Science Journal of Analytical Chemistry

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Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms

Received: 26 September 2015    Accepted: 13 October 2015    Published: 27 October 2015
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Abstract

In the last three decades attention has been paid on environmental management caused by toxic materials such as heavy metals whose levels have risen due to increased anthropogenic activities. Conventional methods for waste treatment are numerous, some of which are expensive and sometimes inefficient. A search for cheaper and environmentally friendly method of treatment using natural products has taken a central stage in the recent past. Moringa oleifera seed powder was investigated with a view of using it as a low cost biosorbent for the removal of toxic heavy metals from wastewater. Fourier transform Infrared (FT-IR) analysis was done for characterization of Moringa oleifera seeds powder. Batch biosorption experiments of Pb2+ and Cr2+ with respect to contact time, pH, particle size, adsorbent dosage, effect of pretreatment and adsorption isotherms were studied. FT-IR showed the presence of –NH, -OH, -COOH functional groups in the biomass. The maximum biosorption capacity was observed at pH 5 for both metals, with the particle size of adsorbent of 0.250 mm and high adsorbent dosage of 0.6 g. The order of modification for Pb2+ was CaCl2 > NaOH > KMnO4 > HCl, while that of Cr2+ was KMnO4 > CaCl2 > HCl > NaOH. Although the data fitted into both the Langmuir and Freundlich adsorption isotherms high correlation coefficients of about 1.00, the Langmuir gave better results than the Freundlich. The results suggest that Moringa oleifera seeds have potential application in Pb2+ and Cr2+ decontamination from aqueous effluents and that pretreatment further enhances biosorption.

DOI 10.11648/j.sjac.20150306.14
Published in Science Journal of Analytical Chemistry (Volume 3, Issue 6, November 2015)
Page(s) 100-108
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Biosorption, Pollution, Langmuir, Freundlich, Moringa, Batch

References
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Author Information
  • Department of Pure and Applied Chemistry, Masinde Muliro University of Science and Technology, Kakamega, Kenya; Department of Chemistry and Biochemistry, University of Eldoret, Eldoret, Kenya

  • Department of Chemistry and Biochemistry, University of Eldoret, Eldoret, Kenya

  • Department of Physical Sciences, Chuka University, Chuka, Kenya

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    Ongulu Roselyn Adhiambo, Kituyi John Lusweti, Getenga Zachary Morang’a. (2015). Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms. Science Journal of Analytical Chemistry, 3(6), 100-108. https://doi.org/10.11648/j.sjac.20150306.14

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    Ongulu Roselyn Adhiambo; Kituyi John Lusweti; Getenga Zachary Morang’a. Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms. Sci. J. Anal. Chem. 2015, 3(6), 100-108. doi: 10.11648/j.sjac.20150306.14

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    AMA Style

    Ongulu Roselyn Adhiambo, Kituyi John Lusweti, Getenga Zachary Morang’a. Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms. Sci J Anal Chem. 2015;3(6):100-108. doi: 10.11648/j.sjac.20150306.14

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  • @article{10.11648/j.sjac.20150306.14,
      author = {Ongulu Roselyn Adhiambo and Kituyi John Lusweti and Getenga Zachary Morang’a},
      title = {Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms},
      journal = {Science Journal of Analytical Chemistry},
      volume = {3},
      number = {6},
      pages = {100-108},
      doi = {10.11648/j.sjac.20150306.14},
      url = {https://doi.org/10.11648/j.sjac.20150306.14},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjac.20150306.14},
      abstract = {In the last three decades attention has been paid on environmental management caused by toxic materials such as heavy metals whose levels have risen due to increased anthropogenic activities. Conventional methods for waste treatment are numerous, some of which are expensive and sometimes inefficient. A search for cheaper and environmentally friendly method of treatment using natural products has taken a central stage in the recent past. Moringa oleifera seed powder was investigated with a view of using it as a low cost biosorbent for the removal of toxic heavy metals from wastewater. Fourier transform Infrared (FT-IR) analysis was done for characterization of Moringa oleifera seeds powder. Batch biosorption experiments of Pb2+ and Cr2+ with respect to contact time, pH, particle size, adsorbent dosage, effect of pretreatment and adsorption isotherms were studied. FT-IR showed the presence of –NH, -OH, -COOH functional groups in the biomass. The maximum biosorption capacity was observed at pH 5 for both metals, with the particle size of adsorbent of 0.250 mm and high adsorbent dosage of 0.6 g. The order of modification for Pb2+ was CaCl2 > NaOH > KMnO4 > HCl, while that of Cr2+ was KMnO4 > CaCl2 > HCl > NaOH. Although the data fitted into both the Langmuir and Freundlich adsorption isotherms high correlation coefficients of about 1.00, the Langmuir gave better results than the Freundlich. The results suggest that Moringa oleifera seeds have potential application in Pb2+ and Cr2+ decontamination from aqueous effluents and that pretreatment further enhances biosorption.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Biosorption of Pb2+ and Cr2+ Using Moringa Oleifera and Their Adsorption Isotherms
    AU  - Ongulu Roselyn Adhiambo
    AU  - Kituyi John Lusweti
    AU  - Getenga Zachary Morang’a
    Y1  - 2015/10/27
    PY  - 2015
    N1  - https://doi.org/10.11648/j.sjac.20150306.14
    DO  - 10.11648/j.sjac.20150306.14
    T2  - Science Journal of Analytical Chemistry
    JF  - Science Journal of Analytical Chemistry
    JO  - Science Journal of Analytical Chemistry
    SP  - 100
    EP  - 108
    PB  - Science Publishing Group
    SN  - 2376-8053
    UR  - https://doi.org/10.11648/j.sjac.20150306.14
    AB  - In the last three decades attention has been paid on environmental management caused by toxic materials such as heavy metals whose levels have risen due to increased anthropogenic activities. Conventional methods for waste treatment are numerous, some of which are expensive and sometimes inefficient. A search for cheaper and environmentally friendly method of treatment using natural products has taken a central stage in the recent past. Moringa oleifera seed powder was investigated with a view of using it as a low cost biosorbent for the removal of toxic heavy metals from wastewater. Fourier transform Infrared (FT-IR) analysis was done for characterization of Moringa oleifera seeds powder. Batch biosorption experiments of Pb2+ and Cr2+ with respect to contact time, pH, particle size, adsorbent dosage, effect of pretreatment and adsorption isotherms were studied. FT-IR showed the presence of –NH, -OH, -COOH functional groups in the biomass. The maximum biosorption capacity was observed at pH 5 for both metals, with the particle size of adsorbent of 0.250 mm and high adsorbent dosage of 0.6 g. The order of modification for Pb2+ was CaCl2 > NaOH > KMnO4 > HCl, while that of Cr2+ was KMnO4 > CaCl2 > HCl > NaOH. Although the data fitted into both the Langmuir and Freundlich adsorption isotherms high correlation coefficients of about 1.00, the Langmuir gave better results than the Freundlich. The results suggest that Moringa oleifera seeds have potential application in Pb2+ and Cr2+ decontamination from aqueous effluents and that pretreatment further enhances biosorption.
    VL  - 3
    IS  - 6
    ER  - 

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