Science Journal of Analytical Chemistry

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Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates

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Abstract

Complexes of the type [Au(L)(L-orL=)]Cl were prepared [L= deprotonated glycine (Gly), Alanine (Ala), Valine(Val) or Methionine (Met), L- = N-Methylcyclohexyldithiocarbamate(N-MeCHdtc) or Benzyldithiocarbamate(Bzdtc) anion and L= =0,0-Dipropyldithiophosphate (DiPrdtp) or 0,0- Dibenzyldithiophosphate (DiBzdtp) anion. The prepared complexes were characterized by elemental analysis, molar conductivity, IR and UV-Vis spetra, magnatic susceptibility and (1H-nmr) for some of the complexes. The gold(III) complexes were all square planar with the dithiocarbamates or dithiophosphates acted as bidentate ligands coordinated through the two sulfur atoms and the aminoacid anions coordinated through N and O except for the methionine ligand which coordinate through S and N atoms.

DOI 10.11648/j.sjac.20130102.13
Published in Science Journal of Analytical Chemistry (Volume 1, Issue 2, November 2013)
Page(s) 21-27
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Amino Acid Complex, Dithiocarbamates, Dithiophosphates

References
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Author Information
  • Department of Chemistry , College of science University of Mosul, Mosul, Iraq.

  • Department of Chemistry , College of science University of Mosul, Mosul, Iraq.

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    Mikkat Zaghlool Hamdi., Ihsan Abdulghani Mustafa. (). Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates. Science Journal of Analytical Chemistry, 1(2), 21-27. https://doi.org/10.11648/j.sjac.20130102.13

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    Mikkat Zaghlool Hamdi.; Ihsan Abdulghani Mustafa. Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates. Sci. J. Anal. Chem. , 1(2), 21-27. doi: 10.11648/j.sjac.20130102.13

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    Mikkat Zaghlool Hamdi., Ihsan Abdulghani Mustafa. Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates. Sci J Anal Chem. ;1(2):21-27. doi: 10.11648/j.sjac.20130102.13

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  • @article{10.11648/j.sjac.20130102.13,
      author = {Mikkat Zaghlool Hamdi. and Ihsan Abdulghani Mustafa},
      title = {Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates},
      journal = {Science Journal of Analytical Chemistry},
      volume = {1},
      number = {2},
      pages = {21-27},
      doi = {10.11648/j.sjac.20130102.13},
      url = {https://doi.org/10.11648/j.sjac.20130102.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjac.20130102.13},
      abstract = {Complexes of the type [Au(L)(L-orL=)]Cl were prepared [L= deprotonated glycine (Gly), Alanine (Ala), Valine(Val) or Methionine (Met), L- = N-Methylcyclohexyldithiocarbamate(N-MeCHdtc) or Benzyldithiocarbamate(Bzdtc) anion and L= =0,0-Dipropyldithiophosphate (DiPrdtp) or 0,0- Dibenzyldithiophosphate (DiBzdtp) anion. The prepared complexes were characterized by elemental analysis, molar conductivity, IR and UV-Vis spetra, magnatic susceptibility and (1H-nmr) for some of the complexes. The gold(III) complexes were all square planar with the dithiocarbamates or dithiophosphates acted as bidentate ligands coordinated through the two sulfur atoms and the aminoacid anions coordinated through N and O except for the methionine ligand which coordinate through S and N atoms.},
     year = {}
    }
    

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    T1  - Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates
    AU  - Mikkat Zaghlool Hamdi.
    AU  - Ihsan Abdulghani Mustafa
    Y1  - 
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    N1  - https://doi.org/10.11648/j.sjac.20130102.13
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    T2  - Science Journal of Analytical Chemistry
    JF  - Science Journal of Analytical Chemistry
    JO  - Science Journal of Analytical Chemistry
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    PB  - Science Publishing Group
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    AB  - Complexes of the type [Au(L)(L-orL=)]Cl were prepared [L= deprotonated glycine (Gly), Alanine (Ala), Valine(Val) or Methionine (Met), L- = N-Methylcyclohexyldithiocarbamate(N-MeCHdtc) or Benzyldithiocarbamate(Bzdtc) anion and L= =0,0-Dipropyldithiophosphate (DiPrdtp) or 0,0- Dibenzyldithiophosphate (DiBzdtp) anion. The prepared complexes were characterized by elemental analysis, molar conductivity, IR and UV-Vis spetra, magnatic susceptibility and (1H-nmr) for some of the complexes. The gold(III) complexes were all square planar with the dithiocarbamates or dithiophosphates acted as bidentate ligands coordinated through the two sulfur atoms and the aminoacid anions coordinated through N and O except for the methionine ligand which coordinate through S and N atoms.
    VL  - 1
    IS  - 2
    ER  - 

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