Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei

doi:doi:10.11648/j.ajche.20190702.13

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Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei

Published in American Journal of Chemical Engineering (Volume 7, Issue 2)

Received: 29 May 2019 Accepted: 1 July 2019 Published: 12 July 2019

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Abstract

The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H₂/CO molar ratio) on light olefin (C₂⁼-C₄⁼), paraffin (C₁ + C₂-C₄) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H₂/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.

Published in	American Journal of Chemical Engineering (Volume 7, Issue 2)
DOI	10.11648/j.ajche.20190702.13
Page(s)	71-80
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

"Fischer-Tropsch Synthesis, Response Surface Methodology, Optimization, Fe-Co-Ce Nanocatalyst, Oleylamine Concentration, Operating Conditions "

References

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APA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. (2019). Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. American Journal of Chemical Engineering, 7(2), 71-80. https://doi.org/10.11648/j.ajche.20190702.13

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ACS Style

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am. J. Chem. Eng. 2019, 7(2), 71-80. doi: 10.11648/j.ajche.20190702.13

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AMA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am J Chem Eng. 2019;7(2):71-80. doi: 10.11648/j.ajche.20190702.13

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@article{10.11648/j.ajche.20190702.13,
  author = {Tahereh Taherzadeh Lari and Hamid Reza Bozorgzadeh and Hossein Atashi and Abdol Mahmood Davarpanah and Ali Akbar Mirzaei},
  title = {Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology},
  journal = {American Journal of Chemical Engineering},
  volume = {7},
  number = {2},
  pages = {71-80},
  doi = {10.11648/j.ajche.20190702.13},
  url = {https://doi.org/10.11648/j.ajche.20190702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20190702.13},
  abstract = {The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.},
 year = {2019}
}

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TY  - JOUR
T1  - Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology
AU  - Tahereh Taherzadeh Lari
AU  - Hamid Reza Bozorgzadeh
AU  - Hossein Atashi
AU  - Abdol Mahmood Davarpanah
AU  - Ali Akbar Mirzaei
Y1  - 2019/07/12
PY  - 2019
N1  - https://doi.org/10.11648/j.ajche.20190702.13
DO  - 10.11648/j.ajche.20190702.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 71
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20190702.13
AB  - The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.
VL  - 7
IS  - 2
ER  -

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Author Information

Tahereh Taherzadeh Lari

Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
Hamid Reza Bozorgzadeh

Catalyst Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
Hossein Atashi

Department of Chemical Engineering, Faculty of Engineering, University of Sistan and Baluchestan, Zahedan, Iran
Abdol Mahmood Davarpanah

Department of Physics, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
Ali Akbar Mirzaei

Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran

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APA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. (2019). Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. American Journal of Chemical Engineering, 7(2), 71-80. https://doi.org/10.11648/j.ajche.20190702.13

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ACS Style

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am. J. Chem. Eng. 2019, 7(2), 71-80. doi: 10.11648/j.ajche.20190702.13

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AMA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am J Chem Eng. 2019;7(2):71-80. doi: 10.11648/j.ajche.20190702.13

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@article{10.11648/j.ajche.20190702.13,
  author = {Tahereh Taherzadeh Lari and Hamid Reza Bozorgzadeh and Hossein Atashi and Abdol Mahmood Davarpanah and Ali Akbar Mirzaei},
  title = {Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology},
  journal = {American Journal of Chemical Engineering},
  volume = {7},
  number = {2},
  pages = {71-80},
  doi = {10.11648/j.ajche.20190702.13},
  url = {https://doi.org/10.11648/j.ajche.20190702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20190702.13},
  abstract = {The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology
AU  - Tahereh Taherzadeh Lari
AU  - Hamid Reza Bozorgzadeh
AU  - Hossein Atashi
AU  - Abdol Mahmood Davarpanah
AU  - Ali Akbar Mirzaei
Y1  - 2019/07/12
PY  - 2019
N1  - https://doi.org/10.11648/j.ajche.20190702.13
DO  - 10.11648/j.ajche.20190702.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 71
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20190702.13
AB  - The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.
VL  - 7
IS  - 2
ER  -

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