Electrodeposited coatings of chromium and diamond nanoparticles on steel were obtained. The chromium is plated directly on the steel matrix without any intermediate layers. The influence of the electrodeposition current density, the electrodeposition time and the concentration of diamond nanoparticles in the chromium-plating electrolyte on the microstructure, the phase composition, the microhardness and the corrosion resistance of the chromium coatings were investigated. The phase and chemical compositions of the composite coating (chromium and diamond nanoparticles) were examined using X-ray Diffraction (XRD) and Scanning Electron Microscopy - Energy-Dispersive X-ray Spectroscopy (SEM-EDS) techniques. The microstructure and microhardness were examined with a metallographic microscope and a microhardness tester. The corrosion resistance was investigated in 3.5 wt % NaCl solution using the gravimetric method. The bond between the chromium coating and the steel matrix has diffusion character. A sublayer of separate irregular shape formations appears at concentration of diamond nanoparticles 25 g/l and more. The formation of these structures depends only on the concentration of diamond nanoparticles and is not influenced by the other electrodeposition parameters. With the increase of the concentration of diamond nanoparticles in the electrolyte the rate of chromium coating deposition increases and respectively the thickness of the coating increases also. This increase is more than twice the thickness of chromium coating without nanodiamonds. The microhardness of the composite coatings rises also compared to unmodified chromium coating. With the increase of the concentration of the diamond nanoparticles 2 times greater microhardness is achieved and up to 5 times greater corrosion resistance compared to monochromium coating. The values of the other electroplating parameters are constant.
| Published in | American Journal of Chemical Engineering (Volume 8, Issue 6) |
| DOI | 10.11648/j.ajche.20200806.11 |
| Page(s) | 125-130 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Diamond Nanoparticles, Chromium Coating, Electrodeposition, Hardness, Corrosion
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APA Style
Vladimir Petkov, Radoslav Valov. (2020). Effects of Diamond Nanoparticles on the Microstructure, Hardness and Corrosion Resistance of Chromium Coatings. American Journal of Chemical Engineering, 8(6), 125-130. https://doi.org/10.11648/j.ajche.20200806.11
ACS Style
Vladimir Petkov; Radoslav Valov. Effects of Diamond Nanoparticles on the Microstructure, Hardness and Corrosion Resistance of Chromium Coatings. Am. J. Chem. Eng. 2020, 8(6), 125-130. doi: 10.11648/j.ajche.20200806.11
AMA Style
Vladimir Petkov, Radoslav Valov. Effects of Diamond Nanoparticles on the Microstructure, Hardness and Corrosion Resistance of Chromium Coatings. Am J Chem Eng. 2020;8(6):125-130. doi: 10.11648/j.ajche.20200806.11
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Download@article{10.11648/j.ajche.20200806.11,
author = {Vladimir Petkov and Radoslav Valov},
title = {Effects of Diamond Nanoparticles on the Microstructure, Hardness and Corrosion Resistance of Chromium Coatings},
journal = {American Journal of Chemical Engineering},
volume = {8},
number = {6},
pages = {125-130},
doi = {10.11648/j.ajche.20200806.11},
url = {https://doi.org/10.11648/j.ajche.20200806.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20200806.11},
abstract = {Electrodeposited coatings of chromium and diamond nanoparticles on steel were obtained. The chromium is plated directly on the steel matrix without any intermediate layers. The influence of the electrodeposition current density, the electrodeposition time and the concentration of diamond nanoparticles in the chromium-plating electrolyte on the microstructure, the phase composition, the microhardness and the corrosion resistance of the chromium coatings were investigated. The phase and chemical compositions of the composite coating (chromium and diamond nanoparticles) were examined using X-ray Diffraction (XRD) and Scanning Electron Microscopy - Energy-Dispersive X-ray Spectroscopy (SEM-EDS) techniques. The microstructure and microhardness were examined with a metallographic microscope and a microhardness tester. The corrosion resistance was investigated in 3.5 wt % NaCl solution using the gravimetric method. The bond between the chromium coating and the steel matrix has diffusion character. A sublayer of separate irregular shape formations appears at concentration of diamond nanoparticles 25 g/l and more. The formation of these structures depends only on the concentration of diamond nanoparticles and is not influenced by the other electrodeposition parameters. With the increase of the concentration of diamond nanoparticles in the electrolyte the rate of chromium coating deposition increases and respectively the thickness of the coating increases also. This increase is more than twice the thickness of chromium coating without nanodiamonds. The microhardness of the composite coatings rises also compared to unmodified chromium coating. With the increase of the concentration of the diamond nanoparticles 2 times greater microhardness is achieved and up to 5 times greater corrosion resistance compared to monochromium coating. The values of the other electroplating parameters are constant.},
year = {2020}
}
TY - JOUR T1 - Effects of Diamond Nanoparticles on the Microstructure, Hardness and Corrosion Resistance of Chromium Coatings AU - Vladimir Petkov AU - Radoslav Valov Y1 - 2020/11/27 PY - 2020 N1 - https://doi.org/10.11648/j.ajche.20200806.11 DO - 10.11648/j.ajche.20200806.11 T2 - American Journal of Chemical Engineering JF - American Journal of Chemical Engineering JO - American Journal of Chemical Engineering SP - 125 EP - 130 PB - Science Publishing Group SN - 2330-8613 UR - https://doi.org/10.11648/j.ajche.20200806.11 AB - Electrodeposited coatings of chromium and diamond nanoparticles on steel were obtained. The chromium is plated directly on the steel matrix without any intermediate layers. The influence of the electrodeposition current density, the electrodeposition time and the concentration of diamond nanoparticles in the chromium-plating electrolyte on the microstructure, the phase composition, the microhardness and the corrosion resistance of the chromium coatings were investigated. The phase and chemical compositions of the composite coating (chromium and diamond nanoparticles) were examined using X-ray Diffraction (XRD) and Scanning Electron Microscopy - Energy-Dispersive X-ray Spectroscopy (SEM-EDS) techniques. The microstructure and microhardness were examined with a metallographic microscope and a microhardness tester. The corrosion resistance was investigated in 3.5 wt % NaCl solution using the gravimetric method. The bond between the chromium coating and the steel matrix has diffusion character. A sublayer of separate irregular shape formations appears at concentration of diamond nanoparticles 25 g/l and more. The formation of these structures depends only on the concentration of diamond nanoparticles and is not influenced by the other electrodeposition parameters. With the increase of the concentration of diamond nanoparticles in the electrolyte the rate of chromium coating deposition increases and respectively the thickness of the coating increases also. This increase is more than twice the thickness of chromium coating without nanodiamonds. The microhardness of the composite coatings rises also compared to unmodified chromium coating. With the increase of the concentration of the diamond nanoparticles 2 times greater microhardness is achieved and up to 5 times greater corrosion resistance compared to monochromium coating. The values of the other electroplating parameters are constant. VL - 8 IS - 6 ER -
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