Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution

Shu Mengmeng; Zhao Youjiao; Long Shijun; Li Xuefeng

doi:doi:10.11648/j.sd.20170507.21

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Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution

Shu Mengmeng, Zhao Youjiao, Long Shijun, Li Xuefeng

Received: 28 December 2017 Accepted: Published: 28 December 2017

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Abstract

Polymer hydrogels are a type of soft and wet materials with three-dimensional network structure, large water content and hydrophilicity. It plays a very important effect in the human tissue engineering because it has some excellent characteristics as human active tissue. In this study, physical/chemical hybrid cross-linked hydrogels were prepared by "one-pot" method, and the mechanical properties of hydrogels were effectively controlled by immersing in different concentration of sodium chloride solution. The tensile strength of the hydrogels can be increased from 0.1 MPa to 1.8 MPa by the controlling the concentration of the sodium chloride solution, and the elongation at break increased from 770.3% to 1320.9%. It was found that the hybrid cross-crosslinked hydrogels has good self-healing properties. Put the cut gels section together, it can be self-healing, and the elongation at break of healing the gels was restored to the original gels of the 30%. Therefore, this high ionic content of the hydrogels have excellent performance in the human cartilage materials, medical materials and electrical properties. The hybrid dual crosslinked hydrogels has excellent overall properties, which are characterized by high-strength hydrogels obtained from polyelectrolytes and "high ionic solutions". So it is of potential value in the application of high performance ionic conductive hydrogels.

DOI	10.11648/j.sd.20170507.21
Published in	Science Discovery (Volume 5, Issue 7, December 2017)
Page(s)	534-537
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

One-pot Method, Polyacrylic Acid, Hybrid Dual Crosslinked Hydrogels, Mechanical Properties, Self-Healing Properties

References

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[3]	B. V. Slaughter, S. S. Khurshid and O. Z. Fisher, “Hydrogels in regenerative medicine,” J. Advanced materials. 21, 3307-3329, 2009.
[4]	N. A. Peppas, Y. Huang and M. Torres-Lugo, “Physicochemical foundations and structural design of hydrogels in medicine and biology,” J. Annual Review of Biomedical Engineering. 2, 9-29, 2000.
[5]	J. Wang, J. Wei and S. Su, “Ion-linked double-network hydrogel with high toughness and stiffness,” J. Journal of Materials Science. 50, 5458-5465, 2015.
[6]	T. L. Sun, T. Kurokawa and S. Kuroda, “Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity,” J. Nature Materials. 12, 932-937, 2013.
[7]	许凤兰，李玉宝，王学江.纳米羟基磷灰石/聚乙烯醇复合水凝胶的制备和性能研究[J].功能材料，2004,35:509-512。
[8]	H. Zhou, G. Xu and J. Li, “Preparation and self-healing behaviors of poly (acrylic acid)/cerium ions double network hydrogels,” J. Macromolecular Research. 23, 1098-1102, 2015.
[9]	Y. Yang, X. Wang and F. Yang, “A Universal Soaking Strategy to Convert Composite Hydrogels into Extremely Tough and Rapidly Recoverable Double-Network Hydrogels,” J. Advanced Materials. 28, 7178-7184, 2016.
[10]	Y. Hu, Z. Du and X. Deng, “Dual physically cross-linked hydrogels with high stretchability, toughness, and good self-recoverability,” J. Macromolecules. 49, 5660-5668, 2006.
[11]	Q. Chen, L. Zhu and C. Zhao, “A Robust, One-Pot Synthesis of Highly Mechanical and Recoverable Double Network Hydrogels Using Thermoreversible Sol-Gel Polysaccharide,” J. Advanced Materials. 25, 4171-4176, 2013.

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APA Style

Shu Mengmeng, Zhao Youjiao, Long Shijun, Li Xuefeng. (2017). Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Science Discovery, 5(7), 534-537. https://doi.org/10.11648/j.sd.20170507.21

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ACS Style

Shu Mengmeng; Zhao Youjiao; Long Shijun; Li Xuefeng. Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Sci. Discov. 2017, 5(7), 534-537. doi: 10.11648/j.sd.20170507.21

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AMA Style

Shu Mengmeng, Zhao Youjiao, Long Shijun, Li Xuefeng. Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Sci Discov. 2017;5(7):534-537. doi: 10.11648/j.sd.20170507.21

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@article{10.11648/j.sd.20170507.21,
  author = {Shu Mengmeng and Zhao Youjiao and Long Shijun and Li Xuefeng},
  title = {Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution},
  journal = {Science Discovery},
  volume = {5},
  number = {7},
  pages = {534-537},
  doi = {10.11648/j.sd.20170507.21},
  url = {https://doi.org/10.11648/j.sd.20170507.21},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20170507.21},
  abstract = {Polymer hydrogels are a type of soft and wet materials with three-dimensional network structure, large water content and hydrophilicity. It plays a very important effect in the human tissue engineering because it has some excellent characteristics as human active tissue. In this study, physical/chemical hybrid cross-linked hydrogels were prepared by "one-pot" method, and the mechanical properties of hydrogels were effectively controlled by immersing in different concentration of sodium chloride solution. The tensile strength of the hydrogels can be increased from 0.1 MPa to 1.8 MPa by the controlling the concentration of the sodium chloride solution, and the elongation at break increased from 770.3% to 1320.9%. It was found that the hybrid cross-crosslinked hydrogels has good self-healing properties. Put the cut gels section together, it can be self-healing, and the elongation at break of healing the gels was restored to the original gels of the 30%. Therefore, this high ionic content of the hydrogels have excellent performance in the human cartilage materials, medical materials and electrical properties. The hybrid dual crosslinked hydrogels has excellent overall properties, which are characterized by high-strength hydrogels obtained from polyelectrolytes and "high ionic solutions". So it is of potential value in the application of high performance ionic conductive hydrogels.},
 year = {2017}
}

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TY  - JOUR
T1  - Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution
AU  - Shu Mengmeng
AU  - Zhao Youjiao
AU  - Long Shijun
AU  - Li Xuefeng
Y1  - 2017/12/28
PY  - 2017
N1  - https://doi.org/10.11648/j.sd.20170507.21
DO  - 10.11648/j.sd.20170507.21
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 534
EP  - 537
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20170507.21
AB  - Polymer hydrogels are a type of soft and wet materials with three-dimensional network structure, large water content and hydrophilicity. It plays a very important effect in the human tissue engineering because it has some excellent characteristics as human active tissue. In this study, physical/chemical hybrid cross-linked hydrogels were prepared by "one-pot" method, and the mechanical properties of hydrogels were effectively controlled by immersing in different concentration of sodium chloride solution. The tensile strength of the hydrogels can be increased from 0.1 MPa to 1.8 MPa by the controlling the concentration of the sodium chloride solution, and the elongation at break increased from 770.3% to 1320.9%. It was found that the hybrid cross-crosslinked hydrogels has good self-healing properties. Put the cut gels section together, it can be self-healing, and the elongation at break of healing the gels was restored to the original gels of the 30%. Therefore, this high ionic content of the hydrogels have excellent performance in the human cartilage materials, medical materials and electrical properties. The hybrid dual crosslinked hydrogels has excellent overall properties, which are characterized by high-strength hydrogels obtained from polyelectrolytes and "high ionic solutions". So it is of potential value in the application of high performance ionic conductive hydrogels.
VL  - 5
IS  - 7
ER  -

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Author Information

Shu Mengmeng

School of Materials and chemical Engineering, Hubei University of Technology, Wuhan, China
Zhao Youjiao

School of Materials and chemical Engineering, Hubei University of Technology, Wuhan, China
Long Shijun

School of Materials and chemical Engineering, Hubei University of Technology, Wuhan, China; Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan, China
Li Xuefeng

School of Materials and chemical Engineering, Hubei University of Technology, Wuhan, China; Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan, China

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APA Style

Shu Mengmeng, Zhao Youjiao, Long Shijun, Li Xuefeng. (2017). Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Science Discovery, 5(7), 534-537. https://doi.org/10.11648/j.sd.20170507.21

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ACS Style

Shu Mengmeng; Zhao Youjiao; Long Shijun; Li Xuefeng. Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Sci. Discov. 2017, 5(7), 534-537. doi: 10.11648/j.sd.20170507.21

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AMA Style

Shu Mengmeng, Zhao Youjiao, Long Shijun, Li Xuefeng. Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution. Sci Discov. 2017;5(7):534-537. doi: 10.11648/j.sd.20170507.21

Copy | Download

@article{10.11648/j.sd.20170507.21,
  author = {Shu Mengmeng and Zhao Youjiao and Long Shijun and Li Xuefeng},
  title = {Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution},
  journal = {Science Discovery},
  volume = {5},
  number = {7},
  pages = {534-537},
  doi = {10.11648/j.sd.20170507.21},
  url = {https://doi.org/10.11648/j.sd.20170507.21},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20170507.21},
  abstract = {Polymer hydrogels are a type of soft and wet materials with three-dimensional network structure, large water content and hydrophilicity. It plays a very important effect in the human tissue engineering because it has some excellent characteristics as human active tissue. In this study, physical/chemical hybrid cross-linked hydrogels were prepared by "one-pot" method, and the mechanical properties of hydrogels were effectively controlled by immersing in different concentration of sodium chloride solution. The tensile strength of the hydrogels can be increased from 0.1 MPa to 1.8 MPa by the controlling the concentration of the sodium chloride solution, and the elongation at break increased from 770.3% to 1320.9%. It was found that the hybrid cross-crosslinked hydrogels has good self-healing properties. Put the cut gels section together, it can be self-healing, and the elongation at break of healing the gels was restored to the original gels of the 30%. Therefore, this high ionic content of the hydrogels have excellent performance in the human cartilage materials, medical materials and electrical properties. The hybrid dual crosslinked hydrogels has excellent overall properties, which are characterized by high-strength hydrogels obtained from polyelectrolytes and "high ionic solutions". So it is of potential value in the application of high performance ionic conductive hydrogels.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Mechanical Properties of Hybrid Double Crosslinked Hydrogel Regulated by Sodium Chloride Solution
AU  - Shu Mengmeng
AU  - Zhao Youjiao
AU  - Long Shijun
AU  - Li Xuefeng
Y1  - 2017/12/28
PY  - 2017
N1  - https://doi.org/10.11648/j.sd.20170507.21
DO  - 10.11648/j.sd.20170507.21
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 534
EP  - 537
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20170507.21
AB  - Polymer hydrogels are a type of soft and wet materials with three-dimensional network structure, large water content and hydrophilicity. It plays a very important effect in the human tissue engineering because it has some excellent characteristics as human active tissue. In this study, physical/chemical hybrid cross-linked hydrogels were prepared by "one-pot" method, and the mechanical properties of hydrogels were effectively controlled by immersing in different concentration of sodium chloride solution. The tensile strength of the hydrogels can be increased from 0.1 MPa to 1.8 MPa by the controlling the concentration of the sodium chloride solution, and the elongation at break increased from 770.3% to 1320.9%. It was found that the hybrid cross-crosslinked hydrogels has good self-healing properties. Put the cut gels section together, it can be self-healing, and the elongation at break of healing the gels was restored to the original gels of the 30%. Therefore, this high ionic content of the hydrogels have excellent performance in the human cartilage materials, medical materials and electrical properties. The hybrid dual crosslinked hydrogels has excellent overall properties, which are characterized by high-strength hydrogels obtained from polyelectrolytes and "high ionic solutions". So it is of potential value in the application of high performance ionic conductive hydrogels.
VL  - 5
IS  - 7
ER  -

Copy | Download