Three Separate Regions in the Prepared Aniline-Palladium Mixture

Yuriy Semenyuk; Orest Pereviznyk; Oleksandr Reshetnyak; Ivan Saldan

doi:doi:10.11648/j.ajpc.20140301.11

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Three Separate Regions in the Prepared Aniline-Palladium Mixture

Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan

Published in American Journal of Physical Chemistry (Volume 3, Issue 1)

Received: 15 December 2013 Accepted: Published: 30 December 2013

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Abstract

Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.

Published in	American Journal of Physical Chemistry (Volume 3, Issue 1)
DOI	10.11648/j.ajpc.20140301.11
Page(s)	1-4
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Aniline, Palladium, Chemical Synthesis, SEM, PXD, FTIR

References

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APA Style

Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. (2013). Three Separate Regions in the Prepared Aniline-Palladium Mixture. American Journal of Physical Chemistry, 3(1), 1-4. https://doi.org/10.11648/j.ajpc.20140301.11

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ACS Style

Yuriy Semenyuk; Orest Pereviznyk; Oleksandr Reshetnyak; Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am. J. Phys. Chem. 2013, 3(1), 1-4. doi: 10.11648/j.ajpc.20140301.11

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AMA Style

Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am J Phys Chem. 2013;3(1):1-4. doi: 10.11648/j.ajpc.20140301.11

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@article{10.11648/j.ajpc.20140301.11,
  author = {Yuriy Semenyuk and Orest Pereviznyk and Oleksandr Reshetnyak and Ivan Saldan},
  title = {Three Separate Regions in the Prepared Aniline-Palladium Mixture},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {1},
  pages = {1-4},
  doi = {10.11648/j.ajpc.20140301.11},
  url = {https://doi.org/10.11648/j.ajpc.20140301.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140301.11},
  abstract = {Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.},
 year = {2013}
}

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TY  - JOUR
T1  - Three Separate Regions in the Prepared Aniline-Palladium Mixture
AU  - Yuriy Semenyuk
AU  - Orest Pereviznyk
AU  - Oleksandr Reshetnyak
AU  - Ivan Saldan
Y1  - 2013/12/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20140301.11
DO  - 10.11648/j.ajpc.20140301.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 4
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140301.11
AB  - Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.
VL  - 3
IS  - 1
ER  -

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Author Information

Yuriy Semenyuk

Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine
Orest Pereviznyk

Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine
Oleksandr Reshetnyak

Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine
Ivan Saldan

Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine; Physics Department, Institute for Energy Technology, Kjeller, Norway

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APA Style

Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. (2013). Three Separate Regions in the Prepared Aniline-Palladium Mixture. American Journal of Physical Chemistry, 3(1), 1-4. https://doi.org/10.11648/j.ajpc.20140301.11

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ACS Style

Yuriy Semenyuk; Orest Pereviznyk; Oleksandr Reshetnyak; Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am. J. Phys. Chem. 2013, 3(1), 1-4. doi: 10.11648/j.ajpc.20140301.11

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AMA Style

Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am J Phys Chem. 2013;3(1):1-4. doi: 10.11648/j.ajpc.20140301.11

Copy | Download

@article{10.11648/j.ajpc.20140301.11,
  author = {Yuriy Semenyuk and Orest Pereviznyk and Oleksandr Reshetnyak and Ivan Saldan},
  title = {Three Separate Regions in the Prepared Aniline-Palladium Mixture},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {1},
  pages = {1-4},
  doi = {10.11648/j.ajpc.20140301.11},
  url = {https://doi.org/10.11648/j.ajpc.20140301.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140301.11},
  abstract = {Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.},
 year = {2013}
}

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TY  - JOUR
T1  - Three Separate Regions in the Prepared Aniline-Palladium Mixture
AU  - Yuriy Semenyuk
AU  - Orest Pereviznyk
AU  - Oleksandr Reshetnyak
AU  - Ivan Saldan
Y1  - 2013/12/30
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20140301.11
DO  - 10.11648/j.ajpc.20140301.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 4
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140301.11
AB  - Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.
VL  - 3
IS  - 1
ER  -

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