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Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table

Received: 16 July 2013    Accepted:     Published: 20 August 2013
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Abstract

It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.

DOI 10.11648/j.ajpc.20130203.11
Published in American Journal of Physical Chemistry (Volume 2, Issue 3, June 2013)
Page(s) 52-59
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Organometallic Compounds, Free Energy of Combustion, Free Energy of Formation, Entropy, Heat Capacity, Heat of Combustion Heat of Formation

References
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Author Information
  • Department of General Chemistry and Ecology, Tupolev Kazan National Researching Technical University, Tatarstan, Russia

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    Vitaly Vitalevich Ovchinnikov. (2013). Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. American Journal of Physical Chemistry, 2(3), 52-59. https://doi.org/10.11648/j.ajpc.20130203.11

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    Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am. J. Phys. Chem. 2013, 2(3), 52-59. doi: 10.11648/j.ajpc.20130203.11

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    AMA Style

    Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am J Phys Chem. 2013;2(3):52-59. doi: 10.11648/j.ajpc.20130203.11

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  • @article{10.11648/j.ajpc.20130203.11,
      author = {Vitaly Vitalevich Ovchinnikov},
      title = {Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table},
      journal = {American Journal of Physical Chemistry},
      volume = {2},
      number = {3},
      pages = {52-59},
      doi = {10.11648/j.ajpc.20130203.11},
      url = {https://doi.org/10.11648/j.ajpc.20130203.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajpc.20130203.11},
      abstract = {It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.},
     year = {2013}
    }
    

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    T1  - Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table
    AU  - Vitaly Vitalevich Ovchinnikov
    Y1  - 2013/08/20
    PY  - 2013
    N1  - https://doi.org/10.11648/j.ajpc.20130203.11
    DO  - 10.11648/j.ajpc.20130203.11
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 52
    EP  - 59
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20130203.11
    AB  - It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.
    VL  - 2
    IS  - 3
    ER  - 

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