Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition

Zhao Jingze; Liu Rongjun; Wang Yanfei; Cao Yingbin

doi:doi:10.11648/j.sd.20180604.12

| Peer-Reviewed

Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition

Zhao Jingze, Liu Rongjun, Wang Yanfei, Cao Yingbin

Published in Science Discovery (Volume 6, Issue 4)

Received: 19 July 2018 Accepted: Published: 20 July 2018

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Process control of the oriented growth of vertical aligned carbon nanotube arrays and preparation of various ordered structure of carbon nanotube films is the major challenge for practical application. In order to better understand the parameters governing the catalytic properties of the catalytic nanoparticles, this paper summarizes the advances in the catalyst used for vertical aligned carbon nanotube arrays prepared by catalytic chemical vapor deposition, and the process parameters were considered to be able to control the particles size, composition, structure of catalyst. And investigations into the effects of during time, temperature, atmosphere in pre-treatment process, and the transition layer on catalyst morphology evaluation were further found that the catalyst particles size, distribution and density can be transformed through the surface diffusion and inter-layer diffusion influenced by those process.

Published in	Science Discovery (Volume 6, Issue 4)
DOI	10.11648/j.sd.20180604.12
Page(s)	231-242
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Catalytic Chemical Vapor Deposition, Vertical Aligned Carbon Nanotube Arrays, Catalyst, Structure Tailoring

References

[1]	M.麦亚潘.碳纳米管-科学与应用[M],北京，科学出版社，2007。
[2]	A E Aliev, M E Kozlov, A A Kuznetsov, et al. Giant-stroke, super elastic carbon nanotube aerogel muscles[J], Science, 2009, 323, 1575–1578.
[3]	P Simon, Y Gogotsi, Materials for electrochemical capacitors[J], Nature. Materials. 2008, 7(11): 7845–7854.
[4]	Zu-Po Yang, Lijie Ci, James A. Bur, S-Y Lin, et al., Experimental Observation of an Extremely Dark Material Made By a Low-Density Nanotube Array[J], Nano Letter, 2008, 8(2): 446-451.
[5]	Yang Liu, Yichun Zhang, Xu Wang, et al., Excel-lent Microwave Absorbing Property of Multiwalled Carbon Nanotubes with Skin–Core Heterostructure Formed by Outer Dominated Fluorination[J], The Journal of Physics Chemical C, 2018, 122(11):6357-6367.
[6]	Lin Qiu, Kimberly Scheider, RA Suhaib, Optimized Growth of Muti-walled Carbon Nanotube Arrays for Thermal interface Applications[J], Journal of Engineering Thermophysics, 2017, 38(6): 1323-1327.
[7]	Zhang M, Fang S, Zakhidov A A, et al. Strong, transparent, multifunctional, carbon nanotube sheets[J]. Science, 2005, 309(5738): 1215–1219.
[8]	Feng C, Liu K, Wu J S, et al. Flexible, stretchable, transparent conducting films made from superaligned carbon nanotubes. Advanced Functional Materials, 2010, 10(6): 885–891.
[9]	Kohei Mizuno a, Juntaro Ishii b, Hideo Kishida, et al. A black body absorber from vertically aligned single-walled carbon[J]. PNAS, 2009, 106(15):6044-6047.
[10]	Zu-Po Yang, Mei-Li Hsieh, James A. Bur, et al. Experimental observation of extremely weak optical scattering from an interlocking carbon nanotube array[J], Applied Optics, 2011, 50(13): 1850-1855.
[11]	Zhe Yin, Huimin Wang, Muqiang Jian, et al., Extremely Black Vertically Aligned Carbon Nanotube Arrays for Solar Steam Generation[J], APPLIEDMATERIALS & INTERFACES, 2017, 9(34):28696-28603.
[12]	Lei Zhang, Bin Zhao, Chuan Jiang, et al., Preparation and Transport Performances of High-Density, Aligned Carbon Nanotube Membranes[J], Nanoscale Research Letters, 2015, 10:266.
[13]	S. S. Fan, M. G. Chapline, N. R. Franklin, et al. Self-oriented regular arrays of carbon nanotubes and their field emission properties[J], Science, 1999, 283 (5401):512–519.
[14]	K Hata, D N Futaba, K Mizuno, S Iijima, et al., Water-assisted highly efficient synthesis of impurity-free single-walled carbon nanotubes[J], Science, 2004, 306:1362-1364.
[15]	C Mattevi, C T Wirth, S Hofmann, et al. In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests[J], The Journal of Physics Chemical C, 2008, 112, 12207–12213.
[16]	B Kitiyanan, W E Alvarez, J H Harwell, et al. Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co–Mo catalysts[J], Chemical. Physics Letter, 2000, 317, 497–503.
[17]	Qi Li, Anderson D. Smith, Mazharul Haque, et al. Graphite paper/carbon nanotube composite:A potential supercapacitor electrode for powering microsystem technology[A]. Journal of physics: Conference Series. 2017, 922(1):1-6.
[18]	Linquan Ping, Peng-Xiang Hou, Han Wang, et al,. Clean, fast and scalable transfer of ultrathin/patterned vertically-aligned carbon nanotube arrays[J], Carbon, 133:275-282.
[19]	Shota Miura, Yu Yoshihara, Mayu Asaka, Kei Hasegawa, et al., Millimeter-tall carbon nanotube arrays grown on aluminum Substrates[J], Carbon, 2018, 130:834-842.
[20]	Moisala A, Nasibulin AG, Kauppinen EI. The role of metal nanoparticles in the catalytic production of single-walled carbon nanotubes-a review[J], Journal of Physics: Condens Matter 2003, 15: S3011-3035.
[21]	Dupuis AC. The catalyst in the CCVD of carbon nanotubes-a review[J]. Progress in Material Science, 2005, 50(8):929–961.
[22]	Irle S, Ohta Y, Okamoto Y, et al. Milestones in molecular dynamics simulations of single- walled carbon nanotube formation: a brief critical review[J]. Nano Res, 2009, 2(10):755–767.
[23]	Hong G, Chen YB, Li P, Zhang J. Controlling the growth of single-walled carbon nanotubes on surfaces using metal and non-metal catalysts[J]. Carbon, 2012, 50(6):2067–2082.
[24]	Tessonnier JP, Su DS. Recent progress on the growth mechanism of carbon nanotubes: a review[J]. Chemsuschem, 2011, 4(7):824–47.
[25]	Xu J, Saeys M. First principles study of the stability and the formation kinetics of subsurface and bulk carbon on a Ni catalyst. J Phys Chem C 2008; 112 (26) :9679–85.
[26]	Wei-Qiao Deng, Xin Xu, and William A. Goddard, A Two-Stage Mechanism of Bimetallic Catalyzed Growth of Single-Walled Carbon Nanotubes[J]. Nano Letter, 2004, 4(12):2331-2335.
[27]	Yuki Matsuoka and Masamichi Yoshimura，Effect of catalytic metals of various elements on synthesis of graphite-capped, vertically aligned carbon nanotube arrays[J]，Japanese Journal of Applied Physics, 2014, 53(4):045501.
[28]	Yang W, Feng Y, Chu W, Catalytic chemical vapor deposition of methane to carbon nanotubes: copper promoted effect of Ni/MgO catalysts[J]. Journal of Nanotechnology, 2014, 1-5.
[29]	A J Hart, A H Slocum, Rapid growth and flow-mediated nucleation of millimeter-scale aligned carbon nanotube structures from a thin-film catalyst[J], Journal of Physics Chemical B, 2006, 110 (110):8250–8257.
[30]	Takeo Yamada, Tatsunri Namai, Kenji Hata, et al. Size-selective growth of double-walled carbon nanotube forests from engineered iron catalysts[J], Nature nanotechnology, 2006, 1(2): 131-136.
[31]	Seung-Woong Lee, Jaeseok Han and Hyunsik Im，Facile Method to Control the Diameter and Density of Carbon Nanotubes by Using a Catalyst-embedded Supporting Layer[J]，Journal of the Korean Physical Society, 2015, 66(11): 1715-1719.
[32]	Mandar Kini, Stefan E Schulz, Effects of catalyst configurations and process conditions on the formation of catalyst nanoparticles and growth of single-walled carbon nanotubes[J], Microelectronic Engineering, 2016, 167:95-104.
[33]	N. Bouts, M. Gaillard, L. Donero, et al. Growth control of carbon nanotubes using nanocomposite nickel/carbon thin films[J], The Solid Films, 2017, 630:38-47.
[34]	Toshiyuki Ohashi, Toshiyuki Shima, Synthesis of vertically aligned single-walled carbon nanotubes with metallic chirality through facet control of catalysts[J], Carbon, 2015, 87: 453-461.
[35]	M. Knez, K. Nielsch, and L. Niinisto, Synthesis and surface engineering of complex nanostructures by atomic layer deposition[J], Advanced Materials. 2007, 19(21):3425–3438.
[36]	DRG. Mitchell, DJ Attard, JR Bartlett, TEM and ellipsometry studies of nanolaminate oxide films prepared using atomic layer deposition[J], Applied Surface Science, 2005, 243(1):265–277.
[37]	Bingan Chen, Can Zhang, Santiago Esconjauregui, et al. Carbon nanotube forests growth using catalysts from atomic layer deposition[J], Journal of Applied Physics, 2014, 115(14):878.
[38]	YANG Chao, LI Ying, YAN Lu, Influence of Catalyst Film Thickness Deposited by Atomic Layer Deposition on Growth of Aligned Carbon Nanotubes[J], Journal of Inorganic Materials, 2016, 36(17): 681- 686.
[39]	Lei Tang, Qichong Zhang, Chaowei Li, et al. Atomic layer deposition of Al2O3 catalysts for narrow diameter distributed single-walled carbon nanotube arrays growth[J], Carbon, 2016: 11547.
[40]	田民波，李正操，薄膜技术与薄膜材料[M],清华大学出版社，2011。
[41]	Naoki Yoshikawa, Takuma Asari, Naoki Kishi, et al. An efficient fabrication of vertically aligned carbon nanotubes on flexible aluminum foils by catalyst supported chemical vapor deposition[J], Nanotechnology, 2008, 19(24):245607.
[42]	Kai Zhang, Taotao Li, Lin Ling，et al., Facile synthesis of high density carbon nanotube array by a deposition -growth -densification process[J], Carbon, 2017, 114:435-440.
[43]	Douglas K Russell, Gas-Phase Pyrolysis Mchanisms in Organometallic CVD[J], Chemical Vapor Deposition, 1996, 2(6): 223-233.
[44]	On Mero, Efrat Shawat, Gilbert D, et al. Air-stable nanogranular Fe thin films formed by Chemical Vapor Deposition of triiron dodecacarbonyl as catalysts for carbon nanotube growth[J], Thin Sold Films. 2014, 550:76-84.
[45]	Ioannis G Aviziotis, Thomas Duguet, Combined Macro / Nanoscale Investigation of the Chemical Vapor Deposition of Fe from Fe(CO)5[J], Advanced Materials Interfaces, 2017, 4(18): 1601185.
[46]	Qiang Zhang, Jia-Qi Huang, Meng-Qiang Zhao, et al. Modulating the diameter of carbon nanotubes in array form via floating catalyst chemical vapor deposition[J]，Applied Physics A, 2009, 94(4) : 853-860.
[47]	Xiaoshuang Yang, Lixiang Yuan, Vanessa K，et al. Facile Preparation of Free-Standing Carbon Nanotube Arrays Produced Using Two-Step Floating-Ferrocene Chemical VaporDeposition[J], AppliedMaterials & Interfaces, 2012, 4(3) : 1417-1422.
[48]	Kazunori Kuwana, Kozo Saito, Modeling CVD synthesis of carbon nanotubes:Nanoparticle formation from ferrocene[J], Carbon, 2005, 43(10):2088-2095.
[49]	HJ Kim, Eugene Oh, Jaegeun Lee, KH Lee, Synthesis of single-walled carbon nanotubes using hemoglobin-based iron catalyst[J], Carbon, 2011, 50(2): 722-726.
[50]	李照彬，基于光伏碳纳米管阵列的制备及其陷光性能初步研究[M],燕山大学，2016.5。
[51]	Dawei Li, Lujun Pan, Juanjuan Qian, et al. Highly efficient synthesis of carbon nanocoils by catalyst particles prepared by a sol–gel method[J], Carbon, 2010, 48(1):170-175.
[52]	林青，贺琪，化学气相沉积法制备碳纳米管有序阵列[J],青岛大学学报（工程技术版），2008，3：23-29。
[53]	欧阳雨,刘启鑫,Mo—Fe催化剂中Mo含量对SWCNTs的制备影响[J],临沂师范学院学报,2007,29(6):31-35。
[54]	牛志强, 方炎, 催化剂组分对制备单壁碳纳米管的影响[J], 物理学报, 2007, 56(3):1796-1801。
[55]	Chunhua Li, Kefu Yao, Ji Liang, Study on the features of multiwalled carbon nanotube upported nickel aluminum mixed oxides[J], Applied Catalysis A:General, 2004, 261(2):221-224.
[56]	NIE Jing-Qi, ZHANG Qiang, ZHAO Meng- Qiang, et al. Synthesis of high quality singlewall carbon nanotubes on natural sepiolite and their use for phenol absorption[J]. Carbon. 2011, 49: 1568-1580.
[57]	TANG S, ZHONG Z, XIONG Z, et al. Controlled growth of single-walled carbon nanotubes by catalytic decomposition of CH4 over Mo/Co/MgO catalysts[J]. Chemical Phrsics Letters, 2001, 350: 19-26.
[58]	Kiyofumi Yamagiwa, Yusuke Ayato, Jun Kuwano，Liquid-phase synthesis of highly aligned carbon nanotubes on preheated stainless steel substrates[J], Carbon, 2016, 98:225-231.
[59]	Gilbert D. Nessim, A. John Hart, Jin S. Kim, et al. Tuning of Vertically-Aligned Carbon Nanotube Diameter and Areal Density through Catalyst Pre-Treatment[J], Nano Letters, 2008, 8 (11): 3587-3593.
[60]	Eti Teblum, Yossi Gofer, Cary L Pint, et al. Role of Catalyst Oxidation State in the Growth of Vertically Aligned Carbon Nanotubes[J], The Journal of Physical Chemistry C, 2012, 116(46): 24522-24528.
[61]	Sharma R, Chee SW, Herzing A, Miranda R, Rez P. Evaluation of the role of Au in improving catalytic activity of Ni nanoparticles for the formation of one-dimensional carbon nanostructures[J]. Nano Letter 2011;11(6):2464–671.
[62]	Gilbert D. Nessim, A. John Hart, Jin S. Kim, et al, Tuning of Vertically-Aligned CarbonNanotube Diameter and Areal Density[J], Nano Letters, 2008, 8(11), 3587-3593.
[63]	KH Kim, Aurélien Gohier, Jean-Eric Bouree, et al. The role of catalytic nanoparticle pretreatment on the growth of vertically aligned carbon nanotubes by hot-filament chemical vapor deposition[J], Thin Solid Flims, 2015, 575(23), 84-91.
[64]	Manuel Schweiger a, Maximilian Schaudig a, Florentina Gannott, et al., Controlling the diameter of aligned single-walled carbon nanotubes on quartz via catalyst reduction time[J], Carbon, 2015, 95:452-459.
[65]	S. Sakurai, H. Nishino, D. N. Futaba, S. Yasuda, T. Yamada, A. Maigne, et al., Role of subsurface diffusion and Ostwald ripening in catalyst formation for singlewalled carbon nanotube forest growth, J. Am. Chem. Soc. 2012, 134 (4) :2148-2153.
[66]	Y. Hu, L. Kang, Q. Zhao, H. Zhong, S. Zhang, L. Yang, et al., Growth of highdensity horizontally aligned SWNT arrays using Trojan catalysts, Nature Communication, 2015, 6: 6099.
[67]	S. Pisana, M. Cantoro, A. Parvez, et al., The role of precursor gases on the surface restructuring of catalyst films during carbon nanotube growth[J], Physica E, 2007, 37:1-5.
[68]	Minjae J, Kwang Y E, Young-Joon B, et a1. Effect of NH3 environmental gas on the growth of aligned carbon nanotube in catalystically pyrolizing C2H2[J]. Thin Solid Films，2001, 398: 150-155.
[69]	Harutyunyan A R, Chen G, Paronyan T M, et al. Preferential Growth of Single-Walled Carbon Nanotubes with Metallic Conductivity, Science, 2009, 326, 116−120.
[70]	Martin Fouquet, Bernhard C Bayer, Santiago Esconjauregui, Effect of Catalyst Pretreatment on Chirality-Selective Growth of Single-Walled Carbon Nanotubes[J], The Journal of Physical Chemistry C, 2014, 118(11):5773-5781.
[71]	J D Carey, L L Ong and S R P Silva, Formation of low-temperature self-organized nanoscale nickel metal islands[J], Nanotechnology, 2003, 14(11): 1223- 1227.
[72]	F Z Bouanis, I Florea, M Bouanis, D Muller, et al., Diameter controlled growth of SWCNTs using Ru as catalyst precursors coupled with atomic hydrogen treatment[J], Chemical Engineering Journal, 2017, 332: 92-101.
[73]	Zhaoli Gao, Xinfeng Zhang, Kai Zhang, and Matthew M F Yuen, Growth of Vertically Aligned Carbon Nanotube Arrays on Al Substrates through Controlled Diffusion of Catalyst[J], The Journal of Physical Chemistry C, 2015, 119(27):1-35.
[74]	Venables J A. The chemical physics of solid surfaces. In:King DA, Woodruff DP, editors. Growth and properties of ultrathin epitaxial layers, 1997, 8, 1–45.
[75]	Futaba D N, Hata K, Namai T, et al., 84% catalyst activity of water-assisted growth of single walled carbon nanotube forest characteriza-tion by a statistical and macroscopic approach[J]. The Journal of Physics Chemistry B, 2006, 110(15): 8035–8038.
[76]	See, for example, Henrich V E and Cox P A 1994 The Surface Science of Metal Oxides (Cambridge: Cambridge University Press) chapter 5.
[77]	R. Pretorius, J. M. Harris, M.-A. Nicolet, Solid-State Electron. 21(1978) 667.
[78]	Mattevi C，Wirth C T，Hofmann S，et al. In-situ X-ray photoelectron spectroscopy study of catalyst-support interactions and growth of carbon nanotube forests[J]. The Journalof Physical Chemistry C，2008，112（32）：12207-12213.
[79]	Bingan Chen, Can Zhang, Santiago Esconjauregui, et al., Carbon nanotube forests growthusing catalysts from atomic layer deposition[J], Journal of Applied Physics, 2014, 115(14):144303.
[80]	Yani Zhang, Gengzhi Sun, Zhaoyao Zhan, and Lianxi Zheng, Influence of Al2O3 buffer layer on catalyst morphology and spinnability of carbon nanotube arrays[J], J. Mater. Sci., 2017, 52:6196-6204.
[81]	Han Z J，Ostrikov K. Uniform，dense arrays of vertically aligned，large-diameter single-walled carbon nanotubes[J]. Journal of the American Chemical Society，2012，134（13）：6018-6024.
[82]	Guohai Chen a, Shunsuke Sakurai, Motoo Yumura，et al., Highly pure, millimeter-tall, sub-2-nanometer diameter single-walled carbon nanotube forests[J], Carbon, 2016, 107: 433-439.
[83]	Betty T. Quinton, Kevin D. Leedy, Jacob W. Lawson, et al., Influence of oxide buffer layers on the growth of carbon nanotube arrays on carbon substrates[J], Carbon, 2015, 87:175-185.
[84]	Takashi Tsuji, Kenji Hata, Don N. Futaba and Shunsuke Sakurai, Unexpected Efficient Synthesis of Millimeter-Scale Single-Wall Carbon Nanotube Forests Using a Sputtered MgO Catalyst Underlayer Enabled by a Simple Treatment Process[J], Journal of The American Chemical Society, 2016.

Cite This Article

Plain Text BibTeX RIS

APA Style

Zhao Jingze, Liu Rongjun, Wang Yanfei, Cao Yingbin. (2018). Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Science Discovery, 6(4), 231-242. https://doi.org/10.11648/j.sd.20180604.12

Copy | Download

ACS Style

Zhao Jingze; Liu Rongjun; Wang Yanfei; Cao Yingbin. Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Sci. Discov. 2018, 6(4), 231-242. doi: 10.11648/j.sd.20180604.12

Copy | Download

AMA Style

Zhao Jingze, Liu Rongjun, Wang Yanfei, Cao Yingbin. Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Sci Discov. 2018;6(4):231-242. doi: 10.11648/j.sd.20180604.12

Copy | Download

@article{10.11648/j.sd.20180604.12,
  author = {Zhao Jingze and Liu Rongjun and Wang Yanfei and Cao Yingbin},
  title = {Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition},
  journal = {Science Discovery},
  volume = {6},
  number = {4},
  pages = {231-242},
  doi = {10.11648/j.sd.20180604.12},
  url = {https://doi.org/10.11648/j.sd.20180604.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180604.12},
  abstract = {Process control of the oriented growth of vertical aligned carbon nanotube arrays and preparation of various ordered structure of carbon nanotube films is the major challenge for practical application. In order to better understand the parameters governing the catalytic properties of the catalytic nanoparticles, this paper summarizes the advances in the catalyst used for vertical aligned carbon nanotube arrays prepared by catalytic chemical vapor deposition, and the process parameters were considered to be able to control the particles size, composition, structure of catalyst. And investigations into the effects of during time, temperature, atmosphere in pre-treatment process, and the transition layer on catalyst morphology evaluation were further found that the catalyst particles size, distribution and density can be transformed through the surface diffusion and inter-layer diffusion influenced by those process.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition
AU  - Zhao Jingze
AU  - Liu Rongjun
AU  - Wang Yanfei
AU  - Cao Yingbin
Y1  - 2018/07/20
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180604.12
DO  - 10.11648/j.sd.20180604.12
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 231
EP  - 242
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180604.12
AB  - Process control of the oriented growth of vertical aligned carbon nanotube arrays and preparation of various ordered structure of carbon nanotube films is the major challenge for practical application. In order to better understand the parameters governing the catalytic properties of the catalytic nanoparticles, this paper summarizes the advances in the catalyst used for vertical aligned carbon nanotube arrays prepared by catalytic chemical vapor deposition, and the process parameters were considered to be able to control the particles size, composition, structure of catalyst. And investigations into the effects of during time, temperature, atmosphere in pre-treatment process, and the transition layer on catalyst morphology evaluation were further found that the catalyst particles size, distribution and density can be transformed through the surface diffusion and inter-layer diffusion influenced by those process.
VL  - 6
IS  - 4
ER  -

Copy | Download

Author Information

Zhao Jingze

College of Aerospace Science an Engineering, Science and Technology on Advanced Ceramic Fiber and Composites Laboratory, National University of Defense Technology, Changsha, China
Liu Rongjun

College of Aerospace Science an Engineering, Science and Technology on Advanced Ceramic Fiber and Composites Laboratory, National University of Defense Technology, Changsha, China
Wang Yanfei

College of Aerospace Science an Engineering, Science and Technology on Advanced Ceramic Fiber and Composites Laboratory, National University of Defense Technology, Changsha, China
Cao Yingbin

College of Aerospace Science an Engineering, Science and Technology on Advanced Ceramic Fiber and Composites Laboratory, National University of Defense Technology, Changsha, China

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Zhao Jingze, Liu Rongjun, Wang Yanfei, Cao Yingbin. (2018). Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Science Discovery, 6(4), 231-242. https://doi.org/10.11648/j.sd.20180604.12

Copy | Download

ACS Style

Zhao Jingze; Liu Rongjun; Wang Yanfei; Cao Yingbin. Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Sci. Discov. 2018, 6(4), 231-242. doi: 10.11648/j.sd.20180604.12

Copy | Download

AMA Style

Zhao Jingze, Liu Rongjun, Wang Yanfei, Cao Yingbin. Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition. Sci Discov. 2018;6(4):231-242. doi: 10.11648/j.sd.20180604.12

Copy | Download

@article{10.11648/j.sd.20180604.12,
  author = {Zhao Jingze and Liu Rongjun and Wang Yanfei and Cao Yingbin},
  title = {Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition},
  journal = {Science Discovery},
  volume = {6},
  number = {4},
  pages = {231-242},
  doi = {10.11648/j.sd.20180604.12},
  url = {https://doi.org/10.11648/j.sd.20180604.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20180604.12},
  abstract = {Process control of the oriented growth of vertical aligned carbon nanotube arrays and preparation of various ordered structure of carbon nanotube films is the major challenge for practical application. In order to better understand the parameters governing the catalytic properties of the catalytic nanoparticles, this paper summarizes the advances in the catalyst used for vertical aligned carbon nanotube arrays prepared by catalytic chemical vapor deposition, and the process parameters were considered to be able to control the particles size, composition, structure of catalyst. And investigations into the effects of during time, temperature, atmosphere in pre-treatment process, and the transition layer on catalyst morphology evaluation were further found that the catalyst particles size, distribution and density can be transformed through the surface diffusion and inter-layer diffusion influenced by those process.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Research on the Catalyst Used for Vertical Aligned Carbon Nanotube Arrays Prepared by Catalytic Chemical Vapor Deposition
AU  - Zhao Jingze
AU  - Liu Rongjun
AU  - Wang Yanfei
AU  - Cao Yingbin
Y1  - 2018/07/20
PY  - 2018
N1  - https://doi.org/10.11648/j.sd.20180604.12
DO  - 10.11648/j.sd.20180604.12
T2  - Science Discovery
JF  - Science Discovery
JO  - Science Discovery
SP  - 231
EP  - 242
PB  - Science Publishing Group
SN  - 2331-0650
UR  - https://doi.org/10.11648/j.sd.20180604.12
AB  - Process control of the oriented growth of vertical aligned carbon nanotube arrays and preparation of various ordered structure of carbon nanotube films is the major challenge for practical application. In order to better understand the parameters governing the catalytic properties of the catalytic nanoparticles, this paper summarizes the advances in the catalyst used for vertical aligned carbon nanotube arrays prepared by catalytic chemical vapor deposition, and the process parameters were considered to be able to control the particles size, composition, structure of catalyst. And investigations into the effects of during time, temperature, atmosphere in pre-treatment process, and the transition layer on catalyst morphology evaluation were further found that the catalyst particles size, distribution and density can be transformed through the surface diffusion and inter-layer diffusion influenced by those process.
VL  - 6
IS  - 4
ER  -

Copy | Download