Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene

Mingyue Kou; Wei Zuo; Xiangfu Li; Ruosong Hu; Pan Wang; Jixu Zhan

doi:doi:10.11648/j.jenr.20180701.16

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Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene

Mingyue Kou, Wei Zuo, Xiangfu Li, Ruosong Hu, Pan Wang, Jixu Zhan

Published in Journal of Energy and Natural Resources (Volume 7, Issue 1)

Received: 19 June 2018 Accepted: Published: 20 June 2018

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Abstract

Different kinds of acidified opal shale powders were obtained through the activation of natural opal shale powders with different concentrations of sulfuric acid. The natural opal shale and different acidified opal shale materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. It was found that the opal shale has good acid resistance stability. When the sulfuric acid concentration reaches a high concentration of 6 mol/L in the acidification treatment, the opal shale can still maintain its original main silica structure. Natural opal shale is a typical mesoporous material with a BET specific surface area of about 12 nm, but it also contains a small amount of micropores and macropores. Appropriate acid treatment can increase the specific surface area. An excessively high concentration of acid that exceeds 6 mol/L sulfuric acid can destroy the main structure of the cation, resulting in a decrease in the specific surface area. In this paper, the adsorptive breakthrough curves for toluene, dynamic saturated adsorption capacity and other gas adsorption performances of these materials were studied. Finally, the best adsorption material was the 2 mol/L sulfuric acid acidified opal shale at 333K under stirring for 4 hours.

Published in	Journal of Energy and Natural Resources (Volume 7, Issue 1)
DOI	10.11648/j.jenr.20180701.16
Page(s)	40-46
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Opal Shale, Acid Activation, Adsorption of Toluene

References

[1]	Li Liangbo, Chi Yong, Chen Yu, et al. Experimental study on dynamic adsorption of toluene on activated carbon fibers and the adsorbent regeneration [J]. Environmental Pollution and Control, 2011, 33 (9): 70-74.
[2]	Zheng Yuying, Dou Zhengjie, Du Han, et al. Recovery and Deep Purification of Industrial Organic Waste Gas [J]. Modern Chemical Industry, 2016 (12): 118-120.
[3]	Ren Leifu. Discovery and study of shallow shale composed of shinyshishi stone [J]. Silicate Bulletin, 1982 (2): 15-19. K.
[4]	Chai Erya, Pan Junan, Yuan Guolong and others. Preparation and Electrochemical Property of Polyaniline Coated Opal Shale/Sulfur Composite [J]. Journal of Inorganic Materials, 2017, 32 (11): 1165-1170.
[5]	Li Qingshan, Chen Jie, Gao Jie, et al. Nenjiang Opal Light Shale and Its Application in Polymer Materials [J]. Nonferrous Metals Industry Industry Guide, 2003 (5): 21-23.
[6]	Wang Zemin, Qiao Huanzeng. Study on Production of Filter Aid Using Lightweight Shale in Nenjiang River [J]. Silicate Bulletin, 1991 (6): 39-43.
[7]	Yang Dianfan, Wei Cundi, Ning Weikun, et al. Structure and adsorption properties of Nenjiang opal shale [J]. Journal of Jilin University (Earth Science Edition), 2010, 40 (5): 1061-1065.
[8]	Chen Fuming, You Hong. Discussion On The Decoloring Ability Of Light Scheme By Adsorbent [J]. Non-metallic Mining, 1994 (5): 38-40.
[9]	You Hong, Shen Jin. Lightweight shale adsorbents and their application in the decolorization of soybean oil [J]. Journal of Harbin Institute of Technology, 1994 (4): 71-74.
[10]	Fan Xuemin, Bai Chenhua, Li Guanghui, er al. Effect of Surface Treatment of Opal Shale on Structure and Properties of Supported TiO2 [J]. Multipurpose Utilization of Mineral Resources, 2018, 1 (2): 144-149.
[11]	Gu Xiaohua, Shen Hong, Li Qingshan, et al. Progress in the development and application of opal light shale [J]. Chemical Journal, 2005, 19 (4): 36-41.
[12]	Li Qingshan, Gu Xiaohua, Huang Xiang'an, et al. Research on discovery, creation and application of natural nanomaterials [C]. Symposium on Functional Textiles and Nanotechnology Applications. 2003.
[13]	Chai Erya, Pan Junan, Yuan Guolong, et al. Preparation and Electrochemical Performance of Polyaniline Coated Opal Shale/Sulfur Composites [J]. Journal of Inorganic Materials, 2017, 32 (11): 1165-1170.
[14]	Wang Zemin, Wu Jijun, Ma Xiaofan, et al. Study on the production of filter aids using Nenjiang light shale [J]. Silicate Bulletin, 1991 (6): 39-43.
[15]	Zhang Ling. Complete oxidation of formaldehyde at room temperature over zeolite supported Pt catalysts. [D]. Zhejiang University, 2017.
[16]	Tang Hongming, Meng Yingfeng, Li Yingying, et al. Experimental study on the chemical behavior of kaolinite in acid [J]. Natural Gas Industry, 2006, 26 (10): 111-113.
[17]	Stawiński W, Freitas O, Chmielarz L, et al. The influence of acid treatments over vermiculite based material as adsorbent for cationic textile dyestuffs [J]. Chemosphere, 2016, 153: 115-129.
[18]	Suárez Barrios M, Gonzalez L V F, Rodriguez M A V, et al. 1995. Acid activation of a palygorskite with HCl: development of physico-chemical, textural and surface properties [J]. Applied Clay Science, 1995, 10 (3): 247-258.
[19]	Tian G, Wang W, Li Z, et al. A functionalized hybrid silicate adsorbent derived from naturally abundant low-grade palygorskite clay for highly efficient removal of hazardous antibiotics [J]. Chemical Engineering Journal, 2016, 293: 376-385.
[20]	Huang Haifeng, Ruan Wenjuan, Chen Hongyu, et al. Adsorption performance of ketone organic waste on Y zeolite [J]. Journal of Zhejiang University of Technology, 2014, 42 (5): 513-518.
[21]	Chica A, Strohmaier K G, Iglesia E. Effects of zeolite structure and aluminum content on thiophene adsorption, desorption, and surface reactions [J]. Applied Catalysis B Environmental, 2005, 60 (3–4): 223-232.
[22]	Jiang T, Zhong W, Jafari T, et al. Siloxane D4 adsorption by mesoporous aluminosilicates [J]. Chemical Engineering Journal, 2016, 289: 356-364.
[23]	Huang Haifeng, Yu Xiang, Lu Yifeng, et al. Dynamic adsorption of VOCs by two mesoporous molecular sieves [J]. Chinese Journal of Environmental Science, 2010, 30 (4): 442-447.
[24]	Li Ziyi. Experimental study and molecular simulation of adsorption of gas phase polycyclic aromatic hydrocarbons by mesoporous materials [D]. Beijing University of Science and Technology, 2017.

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APA Style

Mingyue Kou, Wei Zuo, Xiangfu Li, Ruosong Hu, Pan Wang, et al. (2018). Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. Journal of Energy and Natural Resources, 7(1), 40-46. https://doi.org/10.11648/j.jenr.20180701.16

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ACS Style

Mingyue Kou; Wei Zuo; Xiangfu Li; Ruosong Hu; Pan Wang, et al. Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. J. Energy Nat. Resour. 2018, 7(1), 40-46. doi: 10.11648/j.jenr.20180701.16

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AMA Style

Mingyue Kou, Wei Zuo, Xiangfu Li, Ruosong Hu, Pan Wang, et al. Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. J Energy Nat Resour. 2018;7(1):40-46. doi: 10.11648/j.jenr.20180701.16

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@article{10.11648/j.jenr.20180701.16,
  author = {Mingyue Kou and Wei Zuo and Xiangfu Li and Ruosong Hu and Pan Wang and Jixu Zhan},
  title = {Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene},
  journal = {Journal of Energy and Natural Resources},
  volume = {7},
  number = {1},
  pages = {40-46},
  doi = {10.11648/j.jenr.20180701.16},
  url = {https://doi.org/10.11648/j.jenr.20180701.16},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20180701.16},
  abstract = {Different kinds of acidified opal shale powders were obtained through the activation of natural opal shale powders with different concentrations of sulfuric acid. The natural opal shale and different acidified opal shale materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. It was found that the opal shale has good acid resistance stability. When the sulfuric acid concentration reaches a high concentration of 6 mol/L in the acidification treatment, the opal shale can still maintain its original main silica structure. Natural opal shale is a typical mesoporous material with a BET specific surface area of about 12 nm, but it also contains a small amount of micropores and macropores. Appropriate acid treatment can increase the specific surface area. An excessively high concentration of acid that exceeds 6 mol/L sulfuric acid can destroy the main structure of the cation, resulting in a decrease in the specific surface area. In this paper, the adsorptive breakthrough curves for toluene, dynamic saturated adsorption capacity and other gas adsorption performances of these materials were studied. Finally, the best adsorption material was the 2 mol/L sulfuric acid acidified opal shale at 333K under stirring for 4 hours.},
 year = {2018}
}

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TY  - JOUR
T1  - Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene
AU  - Mingyue Kou
AU  - Wei Zuo
AU  - Xiangfu Li
AU  - Ruosong Hu
AU  - Pan Wang
AU  - Jixu Zhan
Y1  - 2018/06/20
PY  - 2018
N1  - https://doi.org/10.11648/j.jenr.20180701.16
DO  - 10.11648/j.jenr.20180701.16
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 40
EP  - 46
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20180701.16
AB  - Different kinds of acidified opal shale powders were obtained through the activation of natural opal shale powders with different concentrations of sulfuric acid. The natural opal shale and different acidified opal shale materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. It was found that the opal shale has good acid resistance stability. When the sulfuric acid concentration reaches a high concentration of 6 mol/L in the acidification treatment, the opal shale can still maintain its original main silica structure. Natural opal shale is a typical mesoporous material with a BET specific surface area of about 12 nm, but it also contains a small amount of micropores and macropores. Appropriate acid treatment can increase the specific surface area. An excessively high concentration of acid that exceeds 6 mol/L sulfuric acid can destroy the main structure of the cation, resulting in a decrease in the specific surface area. In this paper, the adsorptive breakthrough curves for toluene, dynamic saturated adsorption capacity and other gas adsorption performances of these materials were studied. Finally, the best adsorption material was the 2 mol/L sulfuric acid acidified opal shale at 333K under stirring for 4 hours.
VL  - 7
IS  - 1
ER  -

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Author Information

Mingyue Kou

School of Environment, Harbin Institute of Technology, Harbin, China
Wei Zuo

School of Environment, Harbin Institute of Technology, Harbin, China
Xiangfu Li

School of Environment, Harbin Institute of Technology, Harbin, China
Ruosong Hu

School of Environment, Harbin Institute of Technology, Harbin, China
Pan Wang

School of Environment, Harbin Institute of Technology, Harbin, China
Jixu Zhan

School of Environment, Harbin Institute of Technology, Harbin, China

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Plain Text BibTeX RIS

APA Style

Mingyue Kou, Wei Zuo, Xiangfu Li, Ruosong Hu, Pan Wang, et al. (2018). Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. Journal of Energy and Natural Resources, 7(1), 40-46. https://doi.org/10.11648/j.jenr.20180701.16

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ACS Style

Mingyue Kou; Wei Zuo; Xiangfu Li; Ruosong Hu; Pan Wang, et al. Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. J. Energy Nat. Resour. 2018, 7(1), 40-46. doi: 10.11648/j.jenr.20180701.16

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AMA Style

Mingyue Kou, Wei Zuo, Xiangfu Li, Ruosong Hu, Pan Wang, et al. Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene. J Energy Nat Resour. 2018;7(1):40-46. doi: 10.11648/j.jenr.20180701.16

Copy | Download

@article{10.11648/j.jenr.20180701.16,
  author = {Mingyue Kou and Wei Zuo and Xiangfu Li and Ruosong Hu and Pan Wang and Jixu Zhan},
  title = {Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene},
  journal = {Journal of Energy and Natural Resources},
  volume = {7},
  number = {1},
  pages = {40-46},
  doi = {10.11648/j.jenr.20180701.16},
  url = {https://doi.org/10.11648/j.jenr.20180701.16},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20180701.16},
  abstract = {Different kinds of acidified opal shale powders were obtained through the activation of natural opal shale powders with different concentrations of sulfuric acid. The natural opal shale and different acidified opal shale materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. It was found that the opal shale has good acid resistance stability. When the sulfuric acid concentration reaches a high concentration of 6 mol/L in the acidification treatment, the opal shale can still maintain its original main silica structure. Natural opal shale is a typical mesoporous material with a BET specific surface area of about 12 nm, but it also contains a small amount of micropores and macropores. Appropriate acid treatment can increase the specific surface area. An excessively high concentration of acid that exceeds 6 mol/L sulfuric acid can destroy the main structure of the cation, resulting in a decrease in the specific surface area. In this paper, the adsorptive breakthrough curves for toluene, dynamic saturated adsorption capacity and other gas adsorption performances of these materials were studied. Finally, the best adsorption material was the 2 mol/L sulfuric acid acidified opal shale at 333K under stirring for 4 hours.},
 year = {2018}
}

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TY  - JOUR
T1  - Characterization of Acidified Opal Shale and Dynamic Adsorption of Toluene
AU  - Mingyue Kou
AU  - Wei Zuo
AU  - Xiangfu Li
AU  - Ruosong Hu
AU  - Pan Wang
AU  - Jixu Zhan
Y1  - 2018/06/20
PY  - 2018
N1  - https://doi.org/10.11648/j.jenr.20180701.16
DO  - 10.11648/j.jenr.20180701.16
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 40
EP  - 46
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20180701.16
AB  - Different kinds of acidified opal shale powders were obtained through the activation of natural opal shale powders with different concentrations of sulfuric acid. The natural opal shale and different acidified opal shale materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. It was found that the opal shale has good acid resistance stability. When the sulfuric acid concentration reaches a high concentration of 6 mol/L in the acidification treatment, the opal shale can still maintain its original main silica structure. Natural opal shale is a typical mesoporous material with a BET specific surface area of about 12 nm, but it also contains a small amount of micropores and macropores. Appropriate acid treatment can increase the specific surface area. An excessively high concentration of acid that exceeds 6 mol/L sulfuric acid can destroy the main structure of the cation, resulting in a decrease in the specific surface area. In this paper, the adsorptive breakthrough curves for toluene, dynamic saturated adsorption capacity and other gas adsorption performances of these materials were studied. Finally, the best adsorption material was the 2 mol/L sulfuric acid acidified opal shale at 333K under stirring for 4 hours.
VL  - 7
IS  - 1
ER  -

Copy | Download