Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and <sup>1</sup>H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film

Siyamak Shahab; Liudmila Filippovich; Masoome Sheikhi; Hooriye Yahyaei; Maria Aharodnikova; Rakesh Kumar; Mehrnoosh Khaleghian

doi:doi:10.11648/j.ajmsp.20170202.11

Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and ¹H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film

Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, Rakesh Kumar, Mehrnoosh Khaleghian

Published in American Journal of Materials Synthesis and Processing (Volume 2, Issue 2)

Received: 11 March 2017 Accepted: 23 March 2017 Published: 24 April 2017

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Abstract

Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and ¹H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λ_max = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λ_max = 92%) and Stretching Degree (R_s) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ_‖/λ_⊥). Thermal conductivity in a direction of orientation (λ_‖) is higher than in a direction perpendicular orientations (λ_⊥).

Published in	American Journal of Materials Synthesis and Processing (Volume 2, Issue 2)
DOI	10.11648/j.ajmsp.20170202.11
Page(s)	17-23
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Polarizer Film, Dichroic Dye, Thermal Conductivity, Polarization Efficiency

References

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[2]	Shahab S.,Agabekov V., Ariko N., Filippovich L.: Anisotropy of polarizing polyvinyl alcohol films, Advanced Display Technologies: proc. Of the 15 Intern. Symp., Moscow, Russia, Oct. 3–5, 2006/Soc. for Inform. Display. 163-166.
[3]	Agabekov V., Shahab S.,Ariko N., Filippovich L.: Anisotropy of polarizing films with azo dyes, XV Intern. Symp. On Advanced Dis. Tech. SPIE. San Diego, USA, August 27-31, 2007. V.19/4. -P. 174-179.
[4]	Agabekov V., Ivanova N., Shahab S., Kulevskaya I., Ariko N.: Film transfect polarizer, Advanced Display Technologies: Basic Studies of Problems in Inform. Display (FLOWERS 2000), Moscow, Russia, Oct. 10–12, 2000./ed. V.V. Belyaev, I.N. Kompanets; Soc. for Inform. Display.–Bellingham, 2000. -P. 141-143.
[5]	Almodarresiyeh H. A., Shahab S. N., Zelenkovsky V. M., Agabekov V. E.: Electronic structure and absorption spectra of sodium 2-hydroxy-5-({2-methoxy-4[4-sulfophenyl)diazenyl]phenyl}diazenyl)benzoate, J. App. Spect. 81 (2014) 181-183.
[6]	Almodarresiyeh H. A., Shahab S. N., Zelenkovsky V. M., Ariko N. G., Filippovich L. N., Agabekov V. E.: Calculation of UV, IR and NMR spectra of diethyl 2,2'-[(1,1'-biphenyl)-4,4'-diylbis(azanediyl)]diacetate, J. App. Spect. 81 (2014) 42-47.
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Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. (2017). Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. American Journal of Materials Synthesis and Processing, 2(2), 17-23. https://doi.org/10.11648/j.ajmsp.20170202.11

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ACS Style

Siyamak Shahab; Liudmila Filippovich; Masoome Sheikhi; Hooriye Yahyaei; Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am. J. Mater. Synth. Process. 2017, 2(2), 17-23. doi: 10.11648/j.ajmsp.20170202.11

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AMA Style

Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am J Mater Synth Process. 2017;2(2):17-23. doi: 10.11648/j.ajmsp.20170202.11

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@article{10.11648/j.ajmsp.20170202.11,
  author = {Siyamak Shahab and Liudmila Filippovich and Masoome Sheikhi and Hooriye Yahyaei and Maria Aharodnikova and Rakesh Kumar and Mehrnoosh Khaleghian},
  title = {Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film},
  journal = {American Journal of Materials Synthesis and Processing},
  volume = {2},
  number = {2},
  pages = {17-23},
  doi = {10.11648/j.ajmsp.20170202.11},
  url = {https://doi.org/10.11648/j.ajmsp.20170202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20170202.11},
  abstract = {Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).},
 year = {2017}
}

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TY  - JOUR
T1  - Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film
AU  - Siyamak Shahab
AU  - Liudmila Filippovich
AU  - Masoome Sheikhi
AU  - Hooriye Yahyaei
AU  - Maria Aharodnikova
AU  - Rakesh Kumar
AU  - Mehrnoosh Khaleghian
Y1  - 2017/04/24
PY  - 2017
N1  - https://doi.org/10.11648/j.ajmsp.20170202.11
DO  - 10.11648/j.ajmsp.20170202.11
T2  - American Journal of Materials Synthesis and Processing
JF  - American Journal of Materials Synthesis and Processing
JO  - American Journal of Materials Synthesis and Processing
SP  - 17
EP  - 23
PB  - Science Publishing Group
SN  - 2575-1530
UR  - https://doi.org/10.11648/j.ajmsp.20170202.11
AB  - Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).
VL  - 2
IS  - 2
ER  -

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Author Information

Siyamak Shahab

Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus
Liudmila Filippovich

Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus
Masoome Sheikhi

Young Researchers and Elite Club, Gorgan Branch, Islamic Azad University, Gorgan, Iran
Hooriye Yahyaei

Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, Iran
Maria Aharodnikova

Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus
Rakesh Kumar

Department of Applied Sciences, CTIT, CT Group of Institutions, Jalandhar (Punjab), India
Mehrnoosh Khaleghian

Department of Chemistry, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran

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APA Style

Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. (2017). Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. American Journal of Materials Synthesis and Processing, 2(2), 17-23. https://doi.org/10.11648/j.ajmsp.20170202.11

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ACS Style

Siyamak Shahab; Liudmila Filippovich; Masoome Sheikhi; Hooriye Yahyaei; Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am. J. Mater. Synth. Process. 2017, 2(2), 17-23. doi: 10.11648/j.ajmsp.20170202.11

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AMA Style

Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am J Mater Synth Process. 2017;2(2):17-23. doi: 10.11648/j.ajmsp.20170202.11

Copy | Download

@article{10.11648/j.ajmsp.20170202.11,
  author = {Siyamak Shahab and Liudmila Filippovich and Masoome Sheikhi and Hooriye Yahyaei and Maria Aharodnikova and Rakesh Kumar and Mehrnoosh Khaleghian},
  title = {Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film},
  journal = {American Journal of Materials Synthesis and Processing},
  volume = {2},
  number = {2},
  pages = {17-23},
  doi = {10.11648/j.ajmsp.20170202.11},
  url = {https://doi.org/10.11648/j.ajmsp.20170202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20170202.11},
  abstract = {Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film
AU  - Siyamak Shahab
AU  - Liudmila Filippovich
AU  - Masoome Sheikhi
AU  - Hooriye Yahyaei
AU  - Maria Aharodnikova
AU  - Rakesh Kumar
AU  - Mehrnoosh Khaleghian
Y1  - 2017/04/24
PY  - 2017
N1  - https://doi.org/10.11648/j.ajmsp.20170202.11
DO  - 10.11648/j.ajmsp.20170202.11
T2  - American Journal of Materials Synthesis and Processing
JF  - American Journal of Materials Synthesis and Processing
JO  - American Journal of Materials Synthesis and Processing
SP  - 17
EP  - 23
PB  - Science Publishing Group
SN  - 2575-1530
UR  - https://doi.org/10.11648/j.ajmsp.20170202.11
AB  - Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).
VL  - 2
IS  - 2
ER  -

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