With a view to validating the existence of the phenomenon of phase formation via a liquid state stage in metals being electrodeposited, experiments were carried out to reveal electrodeposited metal's structural features typical of metals produced by solidification at ultra-high rates under high supercooling, and to establish consistent changes in metal structural characteristics with increasing degree of supercooling in electrodeposition. Following experimental facts in favour of the existence of the phenomenon in point were found: (1) occurrence of spherulites and pentagonal quasicrystals in electrodeposit layers adjoining the cathode, the occurrence being typical of metals produced by ultra-rapid solidification of a highly supercooled liquid metal phase; (2) emergence of the electrodeposited metals solely in a spherulitic form when transition of spherulitic growth to drusy growth with increasing deposit thickness was prevented; and (3) regular change in characteristics of point, linear and planar defects in the crystalline lattice with increasing degree of supercooling in electrodeposition of metals.
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Advances in Materials (Volume 4, Issue 3-1)
This article belongs to the Special Issue Advances in Electrodeposited Materials: Phase Formation, Structure and Properties |
| DOI | 10.11648/j.am.s.2015040301.15 |
| Page(s) | 33-40 |
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2024. Published by Science Publishing Group |
Structure, Phase Formation, Electrodeposited Metal, Spherulite, Quasicrystal, Crystalline Defect
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APA Style
Oleg B. Girin. (2015). Structural Features of Electrodeposited Metals as a Result of Ultra-Rapid Solidification of a Highly Supercooled Liquid Metal Phase. Advances in Materials, 4(3-1), 33-40. https://doi.org/10.11648/j.am.s.2015040301.15
ACS Style
Oleg B. Girin. Structural Features of Electrodeposited Metals as a Result of Ultra-Rapid Solidification of a Highly Supercooled Liquid Metal Phase. Adv. Mater. 2015, 4(3-1), 33-40. doi: 10.11648/j.am.s.2015040301.15
AMA Style
Oleg B. Girin. Structural Features of Electrodeposited Metals as a Result of Ultra-Rapid Solidification of a Highly Supercooled Liquid Metal Phase. Adv Mater. 2015;4(3-1):33-40. doi: 10.11648/j.am.s.2015040301.15
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Download@article{10.11648/j.am.s.2015040301.15,
author = {Oleg B. Girin},
title = {Structural Features of Electrodeposited Metals as a Result of Ultra-Rapid Solidification of a Highly Supercooled Liquid Metal Phase},
journal = {Advances in Materials},
volume = {4},
number = {3-1},
pages = {33-40},
doi = {10.11648/j.am.s.2015040301.15},
url = {https://doi.org/10.11648/j.am.s.2015040301.15},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.s.2015040301.15},
abstract = {With a view to validating the existence of the phenomenon of phase formation via a liquid state stage in metals being electrodeposited, experiments were carried out to reveal electrodeposited metal's structural features typical of metals produced by solidification at ultra-high rates under high supercooling, and to establish consistent changes in metal structural characteristics with increasing degree of supercooling in electrodeposition. Following experimental facts in favour of the existence of the phenomenon in point were found: (1) occurrence of spherulites and pentagonal quasicrystals in electrodeposit layers adjoining the cathode, the occurrence being typical of metals produced by ultra-rapid solidification of a highly supercooled liquid metal phase; (2) emergence of the electrodeposited metals solely in a spherulitic form when transition of spherulitic growth to drusy growth with increasing deposit thickness was prevented; and (3) regular change in characteristics of point, linear and planar defects in the crystalline lattice with increasing degree of supercooling in electrodeposition of metals.},
year = {2015}
}
TY - JOUR T1 - Structural Features of Electrodeposited Metals as a Result of Ultra-Rapid Solidification of a Highly Supercooled Liquid Metal Phase AU - Oleg B. Girin Y1 - 2015/06/18 PY - 2015 N1 - https://doi.org/10.11648/j.am.s.2015040301.15 DO - 10.11648/j.am.s.2015040301.15 T2 - Advances in Materials JF - Advances in Materials JO - Advances in Materials SP - 33 EP - 40 PB - Science Publishing Group SN - 2327-252X UR - https://doi.org/10.11648/j.am.s.2015040301.15 AB - With a view to validating the existence of the phenomenon of phase formation via a liquid state stage in metals being electrodeposited, experiments were carried out to reveal electrodeposited metal's structural features typical of metals produced by solidification at ultra-high rates under high supercooling, and to establish consistent changes in metal structural characteristics with increasing degree of supercooling in electrodeposition. Following experimental facts in favour of the existence of the phenomenon in point were found: (1) occurrence of spherulites and pentagonal quasicrystals in electrodeposit layers adjoining the cathode, the occurrence being typical of metals produced by ultra-rapid solidification of a highly supercooled liquid metal phase; (2) emergence of the electrodeposited metals solely in a spherulitic form when transition of spherulitic growth to drusy growth with increasing deposit thickness was prevented; and (3) regular change in characteristics of point, linear and planar defects in the crystalline lattice with increasing degree of supercooling in electrodeposition of metals. VL - 4 IS - 3-1 ER -
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