World Journal of Applied Chemistry

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Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid

Received: 29 August 2019    Accepted: 20 September 2019    Published: 28 October 2019
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Abstract

Natural dyes are derived from natural sources such as plants, animals and minerals. They are mostly non-substantive and can be applied on textiles materials by using mordants. Synthetic dyes are derived from organic or inorganic compound. They are cheaper, offer a vast range of new colour and impart better properties to textile materials. Synthetic dyes are widely used in industries amongst which textile processing industries are the major consumers. Acid dyes are soluble in water and it can be permanently fixed to the fibre with the addition of a weak acid and heat. A series of acid dyes were synthesized by diazotization of 1-amino-2-naphthol-4-sulphonic acid and coupled with various naphthalene derivatives such as 1-nitroso-2-naphthol, 2-nitroso-1-naphthol, 1-naphthol, 2-naphthol and N, N-dimethyl aniline. Visible absorption spectra of the dyes were examined in distilled water, ethanol and ethanol plus few drop of concentrated hydrochloric acid. The FT-IR analysis was determined to confirm the functional group present in the synthesized dye. The dye was applied on polyamide (Nylon) fabric and the colour parameters of dyed fabrics were examined to have good exhaustion between pH 3–4.5 and more intense. After the dyeing process, the fabric was subjected to washing and light fastness. The remarkable degree of levelness and brightness of the synthesized acid dye on the nylon fabric is of good penetration, excellent affinity and very good fastness properties.

DOI 10.11648/j.wjac.20190404.14
Published in World Journal of Applied Chemistry (Volume 4, Issue 4, December 2019)
Page(s) 63-68
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Acid Dyes, FT-IR, UV Visible, Percentage Exhaustion, Fastness Properties

References
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[4] Hofenk, J. H. Graaff. The Colourful Past. Origins, Chemistry and Identification of natural Dyestuffs, London, 2004, 8-10.
[5] Nkeoye, P. O. Introductory Textiles; for Home Economists, Students of Art and Beginners Generally. Ahmadu Bello University Press Ltd, Zaria. 2009, 47-54.
[6] Gregory, P. The Chemistry and Application of Dyes. Plenum Press New-York. 1990, 150-187.
[7] A. K. Samanta, P. Agarwal, Application of natural dyes on textiles, Indian Journal of Fibre and Textile Research, 2009, (34): 384–399.
[8] Keharia, H., Patel, H., Madamwar, D. Decolorization Screening of Synthetic dyes by anaerobic methanogenic Sludge using batch decolourization assay. World Journal of Microbiology Biotechnology, 2004, (20): 365–370.
[9] Raffi F., Hall J. D. and Cerniglia C. E. Mutagenicity of azo dyes used in foods, drugs and cosmetics before and after reduction by Clostridium species from the human intestinal tract. Food and Chemical Toxicology. 1997, (35): 897–901.
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[11] Dixit, B. C., Patel, H. M., Dixit, R. B., Desal, D. J. Synthesis, characterization and dyeing assessment of novel acid azo dyes and mordent acid azo dyes basesd on 2-hydroxy-4-methoxybenzophenone on wool and silk fabrics. Journal of the Serbian Chemical society, 2010, 75 (5): 605–614.
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[19] Bornengo G, Merlo F, Paffoni C. Water-soluble acid azo dye, 1980, US 4187218.
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[21] Ameuru, U. S. Synthesis, Characterization and the Dyeing Properties of Nitrosonaphthol Dyes on Tanned Leathers. Unpublished Thesis, Department of Textile Science and Technology, Ahmadu Bello University, Zaria 2009.
[22] Aspland, J. R., Anionic Dyes and their Application to Ionic Fibre. Dyeing Nylon with Acid Dyes, School of Textiles, Clemson University, South Carolina 1993, 15-20.
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Author Information
  • Department of Polymer and Textile Engineering, Ahmadu Bello University, Zaria, Nigeria

  • Department of Polymer and Textile Engineering, Ahmadu Bello University, Zaria, Nigeria

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    Olawale Olayinka Omotosho, Umar Salami Ameuru. (2019). Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid. World Journal of Applied Chemistry, 4(4), 63-68. https://doi.org/10.11648/j.wjac.20190404.14

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    ACS Style

    Olawale Olayinka Omotosho; Umar Salami Ameuru. Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid. World J. Appl. Chem. 2019, 4(4), 63-68. doi: 10.11648/j.wjac.20190404.14

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    AMA Style

    Olawale Olayinka Omotosho, Umar Salami Ameuru. Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid. World J Appl Chem. 2019;4(4):63-68. doi: 10.11648/j.wjac.20190404.14

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  • @article{10.11648/j.wjac.20190404.14,
      author = {Olawale Olayinka Omotosho and Umar Salami Ameuru},
      title = {Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid},
      journal = {World Journal of Applied Chemistry},
      volume = {4},
      number = {4},
      pages = {63-68},
      doi = {10.11648/j.wjac.20190404.14},
      url = {https://doi.org/10.11648/j.wjac.20190404.14},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.wjac.20190404.14},
      abstract = {Natural dyes are derived from natural sources such as plants, animals and minerals. They are mostly non-substantive and can be applied on textiles materials by using mordants. Synthetic dyes are derived from organic or inorganic compound. They are cheaper, offer a vast range of new colour and impart better properties to textile materials. Synthetic dyes are widely used in industries amongst which textile processing industries are the major consumers. Acid dyes are soluble in water and it can be permanently fixed to the fibre with the addition of a weak acid and heat. A series of acid dyes were synthesized by diazotization of 1-amino-2-naphthol-4-sulphonic acid and coupled with various naphthalene derivatives such as 1-nitroso-2-naphthol, 2-nitroso-1-naphthol, 1-naphthol, 2-naphthol and N, N-dimethyl aniline. Visible absorption spectra of the dyes were examined in distilled water, ethanol and ethanol plus few drop of concentrated hydrochloric acid. The FT-IR analysis was determined to confirm the functional group present in the synthesized dye. The dye was applied on polyamide (Nylon) fabric and the colour parameters of dyed fabrics were examined to have good exhaustion between pH 3–4.5 and more intense. After the dyeing process, the fabric was subjected to washing and light fastness. The remarkable degree of levelness and brightness of the synthesized acid dye on the nylon fabric is of good penetration, excellent affinity and very good fastness properties.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Synthesis and Dyeing Properties of Acid Dyes Derived from 1-amino-2-naphthol-4-sulphonic Acid
    AU  - Olawale Olayinka Omotosho
    AU  - Umar Salami Ameuru
    Y1  - 2019/10/28
    PY  - 2019
    N1  - https://doi.org/10.11648/j.wjac.20190404.14
    DO  - 10.11648/j.wjac.20190404.14
    T2  - World Journal of Applied Chemistry
    JF  - World Journal of Applied Chemistry
    JO  - World Journal of Applied Chemistry
    SP  - 63
    EP  - 68
    PB  - Science Publishing Group
    SN  - 2637-5982
    UR  - https://doi.org/10.11648/j.wjac.20190404.14
    AB  - Natural dyes are derived from natural sources such as plants, animals and minerals. They are mostly non-substantive and can be applied on textiles materials by using mordants. Synthetic dyes are derived from organic or inorganic compound. They are cheaper, offer a vast range of new colour and impart better properties to textile materials. Synthetic dyes are widely used in industries amongst which textile processing industries are the major consumers. Acid dyes are soluble in water and it can be permanently fixed to the fibre with the addition of a weak acid and heat. A series of acid dyes were synthesized by diazotization of 1-amino-2-naphthol-4-sulphonic acid and coupled with various naphthalene derivatives such as 1-nitroso-2-naphthol, 2-nitroso-1-naphthol, 1-naphthol, 2-naphthol and N, N-dimethyl aniline. Visible absorption spectra of the dyes were examined in distilled water, ethanol and ethanol plus few drop of concentrated hydrochloric acid. The FT-IR analysis was determined to confirm the functional group present in the synthesized dye. The dye was applied on polyamide (Nylon) fabric and the colour parameters of dyed fabrics were examined to have good exhaustion between pH 3–4.5 and more intense. After the dyeing process, the fabric was subjected to washing and light fastness. The remarkable degree of levelness and brightness of the synthesized acid dye on the nylon fabric is of good penetration, excellent affinity and very good fastness properties.
    VL  - 4
    IS  - 4
    ER  - 

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