Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO<sub>2</sub> Based Dye-Sensitized Solar Cells

Eli Danladi; Philip Musa Gyuk; Ezra Bako Danladi

doi:doi:10.11648/j.jenr.20160505.11

| Peer-Reviewed

Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO₂ Based Dye-Sensitized Solar Cells

Eli Danladi, Philip Musa Gyuk, Ezra Bako Danladi

Published in Journal of Energy and Natural Resources (Volume 5, Issue 5)

Received: 7 August 2016 Accepted: 15 August 2016 Published: 2 September 2016

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Chlorophyll and betalain pigments extracted from scent leaves and flower of Bougainvillea Spectabilis were used as sensitizers for nanostructured TiO₂ based dye-sensitized solar cells (DSSCs), and their perfomances were investigated systematically. The light harvesting pigments have shown absorption in broad range of the visible region of the solar spectrum and appreciable adsorption onto the semiconductor surface. The photovoltaic (PV) parameters such as short circuit current density (J_SC ), open circuit voltage (V_OC), fill factor (FF), and overall solar conversion efficiency (η) were determined under 100 mAcm^-2. The DSSC fabricated with betalains pigment from Bougainvillea Spectabilis was found to be superior to that obtained from chlorophyll pigment of scent leave (Ocimum Gratissimum). The DSSC gave a short circuit current density of 0.093 mAcm^-2, open circuit voltage of 0.433 V, fill factor of 0.550, and an overall solar conversion efficiency of 0.040%. The cell sensitized with betalains pigment exhibits: (i) ~ 1.90 times improvement in conversion efficiency, (ii) ~ 2.11 times enhancement in photocurrent density, and (iii) ~ 1.38 times improvement in fill factor compared to the results obtained with the chlorophyll sensitized solar cell. The sensitization performance related to interaction between the dye and TiO₂ surface is discussed.

Published in	Journal of Energy and Natural Resources (Volume 5, Issue 5)
DOI	10.11648/j.jenr.20160505.11
Page(s)	53-58
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

DSSCs, TiO₂, Natural Pigments, Betalain, Chlorophll, Electron Transfer, Sensitization

References

[1]	Li, B., Wang, L. D., Kang, B. N., Wang, P., & Qiu, Y. (2006). Review of Recent Progress in Solid-State Dye-Sensitized Solar Cells. Solar Energy Materials and Solar Cells, 90(5), 549-573.
[2]	Gratzel, M. (2007). Photovoltaic and Photoelectrochemical Conversion of Solar Energy. Philosophical Transactions of the Royal Society, 365, 1853, 993-1005.
[3]	Jun, H. K., Careem, M. A., & Arof, A. K. (2013). Quantum dot-sensitized solar cells perspective and recent developments: A review of Cd chalcogenide quantum dots as sensitizers. Renewable and Sustainable Energy Reviews, 22, 148–167.
[4]	Lewis, N. S., & Crabtree, G. (2005). Basic research needs for solar energy utilization. In: 2005 report on the basic energy sciences workshop on solar energy utilization. U.S. Department of Energy. Available online at: /http://www.er. doe.gov/bes/reports/files/SEU_rpt.pdfS; April 18–212005 [accessed August, 2011].
[5]	Werner, J. H. (2004). Second and third generation photovoltaics–dreams and reality. Advances in Solid State Physics, 44, 51–67.
[6]	O’Regan, B., & Gratzel, M. (1991). Low-cost A. High-efficiency solar cell based on dye-sensitized colloidal TiO₂ films. Nature, 353, 737–40.
[7]	Lagref, J. J., Nazeeruddin, M. K., & Graetzel, M. (2008). Artificial photosynthesis based on dye-sensitized nanocrystalline TiO₂ solar cells, Inorganica Chimica Acta, 361(3), 735-745.
[8]	Smestad, G. P. & Gratzel, M. (1998). Demonstrating Electron Transfer and Nanotechnology: A Natural Dye-Sensitized Nanocrystalline Energy Converter. Journal of Chemical Education, 75(6), 752-756.
[9]	Danladi, E., Owolabi, J. A., Olowomofe, G. O., & Ezeoke J. (2016). Plasmon-Enhanced Efficiency in Dye Sensitized Solar Cells Decorated with Size-Controlled Silver Nanoparticles Based on Anthocyanins as Light Harvesting Pigment. Journal of Photonic Materials and Technology, 2(1), 6-13.
[10]	Li, G., Shrotriya, V., Yao, Y., & Yang, Y. (2005). Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly (3-hexylthio- phene). Journal of Applied Physics, 98, 043704-1–043704-5.
[11]	Danladi, E., Ezeoke, J., Ahmad, M. S., Danladi, E. B., Sarki, S. H., Iliyasu, I., & Gyuk, P. M. (2016). Photoelectrochemical performance of dye-sensitized organic photovoltaic cells based on natural pigments and wide-bandgap nanostructured semiconductor. Physical Science International Journal, 10(2), 1-7.
[12]	Danladi, E., Onimisi, M. Y., Abdu, S. G., Ezeoke, J., & Yakubu, S. O. (2016). Photoelectric characterization of a dye-sensitized solar cell based on natural pigment extracted from Roselle (Hibiscus sabdariffa) flower and TiO₂ nanoparticles. British Journal of Applied Science & Technology, 15(2), 1-6.
[13]	Isah, H., Danladi E., & Gyuk, P. M. (2015). Development of Organic Dye Sensitized Solar Cell Incorporated with TiO₂ Nanostructures with Low Conversion Efficiency for Exploring Solar Energy Concepts. International Journal of Optoelectronic Engineering. 2015, 5 (1): 16-19. DOI: 10.5923/j.ijoe.20150501.03.
[14]	Danladi, E., Ahmad, M. S., Idodo, M., Danladi, E. B., Aungwa, F., & Sarki, S. H. (2016). Dye-sensitized solar cells using natural dyes extracted from Roselle (Hibiscus sabdariffa) flowers and pawpaw (Carica papaya) leaves as sensitizers. Journal of Energy and Natural Resources, 5(1), 11-15.
[15]	Danladi, E., Owolabi, J. A., Olowomofe, G. O., Onimisi, M. Y., & Aungwa, F. (2016). Enhancement in Photovoltaic Parameters of a Dye Sensitized Solar Cell by Surface Plasmon Resonance of Metallic Silver Nanoparticles. American Chemical Science Journal, 14(3), 1-8.
[16]	Ezeoke J., Onimisi, M. Y., Danladi, E., Abdu, S. G., & Abdulsalam, M. S. (2016). Photovoltaic Perfomance of Dye Sensitized Solar Cells Using Natural Dyes Extracted from Bougainvillea Flower and Mango Leaves. Journal of Scientific Research & Reports, 10(6), 1-5.
[17]	Boyo, O., Paul, O., Abdulsalami, I., Surukite, O., Boyo, H. O., Boyo, H. (2013). Application of Hibiscus Sabdariffa and leaves of Azardirachta Indica calyxes as sensitizers in Dye sensitized solar cells. International Journal of Engineering Research and Development, 8(12), 38-42.
[18]	Wongcharee, K., Meeyoo, V., & Chavadej, S. (2007). Dye sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Solar energy materials and solar cells, 91(7), 566-571.
[19]	Mphande, B. C., & Pogrebnoi, A. (2015). Outdoor photoelectrochemical characterization of dyes from Acalypha wilkesiana ‘Haleakala’ and Hibiscus sabdariffa as dye solar cells sensitizers. British Journal of Applied Science & Technology, 7(2), 195-204.
[20]	Danladi, E., Onimisi, M. Y., Abdu, S. G., Gyuk, P. M., & Ezeoke, J. (2016). Enhanced performance of a dye sensitized solar cell using silver nanoparticles modified photoanode. Journal of Scientific Research & Reports, 10(4), 1-8.
[21]	Danladi, E., Ahmad, M. S., Ayiya, B. B., & Babatunde, O. A. (2016). Plasmonic dye sensitized solar cells incorporated with TiO₂-Ag nanostructures. International Research Journal of Pure & Applied Chemistry, 11(3), 1-7.
[22]	Onimisi, M. Y., Danladi, E., Abdu, S. G., Aboh, H. O., & Ezeoke, J. (2016). Size effects of silver nanoparticles on the photovoltaic performance of dye sensitized solar cells. American Chemical Science Journal, 13(3), 1-8.
[23]	Calogero, G., Yum, J. H., Sinopoli, A., Di Marco, G., Gratzel, M. K. Nazeeruddin, M. K. (2012). Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells. Solar Energy, 86, 1563-1575.
[24]	Zhou, H., Wu, L., Gao, Y., & Ma, T. (2011). Dye-sensitized solar cells using 20 natural dyes as sensitizers. Journal of Photobiology A Chemistry 291, 188-194.
[25]	Calogero, G., Di Marco, G., Cazzanti, S., Caramori, S., Argazzi, R.D.C.A., & Bignozzi, C. (2010). Efficient dye sensitized solar cells using red turnip and purple wild Sicilian prickly pear fruits. International Journal of Molecular Science, 11, 254-267.
[26]	Quin, C., & Clark, A. (2007). DFT Characterization of the optical and redox properties of natural pigments relevant to dye sensitized solar cells. Chemical Physics Letters, 438, 26-30.
[27]	Zhang, D., Lanier, S. M., Downing, J. A., Avent, J. L., Lum, J., & McHale, J. L. (2008). Betalain pigments for dye sensitized solar cells. Journal of Photochemistry and Photobiology A: Chemistry, 195, 72-80.
[28]	Yirga, G., Tadesse, S., & Yohannes, T. (2016). Photoelectrochmeical Cell Based on Natural Pigments and ZnO Nanoparticles. Journal of Energy and Natural Resources, 5(1), 1-10.
[29]	Kushwaha, R., Srivastava, P., & Bahadur, L. (2013). Natural Pigments from Plants Used as Sensitizers for TiO₂ Based Dye-Sensitized Solar Cells. Journal of Energy, 2013, Article ID 654953, 8 pages.

Cite This Article

Plain Text BibTeX RIS

APA Style

Eli Danladi, Philip Musa Gyuk, Ezra Bako Danladi. (2016). Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. Journal of Energy and Natural Resources, 5(5), 53-58. https://doi.org/10.11648/j.jenr.20160505.11

Copy | Download

ACS Style

Eli Danladi; Philip Musa Gyuk; Ezra Bako Danladi. Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. J. Energy Nat. Resour. 2016, 5(5), 53-58. doi: 10.11648/j.jenr.20160505.11

Copy | Download

AMA Style

Eli Danladi, Philip Musa Gyuk, Ezra Bako Danladi. Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. J Energy Nat Resour. 2016;5(5):53-58. doi: 10.11648/j.jenr.20160505.11

Copy | Download

@article{10.11648/j.jenr.20160505.11,
  author = {Eli Danladi and Philip Musa Gyuk and Ezra Bako Danladi},
  title = {Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells},
  journal = {Journal of Energy and Natural Resources},
  volume = {5},
  number = {5},
  pages = {53-58},
  doi = {10.11648/j.jenr.20160505.11},
  url = {https://doi.org/10.11648/j.jenr.20160505.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20160505.11},
  abstract = {Chlorophyll and betalain pigments extracted from scent leaves and flower of Bougainvillea Spectabilis were used as sensitizers for nanostructured TiO2 based dye-sensitized solar cells (DSSCs), and their perfomances were investigated systematically. The light harvesting pigments have shown absorption in broad range of the visible region of the solar spectrum and appreciable adsorption onto the semiconductor surface. The photovoltaic (PV) parameters such as short circuit current density (JSC ), open circuit voltage (VOC), fill factor (FF), and overall solar conversion efficiency (η) were determined under 100 mAcm-2. The DSSC fabricated with betalains pigment from Bougainvillea Spectabilis was found to be superior to that obtained from chlorophyll pigment of scent leave (Ocimum Gratissimum). The DSSC gave a short circuit current density of 0.093 mAcm-2, open circuit voltage of 0.433 V, fill factor of 0.550, and an overall solar conversion efficiency of 0.040%. The cell sensitized with betalains pigment exhibits: (i) ~ 1.90 times improvement in conversion efficiency, (ii) ~ 2.11 times enhancement in photocurrent density, and (iii) ~ 1.38 times improvement in fill factor compared to the results obtained with the chlorophyll sensitized solar cell. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells
AU  - Eli Danladi
AU  - Philip Musa Gyuk
AU  - Ezra Bako Danladi
Y1  - 2016/09/02
PY  - 2016
N1  - https://doi.org/10.11648/j.jenr.20160505.11
DO  - 10.11648/j.jenr.20160505.11
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 53
EP  - 58
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20160505.11
AB  - Chlorophyll and betalain pigments extracted from scent leaves and flower of Bougainvillea Spectabilis were used as sensitizers for nanostructured TiO2 based dye-sensitized solar cells (DSSCs), and their perfomances were investigated systematically. The light harvesting pigments have shown absorption in broad range of the visible region of the solar spectrum and appreciable adsorption onto the semiconductor surface. The photovoltaic (PV) parameters such as short circuit current density (JSC ), open circuit voltage (VOC), fill factor (FF), and overall solar conversion efficiency (η) were determined under 100 mAcm-2. The DSSC fabricated with betalains pigment from Bougainvillea Spectabilis was found to be superior to that obtained from chlorophyll pigment of scent leave (Ocimum Gratissimum). The DSSC gave a short circuit current density of 0.093 mAcm-2, open circuit voltage of 0.433 V, fill factor of 0.550, and an overall solar conversion efficiency of 0.040%. The cell sensitized with betalains pigment exhibits: (i) ~ 1.90 times improvement in conversion efficiency, (ii) ~ 2.11 times enhancement in photocurrent density, and (iii) ~ 1.38 times improvement in fill factor compared to the results obtained with the chlorophyll sensitized solar cell. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.
VL  - 5
IS  - 5
ER  -

Copy | Download

Author Information

Eli Danladi

Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria
Philip Musa Gyuk

Department of Physics, Kaduna State University, Kaduna, Nigeria
Ezra Bako Danladi

Department of Agricultural Science, Kaduna State University, Kaduna, Nigeria

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Eli Danladi, Philip Musa Gyuk, Ezra Bako Danladi. (2016). Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. Journal of Energy and Natural Resources, 5(5), 53-58. https://doi.org/10.11648/j.jenr.20160505.11

Copy | Download

ACS Style

Eli Danladi; Philip Musa Gyuk; Ezra Bako Danladi. Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. J. Energy Nat. Resour. 2016, 5(5), 53-58. doi: 10.11648/j.jenr.20160505.11

Copy | Download

AMA Style

Eli Danladi, Philip Musa Gyuk, Ezra Bako Danladi. Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells. J Energy Nat Resour. 2016;5(5):53-58. doi: 10.11648/j.jenr.20160505.11

Copy | Download

@article{10.11648/j.jenr.20160505.11,
  author = {Eli Danladi and Philip Musa Gyuk and Ezra Bako Danladi},
  title = {Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells},
  journal = {Journal of Energy and Natural Resources},
  volume = {5},
  number = {5},
  pages = {53-58},
  doi = {10.11648/j.jenr.20160505.11},
  url = {https://doi.org/10.11648/j.jenr.20160505.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20160505.11},
  abstract = {Chlorophyll and betalain pigments extracted from scent leaves and flower of Bougainvillea Spectabilis were used as sensitizers for nanostructured TiO2 based dye-sensitized solar cells (DSSCs), and their perfomances were investigated systematically. The light harvesting pigments have shown absorption in broad range of the visible region of the solar spectrum and appreciable adsorption onto the semiconductor surface. The photovoltaic (PV) parameters such as short circuit current density (JSC ), open circuit voltage (VOC), fill factor (FF), and overall solar conversion efficiency (η) were determined under 100 mAcm-2. The DSSC fabricated with betalains pigment from Bougainvillea Spectabilis was found to be superior to that obtained from chlorophyll pigment of scent leave (Ocimum Gratissimum). The DSSC gave a short circuit current density of 0.093 mAcm-2, open circuit voltage of 0.433 V, fill factor of 0.550, and an overall solar conversion efficiency of 0.040%. The cell sensitized with betalains pigment exhibits: (i) ~ 1.90 times improvement in conversion efficiency, (ii) ~ 2.11 times enhancement in photocurrent density, and (iii) ~ 1.38 times improvement in fill factor compared to the results obtained with the chlorophyll sensitized solar cell. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Chlorophyll and Betalain as Light-Harvesting Pigments for Nanostructured TiO2 Based Dye-Sensitized Solar Cells
AU  - Eli Danladi
AU  - Philip Musa Gyuk
AU  - Ezra Bako Danladi
Y1  - 2016/09/02
PY  - 2016
N1  - https://doi.org/10.11648/j.jenr.20160505.11
DO  - 10.11648/j.jenr.20160505.11
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 53
EP  - 58
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20160505.11
AB  - Chlorophyll and betalain pigments extracted from scent leaves and flower of Bougainvillea Spectabilis were used as sensitizers for nanostructured TiO2 based dye-sensitized solar cells (DSSCs), and their perfomances were investigated systematically. The light harvesting pigments have shown absorption in broad range of the visible region of the solar spectrum and appreciable adsorption onto the semiconductor surface. The photovoltaic (PV) parameters such as short circuit current density (JSC ), open circuit voltage (VOC), fill factor (FF), and overall solar conversion efficiency (η) were determined under 100 mAcm-2. The DSSC fabricated with betalains pigment from Bougainvillea Spectabilis was found to be superior to that obtained from chlorophyll pigment of scent leave (Ocimum Gratissimum). The DSSC gave a short circuit current density of 0.093 mAcm-2, open circuit voltage of 0.433 V, fill factor of 0.550, and an overall solar conversion efficiency of 0.040%. The cell sensitized with betalains pigment exhibits: (i) ~ 1.90 times improvement in conversion efficiency, (ii) ~ 2.11 times enhancement in photocurrent density, and (iii) ~ 1.38 times improvement in fill factor compared to the results obtained with the chlorophyll sensitized solar cell. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.
VL  - 5
IS  - 5
ER  -

Copy | Download