Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed <i>Pongamia Pinnata</i> Seed Oil and Dimethyl Carbonate

Balaji Panchal; Qin Shenjun; Wang Jinxi; Bian Kai; Tao Chang

doi:doi:10.11648/j.ajee.20180603.11

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Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate

Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang

Published in American Journal of Energy Engineering (Volume 6, Issue 3)

Received: 20 October 2018 Accepted: 2 November 2018 Published: 28 November 2018

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Abstract

The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.

Published in	American Journal of Energy Engineering (Volume 6, Issue 3)
DOI	10.11648/j.ajee.20180603.11
Page(s)	21-28
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Pongamia Pinnata Oil, Iron Oxide Nano-catalyst, Dimethyl Carbonate, TLC, GC-MS

References

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APA Style

Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. (2018). Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. American Journal of Energy Engineering, 6(3), 21-28. https://doi.org/10.11648/j.ajee.20180603.11

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ACS Style

Balaji Panchal; Qin Shenjun; Wang Jinxi; Bian Kai; Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am. J. Energy Eng. 2018, 6(3), 21-28. doi: 10.11648/j.ajee.20180603.11

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AMA Style

Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am J Energy Eng. 2018;6(3):21-28. doi: 10.11648/j.ajee.20180603.11

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@article{10.11648/j.ajee.20180603.11,
  author = {Balaji Panchal and Qin Shenjun and Wang Jinxi and Bian Kai and Tao Chang},
  title = {Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate},
  journal = {American Journal of Energy Engineering},
  volume = {6},
  number = {3},
  pages = {21-28},
  doi = {10.11648/j.ajee.20180603.11},
  url = {https://doi.org/10.11648/j.ajee.20180603.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajee.20180603.11},
  abstract = {The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.},
 year = {2018}
}

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TY  - JOUR
T1  - Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate
AU  - Balaji Panchal
AU  - Qin Shenjun
AU  - Wang Jinxi
AU  - Bian Kai
AU  - Tao Chang
Y1  - 2018/11/28
PY  - 2018
N1  - https://doi.org/10.11648/j.ajee.20180603.11
DO  - 10.11648/j.ajee.20180603.11
T2  - American Journal of Energy Engineering
JF  - American Journal of Energy Engineering
JO  - American Journal of Energy Engineering
SP  - 21
EP  - 28
PB  - Science Publishing Group
SN  - 2329-163X
UR  - https://doi.org/10.11648/j.ajee.20180603.11
AB  - The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.
VL  - 6
IS  - 3
ER  -

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Author Information

Balaji Panchal

Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China
Qin Shenjun

Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China
Wang Jinxi

Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China
Bian Kai

Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China
Tao Chang

Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

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APA Style

Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. (2018). Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. American Journal of Energy Engineering, 6(3), 21-28. https://doi.org/10.11648/j.ajee.20180603.11

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ACS Style

Balaji Panchal; Qin Shenjun; Wang Jinxi; Bian Kai; Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am. J. Energy Eng. 2018, 6(3), 21-28. doi: 10.11648/j.ajee.20180603.11

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AMA Style

Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am J Energy Eng. 2018;6(3):21-28. doi: 10.11648/j.ajee.20180603.11

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@article{10.11648/j.ajee.20180603.11,
  author = {Balaji Panchal and Qin Shenjun and Wang Jinxi and Bian Kai and Tao Chang},
  title = {Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate},
  journal = {American Journal of Energy Engineering},
  volume = {6},
  number = {3},
  pages = {21-28},
  doi = {10.11648/j.ajee.20180603.11},
  url = {https://doi.org/10.11648/j.ajee.20180603.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajee.20180603.11},
  abstract = {The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.},
 year = {2018}
}

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TY  - JOUR
T1  - Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate
AU  - Balaji Panchal
AU  - Qin Shenjun
AU  - Wang Jinxi
AU  - Bian Kai
AU  - Tao Chang
Y1  - 2018/11/28
PY  - 2018
N1  - https://doi.org/10.11648/j.ajee.20180603.11
DO  - 10.11648/j.ajee.20180603.11
T2  - American Journal of Energy Engineering
JF  - American Journal of Energy Engineering
JO  - American Journal of Energy Engineering
SP  - 21
EP  - 28
PB  - Science Publishing Group
SN  - 2329-163X
UR  - https://doi.org/10.11648/j.ajee.20180603.11
AB  - The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.
VL  - 6
IS  - 3
ER  -

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