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Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target

Received: 12 July 2018    Accepted: 24 July 2018    Published: 17 August 2018
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Abstract

P-type tin oxide thin film deposited by RF sputtering for transparent thin film transistor (TFT) applications is the subject of this study. P-type tin oxide thin film can be made by doping a cation with a lower valence into n-type SnO2 as an acceptor impurity or by fabrication with tin monoxide (SnO). The later method was investigated in this study by RF magnetron sputtering process, which has a high deposition rate, uniform thickness control, simple stoichiometry control, and reproducibility. A Sn/SnO composite target was used in RF sputtering to utilize the benefits of both metallic and ceramic sputtering targets. A Sn/SnO composite target is expected to provide p-type tin oxide thin films that are easier to manufacture than metallic target or ceramic target. The metallic Sn element provides an excellent control of structural defects, while the ceramic SnO element provides stable stoichiometry. The p-type tin oxide thin film with a Sn/SnO composite target showed very good transparency of ~95%. and excellent electrical properties. The p-type tin oxide thin film of 15nm thickness had a carrier concentration of 8.03X1015cm-3 and a mobility of 15.2cm2/Vs. With these ultrathin tin oxide films, a p-channel TFT was fabricated with a staggered bottom-gate structure, and the effect of different channel thicknesses and different distances between the two electrodes were evaluated. The tin oxide TFT with a thick p-channel layer showed a significant increase in current measured than the tin oxide with a thin p-channel layer. The current measured tended to increase greatly as the distance between electrodes decreased. The IV output curves of the tin oxide TFTs exhibited characteristics of bipolar transistors potentially due to the partial creation of the oxygen-deficient SnO2 like structure, but the mechanism of bipolar transistor characteristics from the p-channel tin oxide TFT is still unclear. The fabrication of highly transparent tin oxide thin film with bipolar transistor characteristics is demonstrated herein.

DOI 10.11648/j.am.20180703.13
Published in Advances in Materials (Volume 7, Issue 3, September 2018)
Page(s) 73-77
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Tin Oxide, Sputtering, Composite Target, Thin Film Transistor, Bipolar

References
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Author Information
  • Graduate School of Nano-IT Design, Seoul National University of Science and Technology, Seoul, Korea

  • Graduate School of Nano-IT Design, Seoul National University of Science and Technology, Seoul, Korea

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    Cheol Kim, Sarah Eunkyung Kim. (2018). Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target. Advances in Materials, 7(3), 73-77. https://doi.org/10.11648/j.am.20180703.13

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    ACS Style

    Cheol Kim; Sarah Eunkyung Kim. Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target. Adv. Mater. 2018, 7(3), 73-77. doi: 10.11648/j.am.20180703.13

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    AMA Style

    Cheol Kim, Sarah Eunkyung Kim. Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target. Adv Mater. 2018;7(3):73-77. doi: 10.11648/j.am.20180703.13

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  • @article{10.11648/j.am.20180703.13,
      author = {Cheol Kim and Sarah Eunkyung Kim},
      title = {Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target},
      journal = {Advances in Materials},
      volume = {7},
      number = {3},
      pages = {73-77},
      doi = {10.11648/j.am.20180703.13},
      url = {https://doi.org/10.11648/j.am.20180703.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.am.20180703.13},
      abstract = {P-type tin oxide thin film deposited by RF sputtering for transparent thin film transistor (TFT) applications is the subject of this study. P-type tin oxide thin film can be made by doping a cation with a lower valence into n-type SnO2 as an acceptor impurity or by fabrication with tin monoxide (SnO). The later method was investigated in this study by RF magnetron sputtering process, which has a high deposition rate, uniform thickness control, simple stoichiometry control, and reproducibility. A Sn/SnO composite target was used in RF sputtering to utilize the benefits of both metallic and ceramic sputtering targets. A Sn/SnO composite target is expected to provide p-type tin oxide thin films that are easier to manufacture than metallic target or ceramic target. The metallic Sn element provides an excellent control of structural defects, while the ceramic SnO element provides stable stoichiometry. The p-type tin oxide thin film with a Sn/SnO composite target showed very good transparency of ~95%. and excellent electrical properties. The p-type tin oxide thin film of 15nm thickness had a carrier concentration of 8.03X1015cm-3 and a mobility of 15.2cm2/Vs. With these ultrathin tin oxide films, a p-channel TFT was fabricated with a staggered bottom-gate structure, and the effect of different channel thicknesses and different distances between the two electrodes were evaluated.  The tin oxide TFT with a thick p-channel layer showed a significant increase in current measured than the tin oxide with a thin p-channel layer.  The current measured tended to increase greatly as the distance between electrodes decreased.  The IV output curves of the tin oxide TFTs exhibited characteristics of bipolar transistors potentially due to the partial creation of the oxygen-deficient SnO2 like structure, but the mechanism of bipolar transistor characteristics from the p-channel tin oxide TFT is still unclear. The fabrication of highly transparent tin oxide thin film with bipolar transistor characteristics is demonstrated herein.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Fabrication of Tin Oxide Thin Film Transistors by RF Magnetron Sputtering Using Sn/SnO Composite Target
    AU  - Cheol Kim
    AU  - Sarah Eunkyung Kim
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    PY  - 2018
    N1  - https://doi.org/10.11648/j.am.20180703.13
    DO  - 10.11648/j.am.20180703.13
    T2  - Advances in Materials
    JF  - Advances in Materials
    JO  - Advances in Materials
    SP  - 73
    EP  - 77
    PB  - Science Publishing Group
    SN  - 2327-252X
    UR  - https://doi.org/10.11648/j.am.20180703.13
    AB  - P-type tin oxide thin film deposited by RF sputtering for transparent thin film transistor (TFT) applications is the subject of this study. P-type tin oxide thin film can be made by doping a cation with a lower valence into n-type SnO2 as an acceptor impurity or by fabrication with tin monoxide (SnO). The later method was investigated in this study by RF magnetron sputtering process, which has a high deposition rate, uniform thickness control, simple stoichiometry control, and reproducibility. A Sn/SnO composite target was used in RF sputtering to utilize the benefits of both metallic and ceramic sputtering targets. A Sn/SnO composite target is expected to provide p-type tin oxide thin films that are easier to manufacture than metallic target or ceramic target. The metallic Sn element provides an excellent control of structural defects, while the ceramic SnO element provides stable stoichiometry. The p-type tin oxide thin film with a Sn/SnO composite target showed very good transparency of ~95%. and excellent electrical properties. The p-type tin oxide thin film of 15nm thickness had a carrier concentration of 8.03X1015cm-3 and a mobility of 15.2cm2/Vs. With these ultrathin tin oxide films, a p-channel TFT was fabricated with a staggered bottom-gate structure, and the effect of different channel thicknesses and different distances between the two electrodes were evaluated.  The tin oxide TFT with a thick p-channel layer showed a significant increase in current measured than the tin oxide with a thin p-channel layer.  The current measured tended to increase greatly as the distance between electrodes decreased.  The IV output curves of the tin oxide TFTs exhibited characteristics of bipolar transistors potentially due to the partial creation of the oxygen-deficient SnO2 like structure, but the mechanism of bipolar transistor characteristics from the p-channel tin oxide TFT is still unclear. The fabrication of highly transparent tin oxide thin film with bipolar transistor characteristics is demonstrated herein.
    VL  - 7
    IS  - 3
    ER  - 

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