Self Cleaning PET Fabrics Treated with Nano TiO2 Chemically Cross-Inked with Xanthenes Gum or Cyclodextrin
American Journal of Nano Research and Applications
Volume 3, Issue 3, May 2015, Pages: 46-52
Received: Mar. 26, 2015;
Accepted: Apr. 6, 2015;
Published: Apr. 18, 2015
Views 4289 Downloads 233
Amr Atef Elsayed, Textile Research Division, National Research Centre, 33 Bohouth st. Dokki, Giza, Egypt
Omaima Gaber Allam, Textile Research Division, National Research Centre, 33 Bohouth st. Dokki, Giza, Egypt
Sahar Hassan Salah Mohamed, Dairy Science, Food industry, Nutrition, National Research Centre, 33 Bohouth st. Dokki, Giza, Egypt
Hussain Murad, Dairy Science, Food industry, Nutrition, National Research Centre, 33 Bohouth st. Dokki, Giza, Egypt
This paper would like to compare the ability of two cellulosic polymers to bind nano titania to polyester fabrics, in order to provide the fabric a self-cleaning property. The fixation of the nano titania on the polyester fabric was explored using Cyclodextrin or Xanthan gum. The photocatalytic activity of TiO2 nanoparticles deposited on the polyester fabric was followed by the degradation of methylene blue as a model of an organic stain on the polyester fabric surface. The XRD patterns and SEM photographs of polyester fabric coated with nano titania were recorded. The different factors affecting the self-cleaning property as well as the fixation of nano titania was investigated.
Amr Atef Elsayed,
Omaima Gaber Allam,
Sahar Hassan Salah Mohamed,
Self Cleaning PET Fabrics Treated with Nano TiO2 Chemically Cross-Inked with Xanthenes Gum or Cyclodextrin, American Journal of Nano Research and Applications.
Vol. 3, No. 3,
2015, pp. 46-52.
Baeyer, H. C. V. The Lotus Effect. Sciences, vol.40, pp12-15, (2000).
Kathirvelu, S., Louis, D., and Bharathi, D. “Nanotechnology applications in textiles”. Ind. J. Sci. Tech., vol. 1, pp 1-10, (2008).
Bozzi, A., Yuranova, T., & Kiwi, J. “Self-cleaning of wool-polyamide and polyester textiles by TiO2-rutile modification under daylight irradiation at ambient temperature. J. Photochem. Photobio. A, vol. 172, pp 27–34, (2005).
Daoud, W. A., & Xin, J. H. “Low temperature sol–gel processed Photocatalytic titanium coating. J. of Sol–Gel Sci Tech” vol. 29, pp25–29, (2004).
Daoud, W. A., & Xin, J. H. “Synthesis of Single-Phase Anatase Nanocrystallites at Near Room Temperatures” Chem. Commun., vol. 16, pp 2110–2112,(2005).
Daoud , b.b., Leung,W. A. Tung, S. K., Xin, W. S. J. H., Cheuk , K., & Qi, K. “Self-cleaning keratins” Chem. Mater., vol. 20, pp1242–1244, (2008)
Dong, Y., Bai, Z., Zhang, L., Liu, R., & Zhu, T. “Finishing of cotton fabrics with aqueous nano-titanium dioxide dispersion and the decomposition of gaseous ammonia by ultraviolet irradiation”. J Appl. Poly. Sci., vol. 99, pp 86–291(2006).
Fei, B., Deng, Z., Zhang, Y., & Pang, G. “Room temperature synthesis of Rutile nanorods and their applications on cloth”. Nanotechnology, vol. 17, pp 1927–1931, (2006).
Mihailovic, D., Radetic, M., Ilic, V., Stank Vic, S., Jovancic, P., Potomac, B. “Modification of corona pretreated polyester fabrics with colloidal TiO2 nanoparticles for imparting specific properties”. Proceedings of Aachen Dresden International Textile Conference. Dresden, Germany (2008).
Bozzi, A., Yuranova, T., Guasaquillo, I., Laub, D., & Kiwi, J.” Self-cleaning of modified cotton textiles by TiO2 at low temperatures under daylight irradiation” J. Photochem Photobio A, vol. 174, pp 156–164, (2005).
Darka, M., Zoran , Š., Marija , R.,Tamara , R., Petar , J., Jovan, N., Maja , R. “Functionalization of polyester fabrics with alginates and TiO2 nanoparticles” Carbo. Poly., vol. 79, pp 526–532, (2010).
Nazaria, A., Montazerb, M., Moghadamc. M.B., Anary-Abbasinejadd, M. “Self- cleaning properties of bleached and cationized cotton using TiO2: A statistical approach”. Carb. Poly., vol. 83, pp 1119–1127, (2011).
Wong, Y. W. H., Yuen, C. W. M., Leung, M. Y. S., Ku, S. K. A., & Lam, L. I. “Selected applications of nanotechnology in textiles” Autex Res. J., vol. 6, pp 1–8, (2006).
Szejtli, J., Zsadon, B., Fenyvesi,E., Horvarth,O., & Tudos, F.( 1982)US Patent 4,357,468 .
Martel, B., Morcellet, M., Ruffin, D., Ducoroy, L., & weltrowski, M. “Finishing of Polyester Fabrics with Cyclodextrins and Polycarboxylic Acids as Crosslinking Agents”. J. Inclu. Phen. Macro. Chem., vol. 44, pp 443–446, (2002).
Kaihong , Qi., John ,H. X., & Walid, A. D. “Functionalizing Polyester Fiber with a Self-Cleaning Property Using Anatase TiO2 and Low-Temperature Plasma Treatment” Int. J. Appl. Ceram. Technol., vol. 4, pp 554–563, (2007).
Abd El-Gawad, I.A., Murad, H.A., El-Sayed, E.M., Salah, S.H.”Optimum conditions for production of xanthan gum from hydrolyzed UF- Milk permeate by locally isolated Xanthomonas campestris”. Egypt J Dairy Sci., vol. 1, pp 29-37, (2001).
Qi, K. H., Daoud, W. A., Xin, J. H., Mak, C. L., Tang, W. S., & Cheung, W. P. “Self-Cleaning Cotton” J. Mater. Chem., vol. 16, pp 47, 4567–4574, (2006).
Daoud, W. A., Xin, J. H., & Zhang, Y. H.”Surface functionalization of Cellulose fibers with titanium dioxide nanoparticles and their combined bactericidal activities “Surf Sci, vol. 599 .pp 69–75, (2006).
Ducoroy, L., Martel, B., Bacquet, B., & Morcellet, M. “Ion exchange textiles from the finishing of PET fabrics with cyclodextrins and citric acid for the sorption of metallic cations in water”. J. Incl. Phenom. Macrocycl. Chem., vol. 57, pp 271–277, (2007).
Laurent, D., Maryse, B., Bernard, M., Michel, M. “Removal of heavy metals from aqueous media by cation exchange nonwoven PET coated with b-cyclodextrin-polycarboxylic moieties”. Reac. Func. Poly., vol. 68, pp594–600, (2008).
Chen, L. X., Rajh, T., Jager, W., Nedeljkovic, J., & Thurnauer, N. C.” X-ray absorption reveals surface structure of titanium dioxide nanoparticles”. J. Synchrotron Rad., vol. 6, pp445–447, (1999).
Rajh, T., Chen, L. X., Lukas, K., Liu, T., Thurnauer, M. C., & Tiede, D. M. “Surface restructuring of nanoparticles: An efficient route for ligand–metal oxide crosstalk”. J. Phys. Chem. B, vol. 106, pp 10543–10552, (2002).