Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint

Eluchie Nene Pearl

doi:doi:10.11648/j.abb.20160406.14

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Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint

Eluchie Nene Pearl

Published in Advances in Bioscience and Bioengineering (Volume 4, Issue 6)

Received: 21 October 2016 Accepted: 12 November 2016 Published: 6 December 2016

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Abstract

The behavior of Palm Kernel Oil was saponified by potassium hydroxide to form soluble soap which was later reacted with solutions of copper, cobalt, Iron and calcium to produce the metal soaps which were used as drier in coating mixture (Paint). The performance of these metal soaps has been studied. The effect of environmental and corrosive factors on paints was also studied. From the study, the formulated paint samples using metal soap had low specific gravity (1.45-1.47). This is an indication that more metal soap can be incorporated into the paint. Full hardness of paint samples was within the range (0.38-0.41mm) which implies that the samples will have high tolerance to anti-corrosive coating. The paints showed strong adhesion properties that are capable to withstand abrasive and corrosive agents. Also when exposed to surfaces like paper and glass, the exhibited strong adaptability without rust. Considering the drying time of coating mixture (paints) containing metal soaps showed increased oxidizing activity of drier and shortened drying time. The progress of the formulated metal soap paint reaction on storage was monitored and confirmed using physical methods. The high performance of the paints prepared from metal soap is good evidence to justify their utilization as driers in the surface coat industry.

Published in	Advances in Bioscience and Bioengineering (Volume 4, Issue 6)
DOI	10.11648/j.abb.20160406.14
Page(s)	85-90
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Palm Kernel Oil, Metal Soap, Saponification, Driers, Synthesis, Metal Soap Paint

References

[1]	R. A. Odemide; I. A. Ajayi; A. Ademuji. Characterization of seed and seed oil of Hura crepitans and kinetics of degradation of the oil during heating, EJAFChe, pp. 201–208, 2009.
[2]	S.B. Elliot. Driers and metallic soaps in Encyclopedia of chemical Technology. 1st ed. Vol. 5. Ferro Chem Corporation. 1979, pp. 195-206.
[3]	M. Gonen, D. Balkose, F. Inal, S. Ulku. Zinc stearate production by precipitation and fusion processes, Ind. Eng. Chem. Res. 14(6):1627–1633, 2005.
[4]	S.K. Upadhyaya, P. S. Sharma. Thermal, Infrared and X-ray diffraction studies on manganese and zinc soaps. Asian J. Chem, 9: 388-39, 1997.
[5]	Akanni, S. M; Okah, E. K; Burrows, H. D; Ellis, H. A. (1992). The valent thermal behavior of divalent and valent metal soaps, a review, Thermochim. Acta. 208: 1–41, 1992.
[6]	E.D. Owe, K.J. Msayib. Catalyzed degradation of poly (vinyl chloride) III Zinc (II) chloride catalysis, J. Polym. Sci. Polym. Chem. A27:399–408, 1989.
[7]	T. O Egbuchunam, P. E. Okieimen, A. I. Aigbodion. Studies in the thermal stability of metal soaps of rubber seed oil, Tech. J. 1: 18–23, 2005.
[8]	T. O Egbuchunam; D. Balkose; F. E. Okieimen. Structure and thermal behavior of polyvalent metal soaps of rubber seed oil, J. Chem. Soc.Nigeria, 32:107–116, 2007.
[9]	K. Biennemans, R. Van Deun, B.Thijs, I. Vanwelkenhuysen, I. Geneus. Structure and mesomorphism of silver alkanoates. Chem. Mater.16:2021–2027, 2004.
[10]	J. Salager. Surfactants: Types and uses. FIRP. http:/www.nanoparticles.org, 2012.
[11]	AOAC, Official Methods of Analysis. Association of Official Analytical Chemist, Arlington, Va, USA, 14th edition, Vol. 67, 1994.
[12]	J. B. Owolabi, K.A. Alabi and L. Lajide. Synthesis and characterization of copper metal soaps from Thevetia Peruviana and Hura Crepitans seeds oil. Academic Journals. Vol. 10 (23) pp. 649-654, 2015.
[13]	P. Ekpa. and U. I. Ibok. Suitable methods for producing Adhesives from Hevea Crumb (Hevea Brazilliensis). Tropical Journal of Applied Science 1 (1). PP. 53-55, 1991.
[14]	C. M. Ewulonu, I. O. Igwe, G. N. Onyeagoro. Performance of local clay titanium dioxide core shell extender pigments in alkyd paints. Advances in Nanoparticles, 2016, 5, 90-102.
[15]	B. M Mildwidsky and D. M Gabriel. Detergent analysis. A handbook for cost effective control. Micelle press, London, 1994, 160-161.
[16]	B. Kozlevčar, N. Lah, S. Makuc, P. Šegedin, and F. Pohleven, “Copper (II) carboxylates—synthesis, structure and biological activity. IV. Fatty acid copper (II) carboxylates with urea,” Acta Chimica Slovenica, vol. 47, no. 4, pp. 421–433, 2000. View at Google Scholar • View at Scopus.
[17]	J. H. IngoldBieleman, Additives for Coatings, Wiley-VCH, Weinheim, Germany, 2000.
[18]	E.K. Ossai. Preparation and characterization of metal soaps of cocos Nucifra seed oil. J. Applied Sci. Environ Manage, Vol. 18 (2) 359-363, 2014.
[19]	IMERYS Saving TiO2 in Semi-Gloss Emulsion Paints with Supreme. IMERYS World Minerals Publication. (2009) www.imerys-perfmins.com.
[20]	Osabor, V. N, Okafor, P. C, Ibe, K. A. and Ayi, A. A. Characterization of Clays in Odukpani, South Eastern, Nigeria. African Journal of Pure and Applied Chemistry, 3, 79-85, 2009.
[21]	Morgans, W. M. Outlines of Paint Technology. Edward Arnold, London, 1990.
[22]	Henton, L. E. Determination of Volume Solids of Paints and Coatings. Engineering Experiment Station, Georgia Institute of Technology, Atlanta, 1981.
[23]	Tiwari, S. and Saxena, M. Use of Fly Ash in High Performance Industrial Coatings. British Corrosion Journal, 34, 184-191, 1999. http://dx.doi.org/10.1179/000705999101500824.
[24]	Nylen, P. and Suderland, E. Modern Surface Coatings. Interscience, London, 1965.
[25]	Payne, H.F. Organic Coating Technology: Volume 1, Oils, Resins, Varnishes, and Polymers. Chapman & Hall, New York, London, 1954.
[26]	Kezaiah, A.C. and Ogbennaya, I.I. Studies on the Use of an Industrial Waste Clay in Alkyd Paint Formulations. International Journal of Academic Research, 4, 306-313, 2012.
[27]	Tan Tian Aik, D. (1995) Durability and TiO2 Pigments. Paint India Annual, 84-93, 1995.

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APA Style

Eluchie Nene Pearl. (2016). Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Advances in Bioscience and Bioengineering, 4(6), 85-90. https://doi.org/10.11648/j.abb.20160406.14

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ACS Style

Eluchie Nene Pearl. Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Adv. BioSci. Bioeng. 2016, 4(6), 85-90. doi: 10.11648/j.abb.20160406.14

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AMA Style

Eluchie Nene Pearl. Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Adv BioSci Bioeng. 2016;4(6):85-90. doi: 10.11648/j.abb.20160406.14

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@article{10.11648/j.abb.20160406.14,
  author = {Eluchie Nene Pearl},
  title = {Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint},
  journal = {Advances in Bioscience and Bioengineering},
  volume = {4},
  number = {6},
  pages = {85-90},
  doi = {10.11648/j.abb.20160406.14},
  url = {https://doi.org/10.11648/j.abb.20160406.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.abb.20160406.14},
  abstract = {The behavior of Palm Kernel Oil was saponified by potassium hydroxide to form soluble soap which was later reacted with solutions of copper, cobalt, Iron and calcium to produce the metal soaps which were used as drier in coating mixture (Paint). The performance of these metal soaps has been studied. The effect of environmental and corrosive factors on paints was also studied. From the study, the formulated paint samples using metal soap had low specific gravity (1.45-1.47). This is an indication that more metal soap can be incorporated into the paint. Full hardness of paint samples was within the range (0.38-0.41mm) which implies that the samples will have high tolerance to anti-corrosive coating. The paints showed strong adhesion properties that are capable to withstand abrasive and corrosive agents. Also when exposed to surfaces like paper and glass, the exhibited strong adaptability without rust. Considering the drying time of coating mixture (paints) containing metal soaps showed increased oxidizing activity of drier and shortened drying time. The progress of the formulated metal soap paint reaction on storage was monitored and confirmed using physical methods. The high performance of the paints prepared from metal soap is good evidence to justify their utilization as driers in the surface coat industry.},
 year = {2016}
}

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TY - JOUR
T1 - Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint
AU - Eluchie Nene Pearl
Y1 - 2016/12/06
PY - 2016
N1 - https://doi.org/10.11648/j.abb.20160406.14
DO - 10.11648/j.abb.20160406.14
T2 - Advances in Bioscience and Bioengineering
JF - Advances in Bioscience and Bioengineering
JO - Advances in Bioscience and Bioengineering
SP - 85
EP - 90
PB - Science Publishing Group
SN - 2330-4162
UR - https://doi.org/10.11648/j.abb.20160406.14
AB - The behavior of Palm Kernel Oil was saponified by potassium hydroxide to form soluble soap which was later reacted with solutions of copper, cobalt, Iron and calcium to produce the metal soaps which were used as drier in coating mixture (Paint). The performance of these metal soaps has been studied. The effect of environmental and corrosive factors on paints was also studied. From the study, the formulated paint samples using metal soap had low specific gravity (1.45-1.47). This is an indication that more metal soap can be incorporated into the paint. Full hardness of paint samples was within the range (0.38-0.41mm) which implies that the samples will have high tolerance to anti-corrosive coating. The paints showed strong adhesion properties that are capable to withstand abrasive and corrosive agents. Also when exposed to surfaces like paper and glass, the exhibited strong adaptability without rust. Considering the drying time of coating mixture (paints) containing metal soaps showed increased oxidizing activity of drier and shortened drying time. The progress of the formulated metal soap paint reaction on storage was monitored and confirmed using physical methods. The high performance of the paints prepared from metal soap is good evidence to justify their utilization as driers in the surface coat industry.
VL - 4
IS - 6
ER -

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Eluchie Nene Pearl

Biotechnology and Energy Research, Ministry of Science and Technology, Umuahia, Nigeria

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APA Style

Eluchie Nene Pearl. (2016). Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Advances in Bioscience and Bioengineering, 4(6), 85-90. https://doi.org/10.11648/j.abb.20160406.14

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ACS Style

Eluchie Nene Pearl. Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Adv. BioSci. Bioeng. 2016, 4(6), 85-90. doi: 10.11648/j.abb.20160406.14

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AMA Style

Eluchie Nene Pearl. Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint. Adv BioSci Bioeng. 2016;4(6):85-90. doi: 10.11648/j.abb.20160406.14

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@article{10.11648/j.abb.20160406.14,
  author = {Eluchie Nene Pearl},
  title = {Synthesis, Characterization and Permofarmance Activity of Metal Soap of Calcium, Cobalt, Iron and Copper from Palm Kernel Oil as a Drier in Paint},
  journal = {Advances in Bioscience and Bioengineering},
  volume = {4},
  number = {6},
  pages = {85-90},
  doi = {10.11648/j.abb.20160406.14},
  url = {https://doi.org/10.11648/j.abb.20160406.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.abb.20160406.14},
  abstract = {The behavior of Palm Kernel Oil was saponified by potassium hydroxide to form soluble soap which was later reacted with solutions of copper, cobalt, Iron and calcium to produce the metal soaps which were used as drier in coating mixture (Paint). The performance of these metal soaps has been studied. The effect of environmental and corrosive factors on paints was also studied. From the study, the formulated paint samples using metal soap had low specific gravity (1.45-1.47). This is an indication that more metal soap can be incorporated into the paint. Full hardness of paint samples was within the range (0.38-0.41mm) which implies that the samples will have high tolerance to anti-corrosive coating. The paints showed strong adhesion properties that are capable to withstand abrasive and corrosive agents. Also when exposed to surfaces like paper and glass, the exhibited strong adaptability without rust. Considering the drying time of coating mixture (paints) containing metal soaps showed increased oxidizing activity of drier and shortened drying time. The progress of the formulated metal soap paint reaction on storage was monitored and confirmed using physical methods. The high performance of the paints prepared from metal soap is good evidence to justify their utilization as driers in the surface coat industry.},
 year = {2016}
}

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