Palladium(II)-Catalyzed Oxidation of Pyrimidine Derivative by Hexacyanoferrate(III) in Aqueous Alkaline Medium: A Kinetic Study
American Journal of Chemical Engineering
Volume 4, Issue 2, March 2016, Pages: 38-45
Received: Mar. 10, 2016;
Accepted: Mar. 18, 2016;
Published: Mar. 31, 2016
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Ahmed Fawzy, Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah, Saudi Arabia; Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt
Ishaq Zaafarany, Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah, Saudi Arabia
Fahd Turkistani, Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah, Saudi Arabia
Jabir Alfahemi, Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah, Saudi Arabia
Moataz Morad, Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makkah, Saudi Arabia
Palladium(II)-Catalyzed Oxidation of Pyrimidine Derivative by Hexacyanoferrate(III) in Aqueous Alkaline Medium: A Kinetic Study, American Journal of Chemical Engineering.
Vol. 4, No. 2,
2016, pp. 38-45.
Joule, John A.; Mills, Keith, eds. (2010). Heterocyclic Chemistry (5th ed.). Oxford: Wiley. p. 250.
Nuevo M, Milam SN, Sandford SA, Elsila JE, Dworkin JP (2009) Formation of uracil from the ultraviolet photo-irradiation of pyrimidine in pure H2O ices. Astrobiology 9: 683–695.
Leung VSK, Chan TYK, Yeung VTF (1999) Ami-traz poisining in humans, Clinical Toxicol. 37: 513-514.
Nakayama A, Sukekawa M, Eguchi Y (1997) Stereo-chemistry and active conformation of a novel insecticide Acetamiprid. Pesticide Sci. 51: 157-164.
Beeman RW, Matsumura F (1973) Chlordimeform: a pesticide acting upon amine regulatory mechanisms. Nature 242: 273-274.
Aziz AA, Knowles CO (1973) Inhibition of monoamine oxidase by the pesticides chlordimeform and related compounds. Nature 242: 417-418.
Fawzy A. (2016) Kinetics and mechanism of uncatalyzed and ruthenium(III)-catalyzed oxidation of formamidine derivative by hexacyanoferrate(III) in aqueous alkaline medium. J. Chem. Sci. In press.
Fawzy A, Zaafarany IA, Yarkandi N, Al-Bonayan A, Almallah Z (2016) Kinetic and mechanism of oxidation of methylaminopyrazole formamidine by alkaline hexacyanoferrate(III) and the effect of divalent transition metal ions. Sci. J. Chem.1:1-8.
Padhye S, Kaufman GB (1985) Transition metal complexes of semicarbazones and thiosemicarbazones. Coord. Chem. Rev. 63: 127-160.
Asiri AM, Khan SA (2010) Palladium(II) complexes of NS donor ligands derived from steroidal thiosemicarbazones as antibacterial agents. Molecules 15: 4784-4791.
Fawzy A (2015) Kinetics and mechanistic approach to the oxidative behavior of biological anticancer platinum(IV) complex towards L-asparagine in acid medium and the effect of copper(II) catalyst. Int. J. Chem. Kinet. 47: 1-12.
Fawzy A, Zaafarany IA (2015) Mechanistic investigation of copper(II)-catalyzed oxidation of L-asparagine by hexachloroplatinate(IV) in aqueous alkaline medium: a kinetic approach.J. Multidisc. Eng. Sci. Technol. 2: 1038-1045.
Asghar BH, Altass HM, Fawzy A (2016) Silver(I)-catalysis of oxidative deamination and decarboxylation of L-asparagine and L-histidine by platinum(IV) in perchloricacid solutions: acomparative kinetics study. J. Env. Chem. Eng. 4: 617-623.
Asghar BH, Altass HM, Fawzy A (2015) Transition metal ions-catalyzed oxidation of L-asparagine by platinum(IV) in acid medium: a kinetic and mechanistic study. Transition Met. Chem. 40: 587–594.
Kelson EP, Phengsy PP (2000) Kinetic study of 2-propanol and benzyl alcohol oxidation by alkaline hexacyanoferrate(III) catalysed by a terpyridyl ruthenium complex. Int. J. Chem. Kinet. 32: 760–770.
Vovk AI, Muraveva IV, Kukhar VP, Baklan VF (2000) Kinetics of oxidation of vitamin B1 and its Oacyl analogs with ferricyanide. A mechanistic model of thiamin-binding protein. Russ. J. Gen. Chem. 70: 1108–1112.
Speakman PT, Waters WA (1955) Kinetic features of the oxidation of aldehydes, ketones and nitroparaffins with alkaline ferricyanide. J. Chem. Soc. 40–50.
Jose TP, Nandibewoor ST, Tuwar SM (2006) Kinetics and mechanism of oxidation of vanillin by hexacyanoferrate(III) in aqueous alkaline medium. J. Solution Chem. 35: 51–62.
Singh VN, Singh MP, Saxena BBL (1970) Kinetics and mechanism of alkaline ferricyanide oxidation of acetone and ethyl methyl ketone. Indian J. Chem. 8: 529–532.
Leal JM, Garcia B, Domingo PL (1998) Outer-sphere hexacyanoferrate(III) oxidation of organic substrates. Coord. Chem. Rev. 173: 79–131.
Jose TP, Angadi MA, Salunke MS, Tuwar SM (2008) Oxidative study of gabapentin by alkaline hexacyanoferrate(III) in room temperature in presence of catalytic amount of Ru(III). A mechanistic approach. J. Mol. Struct. 892: 121–124.
Sharanabasamma K, Angadi MA, Salunke MS, Tuwar SM (2009) Osmium(VIII) catalysed oxidative cleavage of pyrrolidine ring in L-proline by hexacyanoferrate(III) in alkaline media. Ind. Eng. Chem. Res. 48: 10381–10386.
Goel A, Sharma S (2010) Mechanistic study of the oxidation of L-phenylalanine by hexacyanoferrate(III) catalyzed by iridium(III) in aqueous alkaline medium, Transition Met. Chem. 35: 549-554.
Devra V, Yadav MB (2012) Kinetics and mechanism of osmium(VIII) catalyzed oxidation of valine by hexacyanoferrate in alkaline medium, Rassian J. Chem. 5: 67-73.
Upadhyay SK, MC agrawal (1977) Kinetics of Os(VIII)-catalyzed alkaline hexacyanoferrate(III) oxidation of some α-amino acids in presence of excess of ferricyanide, Ind. J. Chem., 15A: 709-712.
Jose TP, Nandibewoor ST, Tuwar SM (2006) Osmium(VIII) catalyzed oxidation of a sulfur containing amino acid – A kinetic and mechanistic Approach. J. Sulfur Chem., 27: 25-36.
Farokhi SA, Nandibewoor ST (2003) Kinetic, mechanistic and spectral studies for the oxidation of sulfanilic acid by alkaline hexacyanoferrate(III). Tetrahedron 59: 7595-7601.
Fawzy A, Shaaban MR (2014) Kinetic and mechanistic investigations on the oxidation of N’-heteroaryl unsymmetrical formamidines by permanganate in aqueous alkaline medium. Transition Met. Chem. 39: 379-386.
Asghar BH, Fawzy A (2014) Kinetic, mechanistic, and spectroscopic studies of permanganate oxidation of azinylformamidines in acidic medium, with autocatalytic behavior of manganese(II). J. Saudi Chem. Soc. in press.
Jeffery GH, Bassett J, Mendham J, Denney RC (1996) Text Book of Quantitative Chemical Analysis, 5th ed.; ELBS Longman: Essex, pp. 384.
Vogel AI (1973) Text book of practical organic chemistry including quantitative organic analysis, 3rd edn, 332 pp. ELBS, Longman.
Feigl F (1975) Spot tests in organic analysis, 195 pp. Elsevier, New York.
Fawzy A. (2016) Kinetics and mechanism of uncatalyzed and ruthenium(III)-catalyzed oxidation of formamidine derivative by hexacyanoferrate(III) in aqueous alkaline medium. J. Chem. Sci. in press.
Wan WK, Zaw K, Henry PM (1988) Oxidation of olefins by palladium(II). 11. Kinetics and mechanism of the oxidation of allyl alcohol by PdCl42- in aqueous solution. Organometallics 7:1677-1683; Nabivaneis BI, Kalabina LV, Kudritskayi LN (1971) Russ. J. Inorg. Chem. 16: 1736.
Koli BI, Nandibewoor ST (2009) Kinetics and mechanism of palladium(II) catalysed oxidation of dimethyl sulfoxide by alkaline periodate. Indian J. Chem. 48A: 958-963.
Leal JM, Domingo PL, Garcla B, Ibeas S (1993) Alkali metal ion catalysis of the oxidation of L-ascorbic acid by hexacyanoferrate(III) in strongly acidic media. J. Chem. Soc. Faraday Trans. 89: 3571–3577.
Frost AA, Person RG (1973) Kinetics and mechanism, 147 pp. Wiley Eastern, New Delhi.
Amis ES (1966) Solvent effect on reaction rates and mechanism, pp. 28, Academic Press, New York.
Michaelis L, Menten ML (1913) The kinetics of invertase action. Biochem. Z. 49: 333–369.
Hicks KW, Toppen DL, Linck RG (1972) Inner-sphere electron-transfer reactions of vanadium(II) with azidoamine complexes of cobalt(III). Inorg. Chem. 11: 310–315.
Sutin N (1968) Free energies, barriers, and reactivity patterns in oxidation-reduction reactions. Acc. Chem. Res. 1: 225–231.
Freeman F (1981) Permanganate ion oxidations. 13. Soluble manganese(IV) species in the oxidation of 2,4(1H,3H)-pyrimidinediones (uracils). J. Am. Chem. Soc. 103: 1154–1158.