by FT-IR, 1H NMR, UV-Vis and fluorescence procedures. The 1H NMR field examined in Chloroform-d solvent. The Fourier Transform-Infrared FT-IR in hard case detected in the area 4000-600 cm-1. The absorption spectrum of the Bis (2-Hydroxy Benzylidene) Benzidine resolved in tetrahydrofuran registered on the range 250-800nm. The fluorescence spectrum show in the region 520-700nm in different pH at room temperature. Photoluminescent properties of the title compound examined in tetrahydrofuran, Chloroform, acetone, and Toluene. The intensity and Stoke’s move of N, N' Bis (2-Hydroxy Benzylidene) Benzidine in THF solvent found greater than other solvents. The structural value, fundamental vibration modes, Proton Nuclear magnetic resonance isotropic chemical changes, and absorption spectrum of the N, N'-Bis (2-Hydroxy Benzylidene) Benzidine computed by density functional theory (DFT) using B3LYP/6-311G (d, p) basis set.},
 year = {2017}
}

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TY  - JOUR
T1  - Synthesis and Fluorescence Spectrum of N, N' Bis (2-Hydroxy Benzylidene) Benzidine with Different Solvents and Different PH
AU  - Zeyad A. Saleh
AU  - Dhaidan Kh. Kafi
Y1  - 2017/10/30
PY  - 2017
N1  - https://doi.org/10.11648/j.ajop.20170504.11
DO  - 10.11648/j.ajop.20170504.11
T2  - American Journal of Optics and Photonics
JF  - American Journal of Optics and Photonics
JO  - American Journal of Optics and Photonics
SP  - 36
EP  - 44
PB  - Science Publishing Group
SN  - 2330-8494
UR  - https://doi.org/10.11648/j.ajop.20170504.11
AB  - In this study, a fluorescent compound; N, N'-Bis (2-Hydroxy Benzylidene) Benzidine, (C26H20N2O2) prepared and calculated by FT-IR, 1H NMR, UV-Vis and fluorescence procedures. The 1H NMR field examined in Chloroform-d solvent. The Fourier Transform-Infrared FT-IR in hard case detected in the area 4000-600 cm-1. The absorption spectrum of the Bis (2-Hydroxy Benzylidene) Benzidine resolved in tetrahydrofuran registered on the range 250-800nm. The fluorescence spectrum show in the region 520-700nm in different pH at room temperature. Photoluminescent properties of the title compound examined in tetrahydrofuran, Chloroform, acetone, and Toluene. The intensity and Stoke’s move of N, N' Bis (2-Hydroxy Benzylidene) Benzidine in THF solvent found greater than other solvents. The structural value, fundamental vibration modes, Proton Nuclear magnetic resonance isotropic chemical changes, and absorption spectrum of the N, N'-Bis (2-Hydroxy Benzylidene) Benzidine computed by density functional theory (DFT) using B3LYP/6-311G (d, p) basis set.
VL  - 5
IS  - 4
ER  -

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