Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten
American Journal of Physical Chemistry
Volume 10, Issue 1, March 2021, Pages: 1-5
Received: Dec. 9, 2020;
Accepted: Dec. 24, 2020;
Published: Jan. 12, 2021
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Samar Refaat Gooda, Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt
Omyma Ramadan Mohammed Khalifa, Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt
Aisha Kassab Abd El-Aziz, Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt
Amany Hassan Marii, Chemistry Department, Faculty of Girls (Arts, Science and Education), Ain Shams University, Cairo, Egypt
The whole world is interested in the metal industry and its permanent development. One of these metals is carbon steel. Therefore, scientists tend to improve the properties of this metal, in this research we have improved the properties of carbon steel through electroless plating process of Ni-P and Ni-W-P alloys. In different industries, electroless nickel-phosphorus Ni-P and nickel-tungsten-phosphorus Ni-W-P deposits have been commonly used as engineering safety coatings. In our research, Ni-P and Ni-W-P were deposited on low carbon steel by using acid bath. To study the improvement of the properties of the coats, microstructure analysis investigated by thin film (XRD), coat’s morphology by electron microscope scan (SEM), analyzing the coat by X-ray dispersive energy (EDX) and protection of corrosion of the coats were determined by potentiodynamic polarization measurements in artificial sea water (3.5% NaCl solution). The results indicated that the phases formed from the electroless coating give excellent corrosion resistance of low carbon steel and also indicated that the alloy formed in the presence of tungsten through the electroless bath give higher corrosion protection than that formed without it. As the concentration of tungstate increase in the bath, coat has higher corrosion protection i.e. Ni-W-P III>Ni-W-P II >Ni-W-P I>Ni-P.
Samar Refaat Gooda,
Omyma Ramadan Mohammed Khalifa,
Aisha Kassab Abd El-Aziz,
Amany Hassan Marii,
Structure and Corrosion Behavior of Nano-Crystalline Ni-P Alloy Containing Tungsten, American Journal of Physical Chemistry.
Vol. 10, No. 1,
2021, pp. 1-5.
J. Sudagar, J. Lian, W. Sha, “Electroless nickel alloy composite and nano coatings – A critical review, Journal of Alloys and Compounds, vol. 571, 2013, pp. 183–204.
S. Cheon, S. Park, Y. Rhym, D. Kim, J. Lee, “'The effect of bath conditions on the electroless nickel plating on the porous carbon substrate, Current Applied Physics, vol. 11, 2011, pp. 790-793.
T. Rabizadeh, S. R. Allahkaram, A. Zarebidaki, An investigation on effects of heat treatment on corrosion properties of Ni–P electroless nano-coatings, Materials and Design, vol. 31, 2010, pp. 3174–3179.
P. Sahoo, S. K. Das, Tribology of electroless nickel coating – a review, Mater, vol. 32, 2011, pp. 1760-1775.
C. Wang, Z. Farhat, G. Jarjoura, M. K. Hassan, A. M. Abdullah, Indentation and erosion behavior of electroless Ni-P coating on pipeline steel, Wear, pp. 376-377, 2017, pp. 1630-1639.
C. Wang, Z. Farhat, G. Jarjoura, M. K. Hassan, A. M. Abdullah, E. M. Fayyad, Investigation of fracture behavior of annealed electroless Ni-P coating on pipeline steel using acoustic emission methodology, Surf. Coat. Technol., Issu. 326, 2017, pp. 336-342.
R. Gan, D. Wang, Z.-H. Xie, L. He, Improving surface characteristic and corrosion inhibition of coating on Mg alloy by trace stannous (II) chloride, Corros. Sci. Issu. 137, 2017, pp. 147-157.
J. Wasserbauer, M. Buchtík, J. Tkacz, S. Fintová, J. Minda and L. Doskoˇcil, Improvement of AZ91 Alloy Corrosion Properties by Duplex NI-P Coating Deposition, Materials vol. 13, 2020, pp. 135.
J. N. Balaraju, Kalavati, K. S. Rajam, Electroless ternary Ni–W–P alloys containing micron size Al2O3 particles, Surf. Coat. Technol. vol. 205, 2010, pp. 575–581.
S. Afroukhteh, C. Dehghanian, M. Emamy, Preparation of the Ni–P composite coating co-deposited by nanoTiC particles and evaluation of its corrosion property, Appl. Surf. Sci. Issu. 258, vol. 7, 2012, pp. 2597–2601.
C. Wang, Z. Farhat, G. Jarjoura, M. K. Hassan, A. M. Abdullah, Indentation and bending behavior of electroless Ni-P-Ti composite coatings on pipeline steel, Surf. Coat. Technol. vol. 334, 2018 pp. 243–252.
L. Masry, G. Jarjoura, Z. Farhat, E. M. Fayyad, A. M. Abdullah, M. K. H. Mohamed, Development of novel corrosion resistant electroless Ni-P composite coatings for pipeline steel, IJESRT. Vol. 7, 2018, pp. 122–134.
Z.-H. Xie, D. Li, Z. Skeete, A. Sharma, C.-J. Zhong, Nanocontainer-enhanced self-healing for corrosion-resistant Ni coating on Mg alloy, ACS Appl. Mater. Interfaces vol. 9, Issu 41, 2017, pp. 36247–36260.
Z.-H. Xie, S. Shan, Nano-containers enhanced self-healing Ni coating for corrosion protection of Mg alloy, J. Mater. Sci. vol. 53, 2018, pp. 3744–3755.
E. M. Fayyada, A. M. Abdullah, A. M. A. Mohamed, G. Jarjoura, Z. Farhat, M. K. Hassan, Effect of electroless bath composition on the mechanical, chemical, and electrochemical properties of new Ni-P–C3N4nanocomposite coatings, Surface & Coatings Technology, Issu 362, 2019, pp. 239–251.
Hu Y, Yang L, Shi C, Tang W. Microstructural evolution and phase transformation kinetics of pulse-electroplated Ni-Cu-P alloy film during annealing. Materials Chemistry and Physics. vol. 141, 2013, pp. 944-950.
Narayanan TSNS, Selvakumar S, Stephen A. Electroless Ni- Co-P ternary alloy deposits: preparation and characteristics. Surface and Coatings Technology. vol. 172, 2003, pp. 298-307.
Zhang WX, Jiang ZH, Li GY, Jiang Q, Lian JS. Electroless Ni-Sn-P coating on AZ91D magnesium alloy and its corrosion resistance. Surface and Coatings Technology. Issu. 202, vol. 12, 2008, pp. 2570-2576.
Balaraju JN, Chembath M. Electroless ternary Ni-Ce-P coatings: Preparation and characterisation. Applied Surface Science, vol. 24, Issu 258, 2012, pp. 9692-9700.
J. N. Balaraju, Kalavati, N. T. Manikandanath, V. K. William, Phase transformation behavior of nanocrystalline Ni–W–P alloys containing various W and P contents, Surface & Coatings Technology, vol. 206, 2012, pp. 2682–2689,.
C. Yanhai, C. Shuai, H. Qingqiang, H. Dongtai, H. Zhengtong, Effect of Tungsten Addition on the Anti-fouling Property of the Electroless Ni-W-P Deposits, Rare Metal Materials and Engineering, Issu. 45, vol. 8, 2016, pp. 1931-1937.
Oliveira, Mara, Correa, Olandir, Ett, Bardia, Sayeg, Lima, Nelson, Antunes, Renato, Influence of the Tungsten Content on Surface Properties of Electroless Ni-W-P Coatings. Materials Research. Issu. 21. vol. 10. 2017, pp. 5373.
Shirya, Andrey & Woodcutters, А&С. С. Adilova & Aliyev, А. Electrochemical deposition of Ni-W-P alloy (Electrodeposition of Ni-W-P alloy). Vol 25, Issu. 51-57. 2020, pp. 95. 1-7.