American Journal of Chemical Engineering

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Effect of Surface Active Pollutants on the Rate of Mass Transfer Controlled Corrosion of Reactors Used in Wastewater Treatment

Received: 22 July 2016    Accepted: 02 August 2016    Published: 09 September 2016
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Abstract

The diffusion controlled corrosion of a cooling system composed of an array of vertical tubes attached to the inner wall of a fixed bed reactor containing plastic Raschig rings was studied by a rapid technique which involves the diffusion controlled dissolution of copper in acidified dichromate. Variables studied were solution velocity, Raschig rings diameter, vertical tube height and the presence of surface active agent. The present data were correlated by a dimensionless equation. The presence of surface active agents decreased the rate of mass transfer by an amount ranging from 7.5 to 36.2 depending on the operating conditions. Implications of the present results for the design and operation of built-in cooling systems of fixed bed reactors was highlighted. Also the possible use of the obtained equation in calculating the rate of heat transfer by analogy was discussed.

DOI 10.11648/j.ajche.20160405.11
Published in American Journal of Chemical Engineering (Volume 4, Issue 5, September 2016)
Page(s) 92-97
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Mass Transfer, Heat Transfer, Fixed Bed, Diffusion Controlled Corrosion, Exothermic Reactions, Catalytic Reactors, Heat Exchanger

References
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[10] M. H. Abdel-Aziz, M. Bassyouni, I. A. S. Mansour, A. Nagi, Wall to liquid mass transport, J IND ENG CHEM. vol. 20, 2014, Issue 5, pp. 2650-2656.
[11] G. H. Sedahmed, The use of drag reducing polymers to combat diffusion controlled corrosion and erosion–corrosion in equipments operated under turbulent flow, Trends Chem. Eng., vol. 9, 2005, pp. 65-72.
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[15] G. Delaunay, A. Storck, A. Laurent, J. C. Charpentler, Electrochemical study of liquid-solid mass transfer in packed beds with upward cocurrent gas–liquid flow, Ind. Eng. Chem. Proc. Des. Dev, vol. 19, 1980, pp. 514–521.
[16] A. I. Vogel, Text Book of Quantitative Analysis, Longman, London, 1989.
[17] A. Findlay, J. K. Ketchener, Practical Physical Chemistry, Longmans, London, 1965.
[18] E. L. Cussler, diffusion Mass transfer in fluid systems, Cambridge university press, Cambridge, 1988.
[19] F. Walsh, A First Course in Electrochemical Engineering, The Electrochemical Consultancy, Hants, United Kingdom, 1993.
[20] D. J. Pickett, Electrochemical Reactor Design, Elsevier, New York, 1977.
[21] A. Ahmed, G. H. Sedahmed, Effects of surfactants on the rate of Mass transfer at gas evolving electrodes, J. Appl. Electrochem, vol. 19, 1989, pp. 219-224.
[22] A. A. MOBARAK, M. S. E. ABDO, M. S. M. HASSAN, G. H. SEDAHMED, Mass transfer behavior of a flow -by fixed bed electrochemical reactor composed of a vertical stack of screens under single and upward two phase flow, J. Appl. Electrochem. vol. 30, 2000, pp. 1269-1276.
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Author Information
  • Chemical Engineering Department, Faculty of Engineering, Alexandria University, Alexandria, Egypt

  • Chemical Engineering Department, Faculty of Engineering, Alexandria University, Alexandria, Egypt

  • Chemical Engineering Department, Faculty of Engineering, Alexandria University, Alexandria, Egypt

  • Fabrication Technology Department, Advanced Technology and New Materials Research Institute, Alexandria, Egypt

  • Chemical Engineering Department, Faculty of Engineering, Alexandria University, Alexandria, Egypt

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  • APA Style

    Eman Radi Sadik, Taghreed Zewail, Abd El-Aziz Konsowa, Mona Abd El-Latif, Gomma Sedahmed. (2016). Effect of Surface Active Pollutants on the Rate of Mass Transfer Controlled Corrosion of Reactors Used in Wastewater Treatment. American Journal of Chemical Engineering, 4(5), 92-97. https://doi.org/10.11648/j.ajche.20160405.11

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    ACS Style

    Eman Radi Sadik; Taghreed Zewail; Abd El-Aziz Konsowa; Mona Abd El-Latif; Gomma Sedahmed. Effect of Surface Active Pollutants on the Rate of Mass Transfer Controlled Corrosion of Reactors Used in Wastewater Treatment. Am. J. Chem. Eng. 2016, 4(5), 92-97. doi: 10.11648/j.ajche.20160405.11

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    AMA Style

    Eman Radi Sadik, Taghreed Zewail, Abd El-Aziz Konsowa, Mona Abd El-Latif, Gomma Sedahmed. Effect of Surface Active Pollutants on the Rate of Mass Transfer Controlled Corrosion of Reactors Used in Wastewater Treatment. Am J Chem Eng. 2016;4(5):92-97. doi: 10.11648/j.ajche.20160405.11

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  • @article{10.11648/j.ajche.20160405.11,
      author = {Eman Radi Sadik and Taghreed Zewail and Abd El-Aziz Konsowa and Mona Abd El-Latif and Gomma Sedahmed},
      title = {Effect of Surface Active Pollutants on the Rate of Mass Transfer Controlled Corrosion of Reactors Used in Wastewater Treatment},
      journal = {American Journal of Chemical Engineering},
      volume = {4},
      number = {5},
      pages = {92-97},
      doi = {10.11648/j.ajche.20160405.11},
      url = {https://doi.org/10.11648/j.ajche.20160405.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajche.20160405.11},
      abstract = {The diffusion controlled corrosion of a cooling system composed of an array of vertical tubes attached to the inner wall of a fixed bed reactor containing plastic Raschig rings was studied by a rapid technique which involves the diffusion controlled dissolution of copper in acidified dichromate. Variables studied were solution velocity, Raschig rings diameter, vertical tube height and the presence of surface active agent. The present data were correlated by a dimensionless equation. The presence of surface active agents decreased the rate of mass transfer by an amount ranging from 7.5 to 36.2 depending on the operating conditions. Implications of the present results for the design and operation of built-in cooling systems of fixed bed reactors was highlighted. Also the possible use of the obtained equation in calculating the rate of heat transfer by analogy was discussed.},
     year = {2016}
    }
    

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    AU  - Eman Radi Sadik
    AU  - Taghreed Zewail
    AU  - Abd El-Aziz Konsowa
    AU  - Mona Abd El-Latif
    AU  - Gomma Sedahmed
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    DO  - 10.11648/j.ajche.20160405.11
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 92
    EP  - 97
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.20160405.11
    AB  - The diffusion controlled corrosion of a cooling system composed of an array of vertical tubes attached to the inner wall of a fixed bed reactor containing plastic Raschig rings was studied by a rapid technique which involves the diffusion controlled dissolution of copper in acidified dichromate. Variables studied were solution velocity, Raschig rings diameter, vertical tube height and the presence of surface active agent. The present data were correlated by a dimensionless equation. The presence of surface active agents decreased the rate of mass transfer by an amount ranging from 7.5 to 36.2 depending on the operating conditions. Implications of the present results for the design and operation of built-in cooling systems of fixed bed reactors was highlighted. Also the possible use of the obtained equation in calculating the rate of heat transfer by analogy was discussed.
    VL  - 4
    IS  - 5
    ER  - 

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